Extraction properties of tetraheptylresorcin[4]arenes in relation to Cr(III) ions

• Autorzy: Konczyk J. , Miroshnychenko S. , Kozlowski C.

Identyfikatory

DOI

10.5277/ppmp160225

• Języki publikacji: EN

Abstrakty

EN

Resorcin[4]arene-based ligand bearing four heptyl chains at the lower rim of the molecule was prepared and modified by four tetradietoxyphosphoryl groups in the upper rim. The compounds obtained were characterized by NMR spectroscopy and their extractability toward chromium(III) ions was studied. The influence of process parameters such as the pH of aqueous phase, agitation time and also extractant’s structure and concentration on efficiency of Cr(III) ions solvent extraction is presented. The highest yield of Cr(III) solvent extraction was obtained for two-hour agitation time of 5.010−4 M metal solution of pH 5.0 and 5.010−3 M chloroform solution of the tetradietoxyphosphorylated derivative of heptyl-resorcin[4]arene. Under optimal conditions, competitive solvent extraction of Cr(III), Zn(II), and Cd(II) ions was performed and separation factor values were established as 77.0 and 24.9 for Cr(III)/Cd(II) and Cr(III)/Zn(II) ions pairs, respectively. The stoichiometry of formed metal-ligand complexes 1:1 was found by classical slope analysis method.

Słowa kluczowe

EN

solvent extraction; resorcin[4]arenes; chromium(III); cadmium(II); zinc ions

• Wydawca: Oficyna Wydawnicza Politechniki Wrocławskiej
• Czasopismo: Physicochemical Problems of Mineral Processing
• Rocznik: 2016
• Tom: Vol. 52, iss. 2
• Strony: 835--844
• Opis fizyczny: Bibliogr. 22 poz., rys., tab.

Twórcy

autor

Konczyk J.

• Institute of Chemistry, Environment Protection and Biotechnology, Jan Długosz University of Czestochowa, al. Armii Krajowej 13/15, 42-201 Czestochowa, Poland

autor

Miroshnychenko S.

• Institute of Chemistry, Environment Protection and Biotechnology, Jan Długosz University of Czestochowa, al. Armii Krajowej 13/15, 42-201 Czestochowa, Poland

autor

Kozlowski C.

• Institute of Chemistry, Environment Protection and Biotechnology, Jan Długosz University of Czestochowa, al. Armii Krajowej 13/15, 42-201 Czestochowa, Poland

Bibliografia

• BARTSCH R.A., 1999, Metal ion separation with proton-ionizable lariat ethers, in: Metal ion separation and preconcentration, ACS, 146-155.
• BENOSMANE N., HAMDI S.M., HAMDI M., BOUTEMEUR B., 2009, Selective transport of metal ions across polymer inclusion membranes (PIMs) containing calix[4]resorcinarenes, Sep. Purif. Technol., 65, 211-219.
• BHAR T., BANERJEE M., BASU S., 2013, Synergistic extraction of Cr(III) using di(2-ethylhexyl)phosphoric acid and 18-crown-6 in n-butanol, Int. J. Chem., 34(2), 1310-1316.
• DAYAN A.D., PAINE A. J., 2001, Mechanisms of chromium toxicity, carcinogenicity and allergenicity: Review of the literature from 1985 to 2000, Hum. Exp. Toxicol., 20, 439–451.
• DELIGOZ H., ERDEM E., 2008, Comparative studies on the solvent extraction of transition metal cations by calixarene, phenol and ester derivatives, J. Hazard. Mater. 154, 29-32.
• JUMINA SARJONO R.E., SISWANTA D., SANTOSA S.J., OHTO K., 2011, Adsorption Characteristics of Pb(II) and Cr(III) onto C-Methylcalix[4]resorcinarene, J. Korean Chem. Soc., 55, 454-462.
• JUMINA SARJONO R.E., PARAMITHA B., HENDARYANI I., SISWANTA D., SANTOSA S.J., ANWAR Ch., SASTROHAMIDJOJO H., OHTO K., OSHIMA T., 2007, Adsorption characteristics of Pb(II) and Cr(III) onto C-4-methylphenylcalix[4]resorcinarene in batch and fixed bed column systems, J. Chinese Chem. Soc., 54, 1167-1178.
• KONCZYK J., KOZLOWSKI C., WALKOWIAK W., 2013, Lead(II) removal from aqueous solutions by solvent extraction with tetracarboxylresorcin[4]arene, Physicochem. Probl. Miner. Process., 49(1), 213-222.
• LANAGAN M.D., IBANA D.C., 2003, The solvent extraction and stripping of chromium with Cyanex 272, Miner. Eng., 16, 237-245.
• LUO J.H., LI J., QI Y.B., CAO Y.Q., 2013, Study on the removal of chromium(III) by solvent extraction, Desalination Water Treat., 51, 2130-2134.
• MÄKINEN M., JALKANEN J.P., VAINIOTALO P., 2002, Conformational properties and intramolecular hydrogen bonding of tetraethyl resorcarene: an ab initio study, Tetrahedron, 58, 8591-8596.
• MATULKOVA I., ROHOVEC J., 2005, Synthesis, characterization and extraction behaviour of calix[4]arene with four propylene phosphonic acid groups on the lower rim, Polyhedron, 24, 311-317.
• OHTO K., 2010, Review of the extraction behavior of metal cations with calixarene derivatives, Solvent Extr. Res. Dev., 17, 1-18.
• PEARSON R.G., 1963, Hard and Soft Acids and Bases, J. Am. Chem. Soc., 85, 3533-3539.
• RAMOS R.L., RUBIO L.F., CORONADO R.M.G., BARON J.M., 1995, Adsorption of trivalent chromium from aqueous solution onto activated carbon, J. Chem. Technol. Biotechnol. 62, 64–67.
• RAO V.M., SASTRI M.N., 1980, Solvent extraction of chromium: a review, Talanta, 27, 771.
• RIAHI F., BAGHERZADEH M., 2010, Separation of some lanthanide(III) ions by using 18-crowns-6 derivativs from acidic solution, J. Appl. Sci., 10, 1781-1786.
• SCHANTWINKEL B., STOLL I., MIX A., REKHAVSKY M.V., BOROVKOV V.V., INOUE Y., MATTAY J., 2008, Monomeric, dimeric and hexameric resorcin[4]arene assemblies with alcohols in apolar solvents, Chem. Commun., 3873-3875.
• ULEWICZ M., WALKOWIAK W., 2006, Removal of Zn(II), Cd(II) and Pb(II) using polymer inclusion membrane transport with proton ionizable DB-16-C-5 crown ethers, Physicochem. Probl. Miner. Process., 40, 185-194.
• WIONCZYK B., APOSTOLUK W., 2004, Solvent extraction of chromium (III) from alkaline media with quaternary ammonium compounds. Part I, Hydrometallurgy, 72, 185.
• WOLINSKA A., STEPNIEWSKA Z., WLOSEK R., 2013, The influence of old leather tannery district on chromium contamination of soils, water and plants, Natural Sci., 5(2A), 253-258.
• WULFSBERG G., 1991, Principles of Descriptive Inorganic Chemistry, University Science Books, Mill Valley, CA, 23.