Removal efficiency of anionic surfactants from water during UVC photolysis and advanced oxidation process in H₂O₂/UVC system

• Autorzy: Ríos F. , Olak-Kucharczyk M. , Gmurek M. , Ledakowicz S.

Identyfikatory

DOI

10.1515/aep-2017-0003

Warianty tytułu

PL

Efektywność usuwania surfaktantów anionowych z wody przy zastosowaniu promieniowania UVC i zaawansowanego utleniania w układzie H₂O₂/UVC

• Języki publikacji: EN

Abstrakty

EN

Surfactants after their use are discharged into aquatic ecosystems. These compounds may be harmful to fauna and flora in surface waters or can be toxic for microorganisms of the activated sludge or biofilm in WWTP. In order to determine effectiveness of different advanced oxidation processes on the degradation of surfactants, in this study the degradation of anionic surfactants in aqueous solution using photolysis by 254 nm irradiation and by advanced oxidation process in a H₂O₂/UVC system was investigated. Two representatives of anionic surfactants, linear alkyl benzene sulphonate (LAS-R_11-14) and ether carboxylic derivate (EC-R_12-14E₁₀) were tested. The influence of pH, initial surfactant concentration and dose of hydrogen peroxide on the degradation was also studied. Results show outstanding effectiveness of the H₂O₂/UVC system in the removal of surfactant from aqueous solutions.

PL

Surfaktanty, podobnie jak większość tego typu substancji chemicznych, po wykorzystaniu trafi ają do środowiska wodnego. Związki te mogą stwarzać zagrożenie dla fl ory i fauny zasiedlającej wody powierzchniowe, jak również mogą działać toksycznie na mikroorganizmy znajdujące się w osadzie czynnym w oczyszczalniach ścieków. W niniejszej pracy przedstawiono wyniki badań degradacji wybranych surfaktantów anionowych w środowisku wodnym przy zastosowaniu promieniowania UVC i zaawansowanego utleniania w układzie H₂O₂/UVC. Zbadano wpływ następujących parametrów reakcyjnych: odczyn środowiska reakcyjnego, początkowego stężenia obiektów badań i nadtlenku wodoru na szybkość degradacji surfaktantów. Uzyskane w toku prac badawczych wyniki potwierdzają wysoką skuteczność zaawansowanego utleniania w układzie H₂O₂/UVC w usuwaniu badanych surfaktantów ze środowiska wodnego, które jest procesem znacznie efektywniejszym w porównaniu do procesu fotolizy. Unauthenticated

Słowa kluczowe

EN

advanced oxidation process; anionic surfactants; ether carboxylic derivate; H2O2/UVC system; linear alkyl benzene sulfonate; UVC photolysis

PL

surfakanty; degradacja surfakantów; zaawansowany proces utleniania; anionowe środki powierzchniowo czynne; eter karboksylowy; system H2O2 / UVC; fotoliza

• Wydawca: Institute of Environmental Engineering, Polish Academy of Sciences
• Czasopismo: Archives of Environmental Protection
• Rocznik: 2017
• Tom: Vol. 43, no. 1
• Strony: 20--26
• Opis fizyczny: Bibliogr. 33 poz., tab., wykr.

Twórcy

autor

Ríos F.

• Department of Chemical Engineering, Spain University of Granada

autor

Olak-Kucharczyk M.

• Lodz University of Technology, Poland, Department of Bioprocess Engineering

autor

Gmurek M.

• Lodz University of Technology, Poland, Department of Bioprocess Engineering

autor

Ledakowicz S.

• Lodz University of Technology, Poland, Department of Bioprocess Engineering

Bibliografia

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Uwagi

Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę (zadania 2017).