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A new radiocarbon laboratory has been established recently at the Lebanese Atomic Ener-gy Commission. This laboratory consists of benzene synthesis line and a low background liquid scin-tillation counter, Tri-Carb 3180 TR/SL for measurements with Bismuth Germanate (BGO) guard de-tector. The effectiveness of the benzene line was tested firstly by preparing benzene from a wood sample after carbide and acetylene receiving. Normalization and standardization of the liquid scintil-lation counter was carried out, as well as the Factor of Merit (E2/B) was determined for three differ-ent counting regions. To assure accuracy and reliability of results, reference materials were used. Based on z-score and u-score evaluation, as well as Student's t-test, acceptable data were obtained from travertine and wood samples available through the International Atomic Energy Agency (IAEA-C2 and IAEA-C5), and humic acid (U) and murex shell (R) from the Fifth International Radiocarbon Intercomparison (VIRI). After that, a preliminary study was done, which is the base for future re-search in order to assess the anthropogenic impact and degree of environmental pollution in terms of radiocarbon isotope ratio (Δ14C) deduced from the Percent Modern Carbon or PMC. This work repre-sents the results of four reference materials and those of five green grass samples. The Δ14C of green grass samples collected from two different clean zones were found to be 50‰ and 52‰, while the values of those collected from different polluted zones were 23‰, 7‰ and 15‰.
Wydawca
Czasopismo
Rocznik
Tom
Strony
87--91
Opis fizyczny
Bibliogr. 23 poz., wykr.
Twórcy
autor
- Lebanese Atomic Energy Commission- National Council for Scientific Research, P.O. Box 11-8281, Riad El Solh, Beirut, Lebanon
autor
- Lebanese Atomic Energy Commission- National Council for Scientific Research, P.O. Box 11-8281, Riad El Solh, Beirut, Lebanon
autor
- Lebanese Atomic Energy Commission- National Council for Scientific Research, P.O. Box 11-8281, Riad El Solh, Beirut, Lebanon
autor
- Lebanese Atomic Energy Commission- National Council for Scientific Research, P.O. Box 11-8281, Riad El Solh, Beirut, Lebanon
autor
- Beirut Arab University, Faculty of Sciences, Chemistry Department, P.O.Box 11 - 50 - 20 Riad El Solh, Beirut, Lebanon
Bibliografia
- 1.Battipaglia G, Marzaioli F, Lubritto C, Altieri S, Strumia S, Cherubini P and Cotrufo MF, 2010. Traffic pollution affects tree-ring width and isotopic composition of Pinus pinea. Science of the Total Environment 408(3): 586–593, DOI 10.1016/j.scitotenv.2009.09.036.
- 2.Beramendi-Orosco LE, Gonzalez-Hernandez G, Urrutia-Fucugauchi J and Morton-Bermea O, 2006. Radiocarbon Laboratory at the National Autonomous University of Mexico: First set of samples and new 14C internal reference material. Radiocarbon 48(3): 485–491.
- 3.Bronić IK, Horvatinčić N, Baresić J and Obelić B, 2009. Measurement of 14C activity by liquid scintillation counting. Applied Radiation and Isotopes 67(5): 800–804, DOI 10.1016/j.apradiso.2009.01.071.
- 4.Bronić IK, Obelić B, Horvatinčić N, Barešić J, Sironić A and Mini-chreiter K, 2010. Radiocarbon application in environmental science and archaeology in Croatia. Nuclear Instruments and Methods in Physics Research A 619(1–3): 491–496, DOI 10.1016/j.nima.2009.11.032.
- 5.Hoque MA and Burgess WG, 2012. 14C dating of deep groundwater in the Bengal Aquifer System, Bangladesh: Implications for aquifer anisotropy, recharge sources and sustainability. Journal of Hydrology 444–445: 209–220, DOI 10.1016/j.jhydrol.2012.04.022.
- 6.Knoll GF, 2010. Radiation detection and measurement, fourth edition, USA.
- 7.Kulkova M, Chadov F and Davidochkina A, 2011. Radiocarbon in vegetation of coastal zone of Finnish Bay (Russia). Procedia Environmental Sciences 8: 375–381.
- 8.L’Annunziata MF, 2003. Handbook of radioactivity analysis, second edition, vol.2, Elsevier, USA.
- 9.Marzaioli F, Fiumano V, Capano M, Passariello I, Cesare NDe and Terrasi F, 2011. Forensic applications of 14C at CIRCE. Nuclear Instruments and Methods in Physics Research B 269: 3171–3175, DOI 10.1016/j.nimb.2011.04.025.
- 10.Mazeika J, Petrosius R and Pukiene R, 2008. Carbon-14 in tree rings and other terrestrial samples in the vicinity of Ignalina Nuclear Power Plant, Lithuania. Journal of Environmental Radioactivity 99(2): 238–247, DOI 10.1016/j.jenvrad.2007.07.011.
- 11.Molnar M, Bujtas T, Svingor E and Fluto I, 2007. Monitoring of atmos-pheric excess 14C around Paks nuclear power plant, Hungary. Radiocarbon 49(2): 1031–1043.
- 12.Muraki Y, Masua K, Arslanov, Toyoizumi H, Kato M, Naruse Y, Murata T and Nishiyama T, 2001. Measurement of radiocarbon content in leaves from some Japanese sites. Radiocarbon 43(2B): 695–701.
- 13.Nakata K, Kodama H, Hasegawa T, Hama K, Lwatsuki T and Miyajima T, 2013. Groundwater dating using radiocarbon in fulvic acid in groundwater containing fuorescein. Journal of Hydrology 489: 189–200, DOI 10.1016/j.jhydrol.2013.03.012.
- 14.Olsen J, Heinemeier J, Hornstrup KM, Bennike P and Thrane H, 2013. “Old wood” effect in radiocarbon dating of prehistoric cremated bones? Journal of Archaeological Science 40(1): 30–34, DOI 10.1016/j.jas.2012.05.034.
- 15.Pataki DE, Randerson JT, Wang W, Herzenach MK and Grulke NE, 2010. The carbon isotope composition of plants and soils as biomarkers of pollution. West et al. (eds), Isoscapes: Understanding Movement, Pattern and Process on Earth Through isotope Mapping, Springer: 407–423, DOI 10.1007/978-90-481-3354-3.
- 16.Rakowski AZ, Nadeau MJ, Nakamura T, Pazdur A, Pawelczyk S and Piotrowska N, 2013. Radiocarbon method in environmental monitoring CO2 emission. Nuclear Instruments and Methods in Physics Research B 294: 503–507, DOI 10.1016/j.nimb.2012.07.017.
- 17.Rozanski K, Stichler W, Gonfianti R, Scott EM, Beukens RP, Kromer B and Vander Plitch J, 1992. The IAEA 14C intercomparison exercise 1990. Radiocarbon 34(3): 506–519.
- 18.Scott EM, Cook GT and Naysmith P, 2010. The Fifth International Radiocarbon Intercomparison (VIRI): An assessment of laboratory performance in stage 3. Radiocarbon 52(2–3): 859–865.
- 19.Sironić A., Bronić IK, Horvatinčić N, Barešić J, Obelić B and Felja I, 2013. Statud report on Zagreb Radiocarbon Laboratory- AMS and LSC results. Nuclear Instruments and Methods in Physics Research B 294: 185–188, DOI 10.1016/j.nimb.2012.01.048.
- 20.Skripkin V and Kovaliukh N, 1998. Recent developments in the proce-dures used at the SSCER laboratory for the routine preparation of lithium carbide. Radiocarbon 49(1): 211–214.
- 21.Stuiver M and Polach HA, 1977. Discussion: Reporting of 14C data. Radiocarbon 19(3): 355–363.
- 22.Svetlik I, Povinec PP, Molnar M, Meinhardt F, Michalek V, Simon J and Svingor E, 2010. Estimation of long-term trends in the tropospheric 14CO2 activity concentration. Radiocarbon 52(2–3): 815– 822.
- 23.Thompson M, Ellison SLR and Wood R, 2006. The international harmonized protocol for the proficiency testing of analytical chemistry laboratories. IUPAC Technical Report. Pure and Applied Chemistry 78(1): 145–196, DOI 10.1351/pac200678010145.
Typ dokumentu
Bibliografia
Identyfikator YADDA
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