Highly efficient facilitated membrane transport of palladium(ii) ions from hydrochloric acid solutions through plasticizer membranes with cyanex 471X

• Autorzy: Pospiech B.

Identyfikatory

DOI

10.5277/ppmp150125

• Języki publikacji: EN

Abstrakty

EN

In this work the efficient recovery of palladium(II) ions from hydrochloric acid solutions by transport through polymer inclusion membranes (PIMs) was studied. The membrane consisted of cellulose triacetate (CTA) as the polymeric support, o-nitrophenyl octyl ether (ONPOE) as the plasticizer and Cyanex 471X (triisobutylphosphine sulphide) as the ion carrier. The effect of various parameters on the transport kinetics and the recovery factor of palladium(II) was studied, including concentration of Cyanex 471X in the membrane, hydrochloric acid concentration in the source phase and potassium thiocyanate (KSCN) concentration in the receiving phase.

Słowa kluczowe

EN

palladium; platinum group metals (PGMs); Cyanex 471X; polymer inclusion membrane (PIM)

• Wydawca: Oficyna Wydawnicza Politechniki Wrocławskiej
• Czasopismo: Physicochemical Problems of Mineral Processing
• Rocznik: 2015
• Tom: Vol. 51, iss. 1
• Strony: 281--291
• Opis fizyczny: Bibliogr. 24 poz., rys., tab.

Twórcy

autor

Pospiech B.

• Department of Chemistry, Czestochowa University of Technology, Armii Krajowej 19, 42-200 Czestochowa, Poland

Bibliografia

• 1. AHMED, I.M., NAYL, A.A., DAOUD J.A., 2011, Extraction of palladium from nitrate solution by Cyanex 471X, Internat. J. Miner. Process. 101, 89-93.
• 2. AROUS, O., KERDJOUDJ, H., SETA, P., 2004, Comparison of carrier-facilitated silver(I) and copper(II) ions transport mechanisms in a supported liquid membrane and in a plasticized cellulose triacetate membrane, J. Membr. Sci., 241 (2), 177-186.
• 3. BANDEKAR, S.V., DHADKE, P.M., 1998, Solvent extraction separation of platinum(IV) and palladium(II) by 2-ethylhexyl phosphonic acid mono-2-ethylhexyl ester, Sep. Purif. Technol., 13, 129-135.
• 4. CHAGNES, A., POSPIECH, B., 2013, A brief review on hydrometallurgical technologies for recycling spent lithium-ion batteries, J. Chem. Technol. Biotechnol. 88 (7), 1191–1199.
• 5. CIESZYNSKA, A., WISNIEWSKI, M., 2011, Selective extraction of palladium(II) from hydrochloric acid solutions with phosphonium extractants, Sep. Purif. Technol. 80, 385-389.
• 6. DANESI, P.R., 1984, Separation of metal species by supported liquid membranes, Sep. Sci. Technol.19,857-879.
• 7. DE AGREDA, D., GARCIA-DIAZ, I., LOPEZ, F.A., ALGUACIL, F.J., 2011, Supported liquid membranes technologies in metals removal from liquid effluents, Rev. Metal., 47, 146-168.
• 8. DE SAN MIGUEL, E., MONROY-BARETTO, R., AGUILAR, J.C., OCAMPO, A., DE GYVES J., 2011, Structural effects on metal ion migration across polymer inclusion membranes: Dependence of membrane properties and transport profiles on the weight and volume fractions of the components, J. Membr. Sci. 379, 416-425.
• 9. FONTAS, C., ANTICOL, E., VOCANSON, F., LAMARTINE, R., SETA, P., 2007, Efficient thiacalix[4]arenes for the extraction and separation of Au(III), Pd(II) and Pt(IV) metal ions from acidic media incorportaed in membranes and solid phases, Sep. Purif. Technol., 54, 322-328.
• 10. FONTAS, C., SALVADO, V., HIDALGO, M., 2003, Selective enrichment of palladium from spent automotive catalysts by using a liquid membrane system, J. Membr. Sci., 223, 39-48.
• 11. FORNALCZYK, A, SATERNUS, M, 2013, Platinum recovery from used auto catalytic converters in electrorefining process, METABK 52(2) 219-222.
• 12. GARDNER, J., WALKER, J., LAMB, J., 2004, Permeability and durability effects of cellulose polymer variation in polymer inclusion membranes, J. Membr. Sci. 229, 87-93.
• 13. GHERASIM, C.V., CRISTEA, M., 2011, New polymer inclusion membrane. Preparation and characterisation, Dig. J. Nanomater. Biostructur. 6, 1499-1508.
• 14. HIDALGO, M., MASANA, A., SALVADO, V., MUÑOZ, M., VALIENTE, M., 1991, Extraction of palladium with tri-isobutylphosphine sulphide (Cyanex 471) in toluene from chloride solutions containing thiocyanate, Talanta 38, 483-488.
• 15. KOLEV, S.D., SAKAI, Y., CATTRALL, R.W., PAIMIN, R., POTTER, I.D., 2000, Theoretical and experimental study of palladium(II) extraction from hydrochloric acid solutions into Aliquat 336/PVC membranes, Anal. Chim. Acta, 413, 241-246.
• 16. O’ROURKE, M., DUFFY, N., De MARCO, R., POTTER, I., 2011, Electrochemical impendance spectroscopy – a simple method for the chararcterization of polymer inclusion membranes containing Aliquat 336, Membranes, 1, 132-148.
• 17. PAN, L., BAO, X., GU, G., 2013, Solvent extraction of palladium(II) and effective separation of palladium(II) and platinum(IV) with synthetic sulfoxide MSO, J. Min. Metall. Sec. B-Metall. 49 (1) B (2013) 57-63.
• 18. POSPIECH, B., 2012(a), Separation of silver(I) and copper(II) from aqueous solutions by transport through polymer inclusion membranes with Cyanex 471X, Sep. Sci. Technol. 47, 1413-1419.
• 19. POSPIECH, B., 2012(b), Studies on platinum recovery from solutions after leaching of spent catalysts by solvent extraction, Physicochem. Probl. Miner. Process. 48, 239-246.
• 20. POSPIECH, B., WALKOWIAK, W., 2010, Studies on iron(III) removal from chloride aqueous solutions by solvent extraction and transport through polymer inclusion membranes with D2EHPA, Physicochem. Probl. Miner. Process., 44, 195-204.
• 21. POSPIECH, B., 2013, Hydrometallurgical recovery of cobalt(II) from acidic chloride solutions by transport through polymer inclusion membranes, Physicochem. Probl. Miner. Process., 49(2), 641-649.
• 22. REDDY, B.R., RAJU, B., LEE, J.Y., PARK, H.K., 2010, Process for the separation and recovery of palladium and platinum from spent automobile catalyst leach liquor using LIX 84I and Alamine 336, J. Hazard. Mater., 180, 253-258.
• 23. SADYRBAEVA, T., 2006, Separation of copper(II) from palladium(II) and platinum(IV) by di(2-ethylhexyl)phosphoric acid-based liquid membranes during electrodialysis, J. Membr. Sci., 275, 195-201.
• 24. SATERNUS, M, FORNALCZYK, A, 2013, Possible ways of refining precious group metals (PGM) obtained from recycling of the used auto catalytic converters, METABK 52(2), 267-270.