Adsorption of ciprofloxacin from aqueous environment by using synthesized nanoceria

• Autorzy: Rahdar Abbas , Rahdar Somayeh , Ahmadi Shahin , Fu Jie

Identyfikatory

DOI

10.1515/eces-2019-0021

Warianty tytułu

PL

Adsorpcja ciprofloksacyny ze środowiska wodnego za pomocą zsyntezowanych nanocząstek tlenku ceru

• Języki publikacji: EN

Abstrakty

EN

Antibiotics are widely detected emerging contaminants in water environments and possess high potential risks to human health and aquatic life. However, conventional water treatment processes cannot remove them sufficiently. To develop innovative nanoadsorbents for effectively remove antibiotic contaminants from water environment, nanoceria were prepared via in situ precipitation method, and evaluated their adsorption capacity for a model antibiotic, ciprofloxacin (CIP). The properties of the prepared nanoceria were characterized by transmission electron microscopy (TEM), X-ray diffraction (XRD) and vibration sample magnetization (VSM). The effect of various operating parameters such as pH, initial CIP concentration, contact time, and adsorbent dosage on adsorptions of CIP were studied in batch experiments. Maximum adsorption capacity of the nanoceria was 49.38 mg/g at the conditions of pH 5, initial CIP concentration of 200 mg/dm³ and adsorbent dosage of 0.2 g/dm³, when 95.43 % of the CIP was removed. For adsorption kinetics, both pseudo-first-order and pseudo-second-order models can well describe the experimental data, indicating that the adsorption process was controlled by both physical diffusion and chemical interaction. For adsorption isotherms, the Freundlich model could fit the experimental data better than the Langmuir and Temkin models, suggesting a multilayer adsorption process. The thermal dynamics study showed the absorption process was spontaneity, exothermic, and irreversible. Finally it was concluded that the nanoceria can be used effectively for CIP removal.

Słowa kluczowe

EN

ciprofloxacin; cerium oxide nanoparticles; adsorption of ciprofloxacin; isotherm models; antibiotic pollutants; thermodynamics studies

PL

cyprofloksacyna; nanocząstki tlenku ceru; adsorpcja cyprofloksacyny; model izotermy; zanieczyszczenia antybiotykami; badania termodynamiczne

• Wydawca: Towarzystwo Chemii i Inżynierii Ekologicznej
• Czasopismo: Ecological Chemistry and Engineering. S
• Rocznik: 2019
• Tom: Vol. 26, nr 2
• Strony: 299--311
• Opis fizyczny: Bibliogr. 31 poz., rys., wykr., tab.

Twórcy

autor

Rahdar Abbas

• Department of Physics, University of Zabol, Zabol, P. O. Box. 98613-35856, Iran

autor

Rahdar Somayeh

• Department of Environmental Health, Zabol University of Medical Sciences, Zabol, Iran

autor

Ahmadi Shahin

• Department of Environmental Health, Zabol University of Medical Sciences, Zabol, Iran

autor

Fu Jie

• Department of Environmental Science & Engineering, Fudan University, Shanghai 200438, China, phone and fax [phone]

Bibliografia

• [1] Gao Y, Li Y, Zhang L, Huang H, Hu J, Shah SM, et al. J Colloid Interface Sci. 2012;368:540-546. DOI: 10.1016/j.jcis.2011.11.015.
• [2] Agarwal S, Tyagi I, Gupta VK, Dehghani MH, Jaafari J, Balarak D, et al. J Mol Liq. 2016;224:618-623. DOI: 10.1016/j.molliq.2016.10.032.
• [3] Wang Z, Shen D, Shen F, Wu C, Gu S. J Mol Liq. 2017;241:612-621. DOI: 10.1016/j.molliq.2017.05.097.
• [4] Elmolla ES, Chaudhuri M. J Hazard Mater. 2010;173:445-449. DOI: 10.1016/j.jhazmat.2009.08.104.
• [5] Gulkowska A, Leung HW, So MK, Taniyasu S, Yamashita N, Yeung LWY, et al. Water Res. 2008;42:395-403. DOI: 10.1016/j.watres.2007.07.031.
• [6] Al-Musawi TJ. J Mol Liq. 2015;211:431-441. DOI: 10.1016/j.molliq.2015.06.067.
• [7] Zhang Y, Jiao Z, Hu Y, Lv S, Fan H, Zeng Y, et al. Environ Sci Pollut Res. 2017;24:2987-2995. DOI: 10.1007/s11356-016-7964-7.
• [8] Wu S, Zhao X, Li Y, Zhao C, Du Q, Sun J, et al. Chem Eng J. 2013;230:389-395. DOI: 10.1016/j.cej.2013.06.072.
• [9] Carabineiro SA, Thavornamornsri T, Pereira MF, Figueiredo JL. Water Res. 2011;45:4583-4591. DOI: 10.1016/j.watres.2011.06.008.
• [10] Rivera-Utrilla J, Sánchez-Polo M, Ferro-García MÁ, Prados-Joya G, Ocampo-Pérez R. Chemosphere. 2013;93:1268-1287. DOI: 10.1016/j.chemosphere.2013.07.059.
• [11] Ay F, Kargi F. J Hazard Mater. 2010;179:622-627. DOI: 10.1016/j.jhazmat.2010.03.048.
• [12] Yuan F, Hu C, Hu X, Qu J, Yang M. Water Res. 2009;43:1766-1774. DOI: 10.1016/j.watres.2009.01.008.
• [13] Sirtori C, Zapata A, Oller I, Gernjak W, Agüera A, Malato S. Water Res. 2009;43:661-668. DOI: 10.1016/j.watres.2008.11.013.
• [14] Vakili M, Rafatullah M, Salamatinia B, Abdullah AZ, Ibrahim MH, Tan KB, et al. Carbohydr Polym. 2014;113:115-130. DOI: 10.1016/j.carbpol.2014.07.007.
• [15] Homem V, Alves A, Santos L. Chem Eng J. 2013;220:35-44. DOI: 10.1016/j.cej.2013.01.047.
• [16] Doltabadi M, Alidadi H, Davoudi M. Environ Prog Sustain. 2016;35:1078-1090. DOI: 10.1002/ep.12334.
• [17] Shukla A, Zhang YH, Dubey P, Margrave JL, Shukla SS. J Hazard Mater. 2002;95:137-152. DOI: 10.1016/S0304-3894(02)00089-4.
• [18] Peng X, Luan Z, Ding J, Di Z, Li Y, Tian B. 2005:1;59:399-403. DOI: 10.1016/j.matlet.2004.05.090.
• [19] Phatai P, Futalan CM. Desalin Water Treat. 2015;57:1-10. DOI: 10.1080/19443994.2015.1027281.
• [20] Su Y, Yang W, Sun W, Li Q, Shang JK. Chem Eng J. 2015;268:270-279. DOI: 10.1016/j.cej.2015.01.070.
• [21] Liu W, Zhao X, Wang T, Fu J, Ni J. J Mater Chem A. 2015;3:17676-17684. DOI: 10.1039/C5TA04521E.
• [22] Phokha S, Pinitsoontorn S, Maensiri S. Nano-Micro Lett. 2013;5:223-233. DOI: 10.1007/bf03353753.
• [23] Peng F, He PW, Luo Y, Lu X, Liang Y, Fu J. Clean - Soil Air Water. 2012;40:493-498. DOI: 10.1002/clen.201100469.
• [24] Vučurović VM, Razmovski RN, Tekić MN. J Taiwan Inst Chem E. 2012;43:108-111. DOI: 10.1016/j.jtice.2011.06.008.
• [25] Fu J, Song R, Mao WJ, Wang Q, An SQ, Zeng QF, et al. Environ Prog Sustain. 2011;30:558-566. DOI: 10.1002/ep.10506.
• [26] Dehghani MH, Faraji M, Mohammadi A, Kamani H. Korean J Chem Eng. 2017;34:454-462. DOI: 10.1007/s11814-016-0274-4.
• [27] Dursun AY. Biochem Eng J. 2006;28:187-195. DOI: 10.1016/j.bej.2005.11.003.
• [28] Peng H, Pan B, Wu M, Liu Y, Zhang D, Xing B. J Hazard Mater. 2012;233-234:89-96. DOI: 10.1016/j.jhazmat.2012.06.058.
• [29] Avisar D, Lester Y, Mamane H. J Hazard Mater. 2010;175:1068-1074. DOI: 10.1016/j.jhazmat.2009.10.122.
• [30] Rahdar S, Rahdar A, Igwegbe CA, Moghaddam F, Ahmadi S. Desalin Wat Treat. 2019;141:386-393. DOI: 10.5004/dwt.2019.23473.
• [31] Bazrafshan E, Rahdar S, Balarak D, Mostafapour F, Zazouli M. Iran J Health Sci. 2015;3:15-28. DOI: 10.1080/19443994.2014.895778.

Uwagi

PL

Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2019).