The lightfastness and structure of semi-permanent hair dyes, derivatives of o-nitro-N-β-hydroxyethylaniline

• Autorzy: Szuster Lucjan , Wojciechowski Krzysztof , Rutowicz Joanna

Identyfikatory

DOI

10.57636/68.2023.1.2

Warianty tytułu

PL

Odporność na działanie światła i budowa barwników typu “semi-permanent”, pochodnych o-nitro-N-β-hydroksyetyloaniliny stosowanych do barwienia włosów

• Języki publikacji: EN

Abstrakty

EN

The aim of this study was to examine the substituent effects on lightfastness and spectral properties of o-nitro-N-β-hydroxyethylaniline derivatives, used in semi-permanent hair dyes of HC (Hair Color-Dyes ) type. It has been found that the fading rate of the color of hair dyed depends on the nature of the ED and EA substituents in the o-nitro-N-β-hydroxyethylaniline. The o-nitro-N-β-hydroxyethyl aniline derivatives undergo discoloration according to kinetics of the first order reaction. A negative value of the slope coefficient indicates the oxidative mechanism of the reaction. From the relationship lmax=f(σ) σp─Hammett’s constant were calculated. Using the semi-empirical AM1 quantum chemical method, we calculated the structures of hair dyes The dye structures were optimized using MM +, DM, and AM1.

PL

Celem pracy było zbadanie wpływu podstawników na działanie światła i właściwości spektralne pochodnych o-nitro-N-β-hydroksyetyloaniliny, stosowanych w półtrwałych farbach (semi-permanent) do barwienia włosów. Stwierdzono, że szybkość zaniku barwy włosów zależy od charakteru podstawników ED i EA w o-nitro-N-β-hydroksyetyloanilinie. Pochodne o-nitro-N-β-hydroksyetyloaniliny ulegają odbarwieniu zgodnie z kinetyką reakcji 1-go rzędu. Ujemna wartość współczynnika nachylenia wskazuje na mechanizm utleniający reakcji. Z zależności lmax=f(σ) obliczono stałe σp─Hammetta. Stosując półempiryczną metodę kwantowo-chemiczną AM1, obliczyliśmy budowę barwników pochodnych N-β-hydroksyetyloamino-nitrobenzenu. Struktury barwników optymalizowano przy użyciu MM +, DM oraz AM1. półtrwałe farby do włosów.

Słowa kluczowe

EN

semi-permanent hair dyes; photochemical degradation; Hammett equation; molecular geometry; AM1 quantum-chemical method

PL

degradacja fotochemiczna; równanie Hammetta; geometria cząsteczki; metoda kwantowo-chemiczna AM1; półtrwałe farby do włosów

• Wydawca: Sieć Badawcza Łukasiewicz - Łódzki Instytut Technologiczny
• Czasopismo: Technologia i Jakość Wyrobów
• Rocznik: 2023
• Tom: R. 68
• Strony: 19--37
• Opis fizyczny: Bibliogr. 42 poz., rys., tab., wykr., wz.

Twórcy

autor

Szuster Lucjan

• Łukasiewicz – Łódź Institute of Technology, 73 Zgierska Str., 91-463 Łódź, Poland

autor

Wojciechowski Krzysztof

• Institute of Environmental Engineering and Building Installations, Lodz University of Technology, Al. Politechniki 6, 90-924 Łódź, Poland

autor

Rutowicz Joanna

• Łukasiewicz – Łódź Institute of Technology, 73 Zgierska Str., 91-463 Łódź, Poland

Bibliografia

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Uwagi

Opracowanie rekordu ze środków MNiSW, umowa nr SONP/SP/546092/2022 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2024).