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The effects of operating conditions on the performance of a direct carbon fuel cell

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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The influences of various operating conditions including cathode inlet air flow rate, electrolyte temperature and fuel particles size on the performance of the direct carbon fuel cell DCFC were presented and discussed in this paper. The experimental results indicated that the cell performance was enhanced with increases of the cathode inlet gas flow rate and cell temperature. Binary alkali hydroxide mixture (NaOH-LiOH, 90-10 mol%) was used as electrolyte and the biochar of apple tree origin carbonized at 873 K was used as fuel. Low melting temperature of the electrolyte and its good ionic conductivity enabled to operate the DCFC at medium temperatures of 723-773 K. The highest current density (601 A m-2) was obtained for temperature 773 K and air flow rate 8.3 x 106 m3s-1. It was shown that too low or too high air flow rates negatively affect the cell performance. The results also indicated that the operation of the DCFC could be improved by proper selection of the fuel particle size.
Rocznik
Strony
187--197
Opis fizyczny
Bibliogr. 16 poz., il.
Twórcy
autor
  • Czestochowa University of Technology, Department of Energy Engineering, Brzeźnicka 60a, 42-200 Częstochowa, Poland
autor
  • Czestochowa University of Technology, Department of Energy Engineering, Brzeźnicka 60a, 42-200 Częstochowa, Poland
autor
  • Czestochowa University of Technology, Department of Energy Engineering, Brzeźnicka 60a, 42-200 Częstochowa, Poland
Bibliografia
  • [1] CAO D., SUN Y., WANG G.: Direct carbon fuel cell: Fundamentals and recent developments. J Power Sources 167(2007), 250-257.
  • [2] COOPER J.F.: Direct conversion of coal derived carbon in fuel cells. In: Recent Trends in Fuel Cell Science and Technology, Chap. 10 (S. Basu, Ed.), Springer and Anamaya, 2007, 248-266.
  • [3] GIDDEY S., BADWAL S.P.S., KULKARNI A., MUNNINGS C.: A comprehensive review of direct carbon fuel cell technology. Prog. Energy Combust. Sci. 38(2012), 360-399.
  • [4] ZECEVIC S., PATTON E.M., PARHAMI P.: Direct electrochemical power generation from carbon in fuel cells with molten hydroxide electrolyte. Chem. Eng. Commun. 192(2005), 1655-1670.
  • [5] PN-EN 15104:2011E - Soild biofuels... (in Polish).
  • [6] PN-G-04584:2001P - Solid fuels... (in Polish).
  • [7] PN-C-04375-2:2013-07P - Investigations of solid and liquid fuels... (in Polish).
  • [8] DIN 66133 - Determination of pore volume distribution and specific surface area of solids by mercury intrusion.
  • [9] KACPRZAK A., KOBYŁECKI R., BIS Z.: Influence of temperature and composition of NaOH-KOH and NaOH-LiOH electrolytes on the performance of a direct carbon fuel cell. J. Power Sources 239(2013), 409-414.
  • [10] KACPRZAK A., WŁODARCZYK R., KOBYŁECKI R., ŚCISŁOWSKA M., BIS Z.: Fuel cell as part of clean technologies. In: Environmental Engineering IV, (Pawłowski A., Dudzińska M.R., Pawłowski L., Eds.), CRC Press, Taylor & Francis Group, London 2013, 443-450, ISBN 978-0-415-64338-2.
  • [11] Advantech USB-4711A datasheet: http://downloadt.advantech.com/ProductFile/PIS/USB-4711A/Product%20-%20Datasheet/USB-4711A_DS20130703153611.pdf.
  • [12] Resistance setup type MDR-93/2-5a datasheet: http://www.kompartpomiar.pl/pobierz.php?plik=dok_mdr.pdf&u=dt.
  • [13] Tektronix DMM 4040 digital multimeter datasheet: http://www.tek.com/sites/tek.com/files/media/media/resources/Tektronix-DMM4050-and-DMM4040-Digital-Multimeter-Datasheet-8.pdf
  • [14] Mass flow controller Brooks 4850 datasheet: http://www.brooksinstrument.com/downloads/Product%20Documentation/Thermal%20Mass%20Flow%20Meters%20Controllers%20Digital%20Gas/Data%20Sheets/ds-tmf-4800-mfc-eng.pdf.
  • [15] Backup power device Powercom BNT 1500AP datasheet: http://www.powercomusa.com/ProductDetail.asp?ID=3978
  • [16] HACKETT G. A., ZONDLO J. W., SVENSSON R.: Evaluation of carbon materials for use in a direct carbon fuel cell. J. Power Sources 168(2007), 111-118.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-63c834c6-13d1-4d63-b99b-4091452d165e
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