Effect of surfactant concentration in modifying solution on corrosion properties of the coatings based on vinyltrimethoxysilane (VTMS) and poly(3,4-ethylenedioxythiophene) (PEDOT)

Kucharczyk, A.; Adamczyk, Lidia; Miecznikowski, K.

doi:10.5604/01.3001.0053.7475

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Tytuł artykułu

Effect of surfactant concentration in modifying solution on corrosion properties of the coatings based on vinyltrimethoxysilane (VTMS) and poly(3,4-ethylenedioxythiophene) (PEDOT)

Autorzy

Kucharczyk A. , Adamczyk Lidia , Miecznikowski K.

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DOI

10.5604/01.3001.0053.7475

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Abstrakty

Purpose: This paper presents an analysis of the structure and physicochemical properties of coatings based on an organofunctional silane (VTMS), a conductive polymer (PEDOT), and a surfactant (polyoxyethylene glycol monolauryl ether BRIJ). Design/methodology/approach The coatings were deposited on X20Cr13 stainless steel and glassy carbon specimens using sol-gel immersion. The obtained coatings were characterised in terms of topography, microstructure, roughness, adhesion to the steel substrate, thickness, and corrosion resistance. Corrosion tests were conducted in sulfate environments with pH = 2 without or with the addition of Cl- ions. Findings: The use of different surfactant concentrations in the modifying solution is intended to improve the deposition efficiency and increase the degree of dispersion of silane and conducting polymer. Research limitations/implications The tested coatings were found to slow down the corrosion of the steel substrate, thus effectively protecting it from this phenomenon. The use of a surfactant compound is intended to increase the degree of dispersion of silane and polymer in the modifying solution to improve deposition efficiency. Practical implications: Test carried out in corrosive media have shown that the coatings proposed in the above work, based on VTMS silane, PEDOT polymer and BRIJ surfactant, significantly increase the corrosion resistance of the tested materials, which confirms their effectiveness and possibility of application in various industries. Originality/value: The novelty of this paper is the use of silane (VTMS), polymer (PEDOT) and surfactant (BRIJ) as components of the anticorrosion coating.

Słowa kluczowe

vinyltrimethoxysilane poly(3,4-ethylenedioxythiophene) polyoxyethylene glycol monolauryl ether stainless steel sol-gel method

winylotrimetoksysilan poli(3,4-etylenodioksytiofen) eter monolaurylowy glikolu polioksyetylenowego stal nierdzewna metoda zol-żel

Wydawca

International OCSCO World Press

Czasopismo

Archives of Materials Science and Engineering

Rocznik

2023

Tom

Vol. 121, nr 1

Strony

5--17

Opis fizyczny

Bibliogr. 56 poz.

Twórcy

autor

Kucharczyk A.

Department of Materials Engineering, Faculty of Production Engineering and Materials Technology, Czestochowa University of Technology, Al. Armii Krajowej 19, 42-200 Częstochowa, Poland

https://orcid.org/0000-0001-6489-972X

autor

Adamczyk Lidia

lidia.adamczyk@pcz.pl

Department of Materials Engineering, Faculty of Production Engineering and Materials Technology, Czestochowa University of Technology, Al. Armii Krajowej 19, 42-200 Częstochowa, Poland

https://orcid.org/0000-0003-4811-5387

autor

Miecznikowski K.

Department of Inorganic and Analytical Chemistry, Faculty of Chemistry, University of Warsaw, ul. Ludwika Pasteura 1, 02-093 Warszawa, Poland

https://orcid.org/0000-0001-7401-5844

Bibliografia

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