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Composites that owns healing property has acquired wide range of application especially in coatings. Microcapsules embedded coatings provide both damage protection and damage management imposing itself among the sophisticated applications. Although the microcapsules coatings have spectacular aspect, their effect on coating properties still under study due the broad properties variation of microcapsules. In this work, PMMA microcapsules filled with Bisphenol-A epoxy is incorporated into epoxy coating. The coating is self-healing and can be used for anti-corrosion applications. The properties of the prepared coating were investigated via scratch test and through microhardness test and the healing process is monitored through optical microscope. The investigation shows that embedding microcapsules into epoxy matrix will achieve both in self-healing coating and better performance.
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Tom
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no. art. 2022108
Opis fizyczny
Bibliogr. 23 poz., rys., tab.
Twórcy
autor
- College of Materials Engineering, Department of Polymer Engineering and Petrochemical Industries, University of Babylon, Iraq
autor
- College of Materials Engineering, Department of Polymer Engineering and Petrochemical Industries, University of Babylon, Iraq
autor
- College of Materials Engineering, Department of Polymer Engineering and Petrochemical Industries, University of Babylon, Iraq
Bibliografia
- 1. Wang X, Yin H, Chen Z, Xia L. Epoxy resin/ethyl cellulose microcapsules prepared by solvent evaporation for repairing microcracks: Particle properties and slow-release performance. Materials Today Communications. 2020;22: 100854. https://doi.org/10.1016/j.mtcomm.2019.100854.
- 2. Zhu DY, Rong MZ, Zhang MQ. Self-healing polymeric materials based on microencapsulated healing agents: From design to preparation. Progress in Polymer Science. 2015;49-50:175-220. http://dx.doi.org/10.1016/j.progpolymsci.2015.07.002.
- 3. Hia IL, Vahedi V, Pasbakhsh P. Self-healing polymer composites: prospects, challenges, and applications. Polymer Reviews. 2016;56(2):225-261. http://dx.doi.org/10.1080/15583724.2015.1106555.
- 4. White SR, Sottos NR, Geubelle PH, Moore JS, Kessler MR, Sriram SR, et al. Autonomic healing of polymer composites. Nature. 2001;409(6873):794-797. https://doi.org/10.1038/35057232.
- 5. Lang S, Zhou Q. Synthesis and characterization of poly(urea-formaldehyde) microcapsules containing linseed oil for self-healing coating development. Progress in Organic Coatings. 2017;105:99-110. http://dx.doi.org/10.1016/j.porgcoat.2016.11.015.
- 6. Huang M, Yang J. Salt spray and EIS studies on HDI microcapsule-based self-healing anticorrosive coatings. Progress in Organic Coatings. 2014;77(1): 168-175. http://dx.doi.org/10.1016/j.porgcoat.2013.09.002.
- 7. Li Q, Siddaramaiah, Kim NH, Hui D, Lee JH. Effects of dual component microcapsules of resin and curing agent on the self-healing efficiency of epoxy. Composites Part B: Engineering. 2013;55:79-85.
- 8. Pittala RK, Ben BS. Synthesis and characterization of amine hardener filled microcapsules for selfhealing composite applications. Materials Research Express. 2019;6(11). https://doi.org/10.1088/2053-1591/ab4734.
- 9. He Z, Jiang S, Li Q, Wang J, Zhao Y, Kang M. Facile and cost-effective synthesis of isocyanate microcapsules via polyvinyl alcohol-mediated interfacial polymerization and their application in self-healing materials. Composites Science and Technology. 2017;138:15-23. http://dx.doi.org/10.1016/j.compscitech.2016.11.004.
- 10. Szabó T, Molnár-Nagy L, Bognár J, Nyikos L, Telegdi J. Self-healing microcapsules and slow release microspheres in paints. Progress in Organic Coatings. 2011;72(1-2):52-57.
- 11. Patchan MW, Fuller BW, Baird LM, Gong PK, Walter EC, Vidmar BJ, et al. Robust composite-shell microcapsules via pickering emulsification. ACS Applied Materials and Interfaces. 2015;7(13):7315-7323. https://doi.org/10.1021/acsami.5b00494.
- 12. Zheng N, Qiao L, Liu J, Lu J, Li W, Li C, et al. Microcapsules of multilayered shell structure synthesized via one-part strategy and their application in self-healing coatings. Composites Communications. 2019;12:26-32. https://doi.org/10.1016/j.coco.2018.12.006.
- 13. Lee Hia I, Chan ES, Chai SP, Pasbakhsh P. A novel repeated self-healing epoxy composite with alginate multicore microcapsules. Journal of Materials Chemistry A. 2018;6(18):8470-8478.
- 14. Ahangaran F, Hayaty M, Navarchian AH, Picchioni F. Micromechanical assessment of PMMA microcapsules containing epoxy and mercaptan as self-healing agents. Polymer Testing. 2017;64:330-336. https://doi.org/10.1016/j.polymertesting.2017.10.014.
- 15. Liang B, Zhong Z, Jia E, Zhang G, Su Z. Transparent and scratch-resistant antifogging coatings with rapid self-healing capability. ACS Applied Materials and Interfaces. 2019;11(33):30300-7. https://doi.org/10.1021/acsami.9b09610.
- 16. Wang H, Zhou Q. Evaluation and failure analysis of linseed oil encapsulated self-healing anticorrosive coating. Progress in Organic Coatings. 2018;118: 108-115. https://doi.org/10.1016/j.porgcoat.2018.01.024.
- 17. Wong MHH-JS. The development of scratch test methodology and characterization of surface damage of polypropylene. Texas A &M University. 2003; 101.
- 18. Bengisu M. Properties of ceramic materials and their evaluation. in: engineering ceramics. Berlin, Heidelberg: Springer Berlin Heidelberg, 2001:209-362. https://doi.org/10.1007/978-3-662-04350-9_4.
- 19. Li Q, Mishra AK, Kim NH, Kuila T, Lau KT, Lee JH. Effects of processing conditions of poly (methylmethacrylate) encapsulated liquid curing agent on the properties of self-healing composites. Composites Part B: Engineering. 2013;49:6-15.
- 20. Khan NI, Halder S, Goyat MS. Effect of epoxy resin and hardener containing microcapsules on healing efficiency of epoxy adhesive based metal joints. Materials Chemistry and Physics. 2016;171:267-275. https://doi.org/10.1016/j.matchemphys.2016.01.017.
- 21. Maity P, Kasisomayajula SV, Parameswaran V, Basu S, Gupta N. Improvement in surface degradation properties of polymer composites due to pre-processed nanometric alumina fillers. IEEE Transactions on Dielectrics and Electrical Insulation. 2008;15(1):63-72.
- 22. Romão BMV, Diniz MF, Azevedo MFP, Lourenço VL, Pardini LC, Dutra RCL, et al. Characterization of the curing agents used in epoxy resins with TG/FT-IR technique. Polimeros. 2006;16(2):94-98.
- 23. Delor-Jestin F, Drouin D, Cheval PY, Lacoste J. Thermal and photochemical ageing of epoxy resin - Influence of curing agents. Polymer Degradation and Stability. 2006;91(6):1247-1255.
Uwagi
Opracowanie rekordu ze środków MEiN, umowa nr SONP/SP/546092/2022 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2022-2023).
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Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-63a74120-3d6d-4451-98d3-b6bc9fdec8e7