Hydrothermal ore mineralization from the Polish part of the Tatra Mts., Central Western Carpathians

• Autorzy: Sitarz Magdalena , Gołębiowska Bożena , Nejbert Krzysztof , Dimitrova Dimitrina , Milovský Ratislav

Identyfikatory

DOI

10.7494/geol.2021.47.3.159

• Języki publikacji: EN

Abstrakty

EN

Several areas with hydrothermal ore mineralization are present in the Polish part of the Western Tatra Mts. Massive and disseminated sulfides, mainly minerals from the tetrahedrite group and chalcopyrite, fill quartz veins accompanied by siderite, dolomite and baryte – many of these were mined between the 16th and 18th century. This paper presents information on the mineralogy of the common sulfides and the preliminary studies of both the isotopic composition of sulfur in tetrahedrite as well as the origin of hydrothermal fluids. The most common primary sulfide minerals in the ores are tetrahedrite-(Zn) and tetrahedrite-(Fe) corresponding to Zn ranges from 1.83 to 5.87 wt.% (0.47–1.44 apfu), and Fe from 1.63 to 5.05 wt.% (0.48–1.52 apfu). The substitution of As for Sb shows maximum As content of 7.25 wt.% (1.588 apfu) which corresponds to the Sb/(Sb+As) = 0.60. Both varieties show substitutions of Bi and Hg, up 0.6 wt.% (0.049 apfu) and 0.96 wt.% (0.081 apfu), respectively, and content of trace elements: Co (max. 976 ppm), Cd (max. 735 ppm), In (max. 14 ppm). Chalcopyrite, pyrite, and galena show compositions close to the ideal formula. Differences in the content of trace elements in the studied tetrahedrite and chalcopyrite were explained by element partitioning between these minerals. The distributions of In, Ga and Sn in the studied minerals indicate that the mineralization was formed at low temperature and pressure. The homogenization temperature of the primary inclusions in quartz in the range of 120–174°C indicate the origin of mineralization in low temperature stage from low salinity fluids (up to 17.92 wt.% NaCl eq.). Stable δ34S isotopes in minerals of the tetrahedrite group suggest that the igneous fluids might be one of the sources from which ores were crystallized.

Słowa kluczowe

EN

tetrahedrite; hydrotherma ore mineralization; fluid inclusions; LA-ICP-MS study; Tatric Superunit; Polish part of the Western Tatra Mts.; Poland

• Wydawca: Wydawnictwa AGH
• Czasopismo: Geology, Geophysics and Environment
• Rocznik: 2021
• Tom: Vol. 47, no. 3
• Strony: 159--179
• Opis fizyczny: Bibliogr. 42 poz., rys., tab., wykr.

Twórcy

autor

Sitarz Magdalena

• Tatra National Park, Zakopane, Poland
• AGH University of Science and Technology, Department of Mineralogy, Petrography and Geochemistry, Krakow, Poland

autor

Gołębiowska Bożena

• AGH University of Science and Technology, Department of Mineralogy, Petrography and Geochemistry; Krakow, Poland

• https://orcid.org/0000-0002-4103-1124

autor

Nejbert Krzysztof

• University of Warsaw, Institute of Geochemistry, Mineralogy and Petrology; Warsaw, Poland

• https://orcid.org/0000-0002-0021-2172+

autor

Dimitrova Dimitrina

• Geological Institute, Bulgarian Academy of Sciences; 1113 Sofia, Bulgaria

• https://orcid.org/0000-0001-8008-394X

autor

Milovský Ratislav

• Slovak Academy of Sciences, Earth Science Institute; Banská Bystrica, Slovakia

• https://orcid.org/0000-0003-1880-865X

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Uwagi

Opracowanie rekordu ze środków MNiSW, umowa Nr 461252 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2021).