Improved SPE-UPLC-UV-based method for the simultaneous determination of triclocarban and triclosan in wastewater

• Autorzy: Li P. , Liu X. , Wang X.
• Języki publikacji: EN

Abstrakty

EN

Triclocarban (TCC) and triclosan (TCS) are used in a wide range of household and personal care products and have been the most frequently detected organic pollutants in both wastewater and surface water. This paper presented a rapid analytical method for simultaneous determination of TCC and TCS in wastewater. The method involves the extraction and cleanup of the target compounds by using silicon dioxide/polystyrene composite microspheres solid-phase extraction and detection with ultra-high-pressure liquid chromatography. Under the optimized conditions, the limits of detection were 0.028 μg/L and 0.040 μg/L for TCC and TCS, respectively. Under the concentrations of the spiking level ranging from 0.100 μg/L to 2.000 μg/L, the spiked recoveries of TCC and TCS in wastewater samples achieved in the range of 89.5–102.8% with RSD below 6.3% for TCC and 95.5–103.6% with RSD below 6.9% for TCS. This method was successfully used in monitoring the water samples from three traditional wastewater treatment plants.

Słowa kluczowe

EN

triclocarban; triclosan; determination; solid-phase extraction; ultra-high-pressure liquid chromatography

• Wydawca: University of Silesia in Katowice ; Akademiai Kiado
• Czasopismo: Acta Chromatographica
• Rocznik: 2015
• Tom: Vol. 27, no. 2
• Strony: 255--266
• Opis fizyczny: Bibliogr. 28 poz., rys., tab.

Twórcy

autor

Li P.

• Qilu University of Technology School of Light Chemistry and Environmental Engineering Jinan 250353 China

autor

Liu X.

• Jinan Water Group Company Limited Jinan 250018 China

autor

Wang X.

• Qilu University of Technology School of Light Chemistry and Environmental Engineering Jinan 250353 China

Bibliografia

• [1] D.R. Orvos, D.J. Versteeg, J. Inauen, M. Capdeveille, A. Rothenstein, and V. Cunningham, Environ. Toxicol. Chem., 21, 1338–1349 (2002)
• [2] E. Engelhaupt, Environ. Sci. Technol., 42, 8179–8186 (2008)
• [3] C. Ponte, J. Richard, C. Bonte, P. Lequien, and A. Lacombe, Semaine Des Hopitaux, 50, 359–365 (1974)
• [4] K.C. Ahn, B. Zhao, J. Chen, G. Cheredenichenko, E. Sanmarti, M.S. Denision, B.L. Lasley, I.N. Pessah, D. Kültz, D.P.Y. Chan, S. J. Gee, and B. D. Hammock, Environ. Health Persp., 116, 1203–1210 (2008)
• [5] A. Hinther, C. M. Bromba, J. E. Wulff, and C. C. Helbing, Environ. Sci. Technol., 45, 5395–5402 (2011)
• [6] M.A. Coogan, R.E. Edziyie, T.W. La Point, and B.J. Venable, Chemosphere, 67, 1911–1918 (2007)
• [7] M.A. Coogan and T.W. La Point, Environ. Toxicol. Chem., 27, 1788–1793 (2008)
• [8] R. U. Halden and D. H. Paull, Environ. Sci. Technol., 38, 4849–4855 (2004)
• [9] S. Chu and C.D. Metcalfe, J. Chromatogr. A, 1164, 212–218 (2007)
• [10] J.H. Guo, X.H. Li, X. L. Cao, Y. Li, X. Z. Wang, and X. B. Xu, J. Chromatogr. A, 1216, 3038–3043 (2009)
• [11] R. S. Zhao, X. Wang, J. Sun, C.Hu, and X.K. Wang, Microchim. Acta, 174, 145–151 (2011)
• [12] P. Canosa, D. Pérez-Palacios, A. Garrido-López, T.M. Tena, I. Rodríguez, E. Rubi, and R. Cela, J. Chromatogr.A,1161, 105–112 (2007)
• [13] A. Sapkota, J. Heidler, and R.U. Halden, Environ. Res., 103, 21–29 (2007)
• [14] R. Montes, I. Rodríguez, E. Rubí, and R. Cela, J. Chromatogr. A, 1072, 107–115 (2005)
• [15] R.S. Zhao, J. P. Yuan, H. F. Li, X. Wang,T. Jiang, and J.M. Lin, Anal. Bioanal. Chem., 387, 2911–2915 (2007)
• [16] M. Kawaguchi, R. Ito, H. Honda, N. Endo, N. Okanouchi, K. Saito, Y. Seto, and H. Nakazawa, J. Chromatogr. A,1206, 196–199 (2008)
• [17] J.Y. Shen, M.S. Chang, S.H. Yang, and G.J. Wu, J. Sep. Sci., 35, 2544–2552 (2012)
• [18] J.B. Quintana and T. Reemtsma, Rapid Comm. Mass Spectrom., 18, 765–774 (2004)
• [19] J. Sun, C.L. Yi, R.S. Zhao, X. Wang, W. Q. Jiang, and X.K. Wang, J. Sep. Sci., 35, 2781–2786 (2012)
• [20] S. C. Shen, J. N. Bi, L. L. Sui, and Y. H. Liu, Chin. J. Anal. Lab., 31, 51–54 (2012)
• [21] W. Boehmer, H. Ruedel, A. Wenzel, and C. Schroeter-Kermani, Organohalogen Comp., 66, 1516–1521 (2004)
• [22] Z. Han, Y. Zheng, N. Chen, L. Luan, C. Zhou, L. Gan, and Y. Wu, J. Chromatogr. A, 1212, 76-81 (2008)
• [23] The quality assurance manual for environmental water monitoring, China National Environmental Monitoring Station Eds, Chemical Industry Press, 2000, Beijing
• [24] J. Heidler, A. Sapkota, and R.U. Halden, Environ. Sci. Technol., 40,3634-3639 (2006)
• [25] R.U. Halden and D.H. Paull, Environ. Sci. Technol., 39, 1420–1426 (2005)
• [26] G. G. Ying and R. S. Kookana, Environ. Int., 33, 199–205 (2007)
• [27] I. Nishi, T. Kawakami, S. Onodera, Bull. Environ. Contam. Toxicol., 80, 163–166 (2008)
• [28] M. Pedrouzo, F. Borrull, R.M. Marce, E. Pocurull, J. Chromatogr. A, 1216, 6994–7000 (2009)