Source rock geochemistry, petrography of reservoir horizons and origin of natural gas in the Devonian of the Lublin and Lviv basins (SE Poland and western Ukraine)

Radkovets, N. Y.; Kotarba, M. J.; Wójcik, K.

doi:10.7306/gq.1361

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Tytuł artykułu

Source rock geochemistry, petrography of reservoir horizons and origin of natural gas in the Devonian of the Lublin and Lviv basins (SE Poland and western Ukraine)

Autorzy

Radkovets N. Y. , Kotarba M. J. , Wójcik K.

Treść / Zawartość

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Radkovets_N_Source_Geol. Quart._Vol. 61_No 3_2017.pdf

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DOI

10.7306/gq.1361

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Abstrakty

The Rock-Eval source rock characteristics, mineral composition and type-porosity of reservoir horizons, and origin of natural gas in the Devonian of the Lublin and Lviv basins are described. In the Lower Devonian, the TOC content ranges from 0.01 to 1.82 wt.% in the Lublin Basin, and from 0.01 to 0.45 wt.% in the Lviv Basin. Transformation of organic matter varies from immature in the Lochkovian (Lviv Basin) to mature and overmature in the Emsian (Lublin Basin). The organic matter contains mainly Type-II kerogen, and underwent primary and/or secondary oxidation processes. In the Middle Devonian, the TOC content varies from 0.00 to 1.63 wt.% in the Lublin Basin, and from 0.02 to 0.64 to 2.35 wt.% in the Lviv Basin. The organic matter contains mainly Type-II kerogen and is immature in the Givetian of the Lviv Basin and mature in the Eifelian of the Lviv Basin and in the Eifelian and Givetian in the Lublin Basin. In the Upper Devonian, the TOC content is from 0.02 to 2.62 wt.% in the Lublin Basin, and from 0.04 to 1.43 wt.% in the Lviv Basin. Type-II kerogen dominates in both basins. Organic matter is mature in the Upper Devonian in the Lublin Basin and in the Famennian of the Lviv Basin and overmature in the Frasnian of the Lviv Basin. The reservoir horizons in the Devonian of the Lublin and Lviv basins are developed in clastic, carbonate and sulphate rocks. Terrigenous rocks form several separate horizons in the Lower and Middle Devonian of the Lviv Basin, and in the Upper Devonian (Famennian) of the Lublin Basin. Their filtration properties relate to intergranular porosity, while the fracture space has subordinate significance. Carbonate rocks form thick saturated horizons in the Givetian in the Lviv Basin, and in the Eifelian, Givetian and Frasnian in the Lublin Basin. Their filtration properties are produced by fracture porosity. Sulphates and carbonate-sulphate rocks with fracture and cavern porosity play a role as reservoir horizons in the Middle Devonian of the Lublin Basin. The natural gas collected from the Upper Devonian of the Lublin Basin was generated mainly during low-temperature thermogenic processes, from Ordovician–Silurian Type-II kerogen. The gas from the Middle Devonian reservoirs of the Lviv Basin was produced from Ordovician–Silurian Type-II kerogen and partly from the Middle and Upper Devonian mixed Type-III/II kerogen with maturity from about 0.9 to 1.4%. Carbon dioxide was formed by both thermogenic and microbial processes. Molecular nitrogen was generated mainly through thermal transformation of organic matter and also from destruction of NH_4-rich illite of the clayey facies of the Ordovician–Silurian strata.

Słowa kluczowe

Devonian Lublin Basin Lviv Basin Rock-Eval pyrolysis petrography isotope geochemistry

Wydawca

Państwowy Instytut Geologiczny - Państwowy Instytut Badawczy

Czasopismo

Geological Quarterly

Rocznik

2017

Tom

Vol. 61, No. 3

Strony

569--589

Opis fizyczny

Bibliogr. 75 poz., rys., tab., wykr.

Twórcy

autor

Radkovets N. Y.

radkov_n@ukr.net

National Academy of Sciences of Ukraine, Institute of Geology and Geochemistry of Combustible Minerals, Naukova 3a, 79060 Lviv, Ukraine

autor

Kotarba M. J.

AGH University of Science and Technology, Faculty of Geology, Geophysics and Environmental Protection, al. Mickiewicza 30, 30-059 Kraków, Poland

autor

Wójcik K.

Polish Geological Institute - National Research Institute, Rakowiecka 4, 00-975 Warsaw, Poland

Bibliografia

1. Bernard, B.B., Brooks, J.M., Sackett, W.M., 1976. Natural gas seepage in the Gulf of Mexico. Earth and Planetary Science Letters, 31: 48-54.
2. Berner, U., Faber, E., 1996. Empirical carbon isotope/maturity relationships for gases from algal kerogens and terrigenous organic matter, based on dry, open-system pyrolysis. Organic Geochemistry, 24: 947-955.
3. Berner, U., Faber, E., 1997. Carbon isotope/maturity relationships for gases from algal kerogens and terrigenous organic matter. Geologisches Jahrbuch, D 103: 129-145.
4. Chebanenko, 1.1., Vishsnyakov, I.B., Vlasov, B.I., 1990. Geotektonika Volyno-Podolii (in Russian). Naukova Dumka, Kiev.
5. Chung, H.M., Gormly, J.R., Squires, R.M., 1988. Origin of gaseous hydrocarbons in subsurface environments: theoretical considerations of carbon isotope distribution. Chemical Geology, 71: 91-103.
6. Coleman, M. L., Shepherd, T.J., Durham, J.J., Rouse, J.E., Moore, G.R., 1982. Reduction of water with zinc for hydrogen isotope analysis. Analytical Chemistry, 54: 993-995.
7. Coplen, T.B., 2011. Guidelines and recommended terms for expression of stable-isotope-ratio and gas-ratio measurement results. Rapid Communications in Mass Spectrometry, 25: 2538-2560.
8. Dai, J., Song, Y., Dai, C., Wang, D., 1996. Geochemistry and accumulation of carbon dioxide gases in China. AAPG Bulletin, 80: 1615-1626.
9. Espitalié, J., Deroo, G., Marquis, F., 1985. La pyrolyse Rock-Eval et ses applications. Revue de l'Institut Franęais du Pétrole, 40-41: 563-579 and 755-784.
10. Fedyshyn, V.O. 1998. Atlas of Oil and Gas Fields of Ukraine. Ukrainian Oil and Gas Academy, Lviv.
11. Fischer, M., Botz, R., Schmidt, M., Rockenbauch, K., Garbe-Schonberg, D., Glodny, J., Gerling, P., Littke, R., 2006. Origins of CO2 in Permian carbonate reservoir rocks (Zechstein, Ca2) of the NW-German Basin (Lower Saxony). Chemical Geology, 227: 184-213.
12. Florkowski, T., 1985. Sample preparation for hydrogen isotope analysis by mass spectrometry. International Journal of Applied Radiation and Isotopes, 36: 991-992.
13. Galabuda, M., Krupskiy, Y., Pavlyuk, Î., Chepil, P., 2007. History of investigation of geological structure and oil and gas bearing perspectives of Volyno-Podillya (in Ukrainian with English abstract). Geologiya i Geokhimiya Goryuchykh Kopalyn, (3): 5-18.
14. Garbacik, Z., 1989. Dokumentacja wynikowa odwiertu poszukiwawczego: Glinnik-2 (in Polish). NAG PIG, Warszawa (Inw. 131902).
15. Gerling, P., Idiz, E., Everlien, G., Sohns, E., 1997. New aspects on the origin of nitrogen in natural gas in Northern Germany. Geologisches Jahrbuch, D103: 65-84.
16. Gutsalo, L.K., Plotnikov, A.M., 1981 Izotopnyi sostav ugleroda v sistemie CH4-CO2 kak kriteriy proiskhozhdeniya metana i dvuokisi ugleroda v prirodnykh gazakh Zemli (in Russian). Doklady Akademyi Nauk SSSR, 259: 470-473.
17. Helcel-Weil, M., Dzięgielowski, J., 2003. Lublin Basin - petroleum prospecting results and their importance for future exploration. Przegląd Geologiczny, 51: 764-770.
18. Helcel-Weil, M., Dzięgielowski, J., Florek, R., Maksym, A., Słyś, M., 2007. The Lublin Basin: petroleum exploration results and their importance for future prospects (in Polísh with English summary). Biuletyn Państwowego Instytutu Geologicznego, 411: 51-62.
19. Hinrichs, K-U., Hayes, J.M., Bach, W., Spivack, A.J., Hmelo, L.R., Holm, N.G., Johnson, C.G., Sylva, S.P., 2006. Biological formation of ethane and propane in the deep marine sediments. Proceedings of the National Academy of Sciences, 103: 14684-14689.
20. Hutcheon, I., Abercrombie, H., 1990. Carbon dioxide in clastic rocks and silicate hydrolysis. Geology, 18: 541-544.
21. Jenden, P.D., Hilton, D.R., Kaplan, I.R., Craig, H., 1993. Abiogenic hydrocarbons and mantle helium in oil and gas fields. U.S. Geological Survey Professional Papers, 1570: 31-56.
22. Karnkowski, P., 1999. Oil and Gas Deposits in Poland. Ed. Geological Society “Geos”, Kraków.
23. Khizhniakov, A.V., 1975. O perspektivakh poiskov nefti i gaza vo Lvovskom progibe (in Russian). In: Zakonomernosti obrazovaniya i razmieshcheniya promyshlennykh mestorozhdeniy nefti i gaza. Naukova Dumka, Kiev.
24. Kosakowski, P., Więcław, D., Kotarba, M.J., Kowalski, A., 2012a. Hydrocarbon potential of the Mesozoic strata between Kraków and Rzeszów (SE Poland). Geological Quarterly, 56 (1): 139-152.
25. Kosakowski, P., Więcław, D., Kowalski, A., Koltun, Y.V., 2012b. Hydrocarbon potential of the Jurassic and Cretaceous source rocks between Tarnogród and Stryi (SE Poland and western Ukraine). Geologica Carpathica, 63: 319-333.
26. Kotarba, M., 1988. Geochemical criteria for origin of natural gases accumulated in the Upper Carboniferous coal-seam-bearing formations in Wałbrzych Coal Basin (in Polish with English summary). Zesz. Nauk. Akad. Górn.-Hutn. (Academy Mining and Metallurgy Bulletin), Geologia (Geology), 42: 1-119.
27. Kotarba, M.J., 2012. Origin of natural gases in the Paleozoic-Mesozoic basement of the Polish Carpathian Foredeep. Geologica Carpathica, 63: 307-318.
28. Kotarba, M.J., Lewan, M.D., 2004. Characterizing thermogenic coalbed gas from Polish coals of different ranks by hydrous pyrolysis. Organic Geochemistry, 35: 615-646.
29. Kotarba, M.J., Lewan, M.D., 2013. Sources of natural gases in Middle Cambrian reservoirs in Polish and Lithuanian Baltic Basin as determined by stable isotopes and hydrous pyrolysis of Lower Palaeozoic source rocks. Chemical Geology, 345: 62-76.
30. Kotarba, M.J., Rice, D.D., 2001. Composition and origin of coalbed gases in the Lower Silesian Basin, northwestern Poland. Applied Geochemistry, 16: 895-910.
31. Kotarba, M.J., Kosakowski, P., Kowalski, A., Więcław, D., 1998. Preliminary geochemical characteristics of organic matter and hydrocarbon potential of the Devonian deposits in the Radom-Lublin and Pomerania areas (in Polish with English summary) Prace Państwowego Instytutu Geologicznego, 165: 207-214.
32. Kotarba, M.J., Więcław, D., Kosakowski, P., Zacharski, J., Kowalski, A., 2003. Evaluation of source rock and petroleum potential of Middle Jurassic strata in the south-eastern part of Poland (in Polish with English abstract). Przegląd Geologiczny, 51: 1031-1040.
33. Kotarba, M.J., Więcław, D., Kosakowski, P., Kowalski, A., Kowalski, T., 2005. Skały macierzyste (in Polish). In: Lokalizacja geologiczna i system naftowy w basenie lubelskim oraz perspektywy poszukiwawcze (ed. M. Narkiewicz). Unpublished report, Archive of Polish Geological Institute - National Research Institute, Warsaw, Chapter 6A: 48 p.
34. Kotarba, M.J., Curtis, J.B., Lewan, M.D., 2009. Comparison of natural gases accumulated in Oligocene strata with hydrous pyrolysis gases from Menilite Shales of the Polish Outer Carpathians. Organic Geochemistry, 40: 769-783.
35. Kotarba, M.J., Więcław, D., Kosakowski, P., Wróbel, M., Buła, Z., Matyszkiewicz, J., Krajewski, M., Kowalski, A., Koltun, Y.V., 2011. Petroleum systems and prospectives of hydrocarbon exploration in the Palaeozoic-Mesozoic basement (SE Poland and western Ukraine). Annales Societatis Geologorum Poloniae, 81: 487-522.
36. Krooss, B.M., Littke, R., Muller, B., Frielingsdorf, J., Schwochau, K., Idiz, E.F., 1995. Generation of nitrogen and methane from sedimentary organic matter: implications on the dynamics of natural gas accumulations. Chemical Geology, 126: 291-318.
37. Krooss, B.M., Friberg, L., Gensterblum, Y., Hollenstein, J., Prinz, D., Littke, R., 2005. Investigation of the pyrolytic liberation of molecular nitrogen from Paleozoic sedimentary rocks. International Journal of Earth Sciences, 94: 1023-1038.
38. Kruglov, C.C., Tsypko, A.K., 1988. Tektonika Ukrainy (in Russian). Nedra, Moscow.
39. Krupskiy, J.Z., 2001. Geodynamic conditions of forming and oil and gas bearing of Carpathian and Volyno-Podillya regions of Ukraine (in Ukrainian with English abstract). UkrDGRI, Kiev.
40. Krupskiy, J.Z., Kurovets, I.M., Senkovskiy, J.M., Michailov, W.A., Chepil, P.M., Drygant, D.M., Shlapinskiy, W.E., Koltun, J.W., Chepil, W.P., Kurovets, S.S., Bodlak, W.P., 2014. Netradytsiyni dzherela vuglevodniv v Ukrayiny (in Ukrainian). Book II: Western gas-bearing region. Nika-Centre, Kiev.
41. Krzywiec, P., Mazur, S., Gągała, Ł, Kufrasa, M., Lewandowski, M., Malinowski, M., Buffenmyer, V., 2017. Late Carboniferous thin-skinned compressional deformation above the SW edge of the East European Craton as revealed by reflection seismic and potential fields data - correlations with the Variscides and the Appalachians. GSA Memoir, 213: 1-20, doi:10.1130/2017.1213(14).
42. Lillis, P.G., 2007. Upper Cretaceous microbial petroleum systems in north-central Montana. The Mountain Geologist, 44: 11-35.
43. Littke, R., Krooss, B.M., Idiz, E.F, Frielingsdorf, J., 1995. Molecular nitrogen in natural gas accumulations: generation from sedimentary organic matter at high temperatures. AAPG Bulletin, 79: 410-430.
44. Lüders, V., Reutel, Ch., Hoth, P., Banks, D.A., Mingram, B., Pettke, T., 2005. Fluid and gas migration in the North German Basin: fluid inclusion and stable isotope constrains. International Journal of Earth Sciences, 94: 990-1009.
45. Medvedyev, A.P., 1979. Priroda doalpiyskoy struktury Volyno-Podolii i smezhnykh rayonov (in Russian). Naukova Dumka, Kiev.
46. Miłaczewski, L., 1981. The Devonian of the south-eastern part of the Radom-Lublin area (in Polish with English summary). Prace Instytutu Geologicznego, 51: 1-90.
47. Miłaczewski, L., 2010. Lithofacies-paleothickness maps of Mid dle Devonian, Frasnian and Famennian, 1:200,000. In: Paleogeological Atlas of the sub-Permian Paleozoic of the East-European Craton in Poland and Neighboring Areas (ed. Z. Modliński). Państwowy Instytut Geologiczny - Państwowy Instytut Badawczy, Warszawa.
48. Milkov, A.V., 2011. Worldwide distribution and significance of secondary microbial methane formed during petroleum biodegradation in conventional reservoirs. Organic Geochemistry, 42: 184-207.
49. Mingram, B., Hoth, P., Luders, V., Harlov, D., 2005. The significance of fixed ammonium in Palaeozoic sediments for the generation of nitrogen-rich natural gases in the North German Basin. International Journal of Earth Sciences, 94: 1010-1022.
50. Modzelewski, R., 1999. Dokumentacja geologiczna złoża gazu ziemnego Ciecierzyn (in Polish). NAG PIG, Warszawa (Inw. 2501/2000).
51. Narkiewicz, M., 2007. Development and inversion of Devonian and Carboniferous basins in the eastern part of the Variscan foreland (Poland). Geological Quarterly, 51 (3): 231-256.
52. Narkiewicz, M., 2011. Lithostratigraphy, depositional systems and transgressive-regressive cycles in the Devonian of the Lublin Basin (south-eastern Poland) (in Polish with English summary). Prace Państwowego Instytutu Geologicznego, 196: 53-146.
53. Narkiewicz, M., Narkiewicz, K., Turnau, E., 2011. Devonian depositional development of the Łysogóry-Radom and Lublin Basins (South-eastern Poland) (in Polish with English summary). Prace Państwowego Instytutu Geologicznego, 196: 289-318.
54. Narkiewicz, M., Maksym, A. , Malinowski , M. , Grad , M. , Guterch, A. , Petecki , Z. , Probulski , J. , Janik, T. , Majdański , M., Środa, P., Czuba, W., Gaczyński, E., Jankowski, L., 2015. Transcurrent nature of the Teisseyre-Tornquist Zone in Central Europe: results of the POLCRUST-01 deep reflection seismic profile. International Journal of Earth Sciences, 104: 775-796.
55. Peters, K.E, Cassa, M.R., 1994. Applied source rock geochemistry. AAPG Memoir, 60: 93-120.
56. Pomyanovskaya, G.M., 1974. The Volyn-Podolian outskirt of the East-European Platform (in Russian with English summary). In: Stratigraphy of the Ukrainian SSR, 4, Part 2, Devonian: 36-120. Naukova Dumka, Kiev.
57. Pożaryski, W., Dembowski, Z., 1983. Mapa geologiczna Polski i krajów ościennych bez utworów kenozoicznych, mezozoicznych i permskich, 1:1 000 000 (in Polish). Instytut Geologiczny, Warszawa.
58. Radkovets, N., 2015. The Silurian of southwestern margin of the East European Platform (Ukraine, Moldova and Romania): lithofacies and palaeoenvironments. Geological Quarterly, 59 (1): 105-118.
59. Radkovets, N., 2016. Lower Devonian lithofacies and palaeoenvironments in the southwestern margin of the East European Platform (Ukraine, Moldova and Romania). Estonian Journal of Earth Sciences, 65: 207-220.
60. Rooney, M.A., Claypool, G.E., Chung, H.M., 1995. Modeling thermogenic gas generation using carbon isotope ratios of natural gas hydrocarbons. Chemical Geology, 126: 219-232.
61. Rzeźnik, M., 2012. Dodatek nr 1 do dokumentacji geologicznej złoża ropy naftowej “Glinnik” w kat. B w miejsc. Amelin, Meszno (in Polish). NAG PIG, Warszawa (Inw. 972/2013).
62. Schoell, M., 1988. Multiple origins of methane in the Earth. Chemical Geology, 71: 1-10.
63. Smith, J.T., Ehrenberg, S.N., 1989. Correlation of carbon dioxide abundance with temperature in clastic hydrocarbon reservoirs: relationship to inorganic chemical equilibrium. Marine and Petroleum Geology, 6: 129-135.
64. Stachurski, Z., Karnkowski, K., Kruczak, E., 1985. Dokumentacja wynikowa otworu badawczego : Ciecierzyn-1. NAG PIG, Warszawa (Inw. 129693).
65. Stahl, W., 1977. Carbon and nitrogen isotopes in hydrocarbon research and exploration. Chemical Geology, 20: 121-149.
66. Vashchenko, V.O., Turchynova, S.M., Turchynov, 1.1., Poliha, G.G. , 2007 . Derzhavna geologichna karta Ukrainy mashtabu 1:200 000 . Karpatska seria . Arkush M-35-XXV (Ivano-Frankivsk) (in Ukrainian). UkrDGRI, Kiev.
67. Whiticar, M.J., 1994. Correlation of natural gases with their sources. AAPG Memoir, 60: 261-283.
68. Whiticar, M.J., Faber, E., Schoell, M., 1986. Biogenic methane formation in marine and freshwater environments: CO2 reduction vs. acetate fermentation-Isotope evidence. Geochimica et Cosmochimica Acta, 50: 693-709.
69. Więcław, D., Kotarba, M.J. , Kowalski , A. , Kosakowski , P. , 2011. Habitat and hydrocarbon potential of the Palaeozoic source rocks in the Kraków-Rzeszów area (SE Poland). Annales Societatis Geologorum Poloniae, 81: 375-394.
70. Więcław, D., Kosakowski, P., Kotarba, M.J., Kowalski, A., Koltun , Y.V. , 2012 . Assessment of hydrocarbon potential of the Lower Palaeozoic strata in the Tarnogród-Stryi area (SE Poland and western Ukraine). Annales Societatis Geologorum Poloniae, 82: 65-80.
71. Zhang, T., Zhang, M., Bai, B., Wang, X., Li , L. , 2008 . Origin and accumulation of carbon dioxide in the Huanghua depression, Bohai Bay Basin, China. AAPG Bulletin, 92: 341-358.
72. Zhu, Y., Shi, B., Fang, C., 2000. The isotopic compositions of molecular nitrogen: implications on their origins in natural gas accumulations. Chemical Geology, 164: 321-330.
73. Zou, Y.-R., Cai, Y., Zhang, Ch., Zhang, X., Peng, P. , 2007 . Variations of natural gas carbon isotope-type curves and their interpretation - A case study. Organic Geochemistry, 38: 1398-1415.
74. Żelichowski, A., 1972. Evolution of the geological structure of the area between the Góry Świętokrzyskie and the river Bug (in Polish with English summary). Biuletyn Instytutu Geologicznego, 263: 1-97.
75. Żelichowski, A., Kozłowski, S., 1983. Atlas of the Geological Structure and Mineral Deposits in the Lublin Region. Wyd. Geol., Warszawa.

Uwagi

Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę (zadania 2017).

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