Synthesis and Electrochemical Properties of N-(ferrocenylmethyl)aminobenzonitrile and N-(ferrocenylmethyl)nitroaniline Derivatives

• Autorzy: Boubekri C. , Khelef A. , Terki B. , Lanez T.

Identyfikatory

DOI

10.18052/www.scipress.com/ILCPA.49.27

• Języki publikacji: EN

Abstrakty

EN

Seven novel ferrocene derivatives containing (methylamino)benzonitrile and N-methylnitroaniline groups (3a-3f and 4) have been synthesized by conventional methods and characterized by FT-IR, NMR and cyclic voltammetry. The electrochemical behavior of these compounds (3a-3f) has been studied by cyclic voltammetry measurements at a platinum electrode in acetonitrile/0.1 M TBAP. The ferrocenyl group in all compounds showed similar reversible one-electron redox process, suggesting that the ferrocene moieties are equivalent and that there are no interactions among them. The formal potential, , is shifted to the more positive potential, indicating that the (methylamino)benzonitrile and N-methylnitroaniline introduced to ferrocene moiety exercise an electron-withdrawing effect.

Słowa kluczowe

EN

cyclic voltammetry; ferrocene derivative; synthesis

• Wydawca: Przedsiębiorstwo Wydawnictw Naukowych "DARWIN"
• Czasopismo: International Letters of Chemistry, Physics and Astronomy
• Rocznik: 2015
• Tom: Vol. 49
• Strony: 27--34
• Opis fizyczny: Bibliogr. 20 poz., rys., wz., tab.

Twórcy

autor

Boubekri C.

• VPRS Laboratory, University of Ouargla, B.P.511, 30000, Ouargla, Algeria

autor

Khelef A.

• VPRS Laboratory, University of Ouargla, B.P.511, 30000, Ouargla, Algeria

autor

Terki B.

• VPRS Laboratory, University of Ouargla, B.P.511, 30000, Ouargla, Algeria

autor

Lanez T.

• VPRS Laboratory, University of Ouargla, B.P.511, 30000, Ouargla, Algeria

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