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Selektywne katalityczne utlenianie (SCO) amoniaku do azotu i pary wodnej wobec mieszanych tlenków pochodzenia hydrotalkitowego – praca przeglądowa

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Warianty tytułu
EN
Selective catalytic oxidation (SCO) of ammonia into nitrogen and water vapour over hydrotalcite originated mixed metal oxides – a short review
Języki publikacji
PL EN
Abstrakty
PL
Selektywne katalityczne utlenianie amoniaku do azotu i pary wodnej jest obecnie uważane za jedną z najbardziej obiecujących metod usuwania amoniaku z gazów spalinowych i poprocesowych. W pracy omówiono technologię SCO, w tym stosowane w procesie katalizatory oraz mechanizmy przebiegu reakcji. Wykonano badania mieszanych tlenków pochodzenia hydrotalkitowego, w tym katalizatorów dwufunkcyjnych. Uzyskane wyniki jednoznacznie wskazują na duży potencjał materiałów hydrotalkitowych jako katalizatorów tego procesu. Zaproponowano dalsze kierunki badań w dziedzinie katalizatorów pochodzenia hydrotalkitowego dla procesu SCO.
EN
Selective catalytic oxidation of ammonia into nitrogen and water vapour is currently regarded as one of the most promising technologies for abatement of ammonia emissions from waste gases. This paper gives an overview of SCO technology, including the catalyst development and possible mechanisms of SCO reaction. The use of mixed metal oxides obtained from synthetic hydrotalcite-like materials in the role of catalysts for the SCO reaction has been reviewed. Obtained results clearly show huge potential of tested materials as industrial catalysts. Finally, future research directions in the area of NH3 oxidation based on mixed oxide catalysts derived from hydrotalcite-like materials are proposed.
Czasopismo
Rocznik
Strony
701--710
Opis fizyczny
Bibliogr. 45 poz., rys., tab.
Twórcy
  • Wydział Chemii, Uniwersytet Jagielloński, Kraków
autor
  • Wydział Chemii, Uniwersytet Jagielloński, Kraków
autor
  • Wydział Chemii, Uniwersytet Jagielloński, Kraków
Bibliografia
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  • 18. Noskov A.S., Zolotarskii I.A., Pokrovskaya S.A., Korotkikh V.N., Slavinskaya E.M., Mokrinskii V.V, Kashkin V.N.: Ammonia oxidation into nitrous oxide over Mn/Ri/AI catalyst: I. Single cooling tube experiments. Chemical Engineering Journal 2003, 91, 2-3, 235.
  • 19. Ivanov A.A., Chernyavsky V.S., Gross M.J., Kharitonov A.S., Uriarte A.K., Panov G.I.: Kinetics of benzene to phenol oxidation over Fe-ZSM-5 catalyst. Applied Catalysis A 2003, 249, 2, 327.
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  • 23. Huang Ch.-M.: Catalytic wet oxidation of ammonia solution: Activity of the nanoscale platinum-palladium-rhodium composite oxide catalyst. Journal of Hazardous Materials 2009, 163, I, 180.
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  • 25. Sobczyk P.D., Hensen E.J.M., de Jong A.M., van Santen A.S.: Low-temperature ammonia oxidation over Pt/ɣ-alumina: the influence of the alumina support. Topics in Catalysis 2003, 23, 1-4, 109.
  • 26. Long R.Q., Yang R.T.: Noble metal (Pt, Rh, Pd) promoted Fe-ZSM-5 for selective catalytic oxidation of ammonia to N2 at low temperatures. Catalysis Letters 2002, 78, 1-4,353.
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  • 28. Amblard M., Burch R., Southward B.W.L.: A study of the mechanism of selective conversion of ammonia to nitrogen on Ni/ɣ-AI203 under strongly oxidising conditions. Catalysis Today 2000, 59, 3-4, 365.
  • 29. Gang L., van Grondelle J., Snderson B.G., van Santen R.A.: Selective low temperature NH3 oxidation to N2 on copper-based catalysts. Journal of Catalysis 1999, 186, I, 100.
  • 30. Curtin T., O'Regan F., Deconick C., Knuttle N., Hodnett B.K.: The catalytic oxidation of ammonia: influence of water and sulfur on selectivity to nitrogen over promoted copper oxide/alumina catalysts. Catalysis Today 2000, 55, 1-2, 189.
  • 31. Long R.Q., Yang R.T.: Selective catalytic oxidation of ammonia to nitrogen over Fe2O3-TiO2 a sol-gel method. Journal of Catalysis 2002, 207, 21, 158.
  • 32. Long R.Q., Yang R.T.: Superior ion-exchanged ZSM-5 catalysts for selective catalytic oxidation of ammonia to nitrogen. Chemical Communications 2000, 17, 1651.
  • 33. Long R.Q., Yang R.T.: Selective catalytic oxidation (SCO) of ammonia to nitro- j gen over Fe-exchanged zeolites. Journal of Catalysis 2001, 201, 1, 145.
  • 34. Cavani F., Trifiro F., Vaccari A.: Hydrotalcite type anionic calys: preparation, properties and applications. Catalysis Today 1991, 11, 2, 173.
  • 35. Kovanda F., Rojka T., Dobešová J., Machovič V., Bezdička R, Obalová L., Jirátová K., Grygar T: Mixed oxides obtained from Co and Mn containing layered double hydroxides: Preparation, characterization, and catalytic properties. Journal of Solid State Chemistry 2006, 179, 3, 812.
  • 36. Sels B.F., de Vos D.E., Jacobs RA.: Hydrotalcite-like anionic clays in catalytic organic reactions. Catalysis Reviews 2001, 43, 4, 443.
  • 37. Chmielarz L., Kuśtrowski R, Rafalska-Łasocha A., Dziembaj R.: Selective j oxidation of ammonia to nitrogen on transition metal containing mixed metal oxides. Applied Catalysis B 2005, 58, 3-4, 235.
  • 38. Chmielarz L., Węgrzyn A., Wojciechowska M., Witkowski S., Michalik M.: Selective Catalytic Oxidation (SCO) of ammonia to nitrogen over I hydrotalcite originated Mg-Cu-Fe mixed oxides. Catalysis Letters 2011, 141, 9, 1345.
  • 39. Jabłońska M., Chmielarz L., Guzik K., Piwowarska Z., Witkowski S., Węgrzyn A., Walton R.I., Dunne P.W., Kovanda F.: Thermal transformations of Cu - Mg (Zn) - Al (Fe) hydrotalcite-like materials into metal oxide systems and their catalytic activity in selective oxidation of ammonia to nitrogen and water vapour. Journal of Thermal Analysis and Calorimetry - in press.
  • 40. Chmielarz L., Jabłońska M., Strumiński A., Piwowarska Z., Węgrzyn A., Witkowski S., Michalik M.: Selective catalytic oxidation of ammonia to nitrogen over Mg-AI, Cu-Mg-AI and Fe-Mg-AI mixed metal oxides doped with noble metals. Applied Catalysis B 2013, 130-131, 152.
  • 41. Darvell L.I., Heiskanen K., Jones J.M., Ross A.B., Simell P., Williams A.: An investigation of alumina-supported catalysts for the selective catalytic oxidation of ammonia in biomass gasification. Catalysis Today 2003, 81, 4, 681.
  • 42. Amores J.M.G., Escribano V.S., Ramis G., Busca G.: An FT-IR study of ammonia adsorption and oxidation over anatase-supported metal oxides. Applied Catalysis B 1997, 13, 1,45.
  • 43. Zawadzki J.: The mechanism of ammonia oxidation and certain analogous reactions. Discussions of the Faraday Society 1950, 8, 140.
  • 44. Qi G., Gatt J.E., Yang R.T.: Selective catalytic oxidation (SCO) of ammonia to nitrogen over Fe-exchanged zeolites prepared by sublimation of FeCl3. Journal of Catalysis 2004, 226, 1, 120.
  • 45. Zhang L., He H.: Mechanism of selective catalytic oxidation of ammonia to nitrogen over Ag/Al2O3. Journal of Catalysis 2009, 268, 1, 18.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-6167861c-0171-499d-b857-8e5d837c4b2f
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