Sectrofluorometric characterisation of the lubricate oil

• Autorzy: Baszanowska E. , Otremba Z.
• Języki publikacji: EN

Abstrakty

EN

Exploitive features of lubricate oils are externalised by various physical and chemical parameters (for example temperature dependencies of density and viscosity, ignition point or water content). On the other hand it is well-known that fluorescence spectra of various types of crude oils and their derivatives are strongly differ from each other. It is reasonable thesis, that exploitive features of oil may be related to transformations of light inside the oil. Therefore, despite of that fact light transformations strongly depend on chemical composition of oil (especially from the content of cyclic and polycyclic molecules). No one can exclude, that physical conditions are for fluorescence processes closely related to changes of physical and chemical properties of oil (and consequently to exploitive features) as well as to newly arising compounds and intrusions (for example metals, caused by contact with various engine elements). The paper presents spectra of fluorescence of exemplary lubricate oil (Marinol) in various configurations, namely: emission spectrum for individual excitation wavelength, excitation spectrum for single emission wavelength, excitation-emission spectrum, synchronous fluorescence spectroscopy and total synchronous fluorescence spectroscopy. Dynamic structures of those spectra gives reason to conclude that shapes of fluorescence spectra may be controlled by exploitive features of oils.

Słowa kluczowe

EN

fluorescence spectroscopy; total synchronous spectra; lubricate oil

PL

spektroskopia fluorescencyjna; widmo synchroniczne; olejowanie

• Wydawca: Faculty of Ocean Engineering and Ship Technology, Gdańsk University of Technology
• Czasopismo: Journal of Polish CIMAC
• Rocznik: 2014
• Tom: Vol. 9, no 2
• Strony: 17--22
• Opis fizyczny: Bibliogr. 16 poz., rys., wykr.

Twórcy

autor

Baszanowska E.

• Gdynia Maritime University, Faculty of Marine Engineering Department of Physics Morska Street 81-87, 81-225 Gdynia, Poland tel.[phone], fax: [phone]

autor

Otremba Z.

• Gdynia Maritime University, Faculty of Marine Engineering Department of Physics Morska Street 81-87, 81-225 Gdynia, Poland tel.[phone], fax: [phone]

Bibliografia

• [1] Baszanowska, E., Zielinski, O., Otremba, Z., Toczek, H., Influence of oil-in-water emulsions on fluorescence properties as observed by excitation-emission spectra, J. Europ. Opt. Soc. Rap. Public., Vol. 8, No. 13069, pp. 13069-1 - 1369-5, 2013.
• [2] Baszanowska, E., Otremba, Z., Toczek, H., Rohde, P., Fluorescence spectra of oil after it contacts with aquatic environment, Journal of KONES Powertrain and Transport, Warsaw, Poland, Vol. 20, No. 3, 29-34, 2013.
• [3] Baszanowska, E., Otremba, Z., Oil identification based on total synchronous spectra, Journal of KONES Powertrain and Transport, Warsaw, Poland, Vol. 21, No. 2, 2014. (in press)
• [4] Cipris, D., Millburn; Thirumalai G. Palanisamy, Morristown; Walsh, A. T., Plains, M., all of NJ, US patent: Lubricant oil monitoring system and method of monitoring lubricant oil quality, US 4792791 A https://docs.google.com/viewer?url=patentimages.storage.googleapis.com/pdfs/US4792791.pdf, 4,792,791 Dec. 20, 1988.
• [5] Paula G. Coble, Marine Optical Biogeochemistry: The Chemistry of Ocean Color, Chem. Rev., Vol. 107, Iss. 2, 402-418, 2007.
• [6] Paula G. Coble, Colored dissolved organic matter in seawater, Chapter 5 in Subsea Optics and Imaging, J. Watson and O. Zielinski, 1st Edition, Woodhead Publishing, 2013.
• [7] Lloyd, J.B.F., Synchronyzed excitation of fluorescence emission spectra, Nature (London) Phys. Sci., 231, 64-65, 1971.
• [8] Markova, L. V., Myshkin, N.K., Ossia, C.V., Kong, H., Fluorescence Sensor for Characterization of Hydraulic Oil Degradation, Tribology in industry, Vol. 29, No. 1&2, 2007.
• [9] Mignani, A.G. , Ciaccheri, L. , Díaz-Herrera, N., Mencaglia, A.A., Ottevaere, H. , Thienpont, H., Francalanci, S., Paccagnini, A., Pavone, F., Optical fiber spectroscopy for measuring quality indicators of lubricant oils, 19th International Conference on Optical Fibre Sensors, edited by David Sampson, Stephen Collins, Kyunghwan Oh, Ryozo Yamauchi, Proc. of SPIE Vol. 7004, 70045R, 2008.
• [10] Operation manual, Aqualog Horiba, rev. A, 2011.
• [11] Otremba, Z., Baszanowska, E., Toczek, H., Rohde, P., Spectrofluorymetry in application to oil-in-water emulsion characterization, Journal of KONES Powertrain and Transport, Warsaw, Poland, Vol. 18, No. 3, 317-321, 2011.
• [12] Patra, D., Mishra, A.K., Total synchronous fluorescence scan spectra of petroleum products, Anal. Bioanal. Chem., Vol. 373, Iss. 4-5, 304–309, 2002.
• [13] Patsayeva, S., Fluorescent remote diagnostic of oil pollutions: oil in films and oil dispesed in the water body, Advances in remote sensing, Vol. 3, No. 3 - VII, 1995.
• [14] Poryvkina, L., Babichenko, S., Davydova, O., SFS characterisation of oil pollution in natural water, Proc. 5th Intern. Conf. on Remote Sensing for Marine and Coastal Environments, 5-7 October, San Diego, California, Vol. 2, 520-524, 1998.
• [15] Steffens, J., Landulfo, E., Coronato, L., Guardani Courrol & Roberto, Application of Fluorescence to the Study of Crude Petroleum, Journal of Fluorescence, DOI 10.1007/s10895-009-0586-4, 2010.
• [16] Stelmaszewski, A., Fluorescence method for determination of oil identity, Optica Appl., XXXIV No. 3, 2004.