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Chemical pretreatment of formaldehyde wastewater by selected Advanced Oxidation Processes (AOPs)

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Języki publikacji
EN
Abstrakty
EN
Chemical oxidation processes: Fenton process and catalytic ozonation with Mn2+ ions were investigated for effectiveness of formaldehyde (FA) oxidation. The influence of operational variables — O3, H2O2, Mn2+ and Fe2+ concentrations and reaction time were investigated. Researches were carried out on aqueous solution of FA, which concentration was 500 mg/l. Fenton process was investigated at pH 3 and catalytic ozonation at pH 7, 10 and 12. Results revealed that Fenton process was much more effective in FA degradation than catalytic ozonation with Mn2+ as a catalyst. The optimal H2O2/Fe2+ dosage for a Fenton process was 2000/1000 mg/l. COD and FA concentrations were reduced 59,6% and 79,5%. In case of catalytic ozonation with Mn2+ the eff ectiveness was much less and it was the biggest at pH 12 and Mn2+ dosage 25 mg/l where COD and FA concentration were reduced 14% and 38%. Therefore, Fenton process can be promising technology for FA wastewater pretreatment.
Rocznik
Strony
42--48
Opis fizyczny
Bibliogr. 25 poz., wykr.
Twórcy
autor
  • Warsaw University of Technology, Environmental Engineering Faculty
Bibliografia
  • [1] Lotfy, H.R., and I.G. Rashed. “A method for treating wastewater containing formaldehyde”. Wat. Res. 36 (2002): 633–637.
  • [2] Kajitvichyanukul, P., et al. “Degradation and detoxifi cation of formaline wastewater by advanced oxidation processes”. J. Hazard. Mater. B135 (2006): 337–343.
  • [3] Kajitvichyanukul, P., M-C. Lu, and A. Jamroensan. “Formaldehyde degradation in the presence of methanol by photo-Fenton process”. J. Environ. Managem. 86 (2008): 545–553.
  • [4] Do, J-S., and C-P. Chen. “In situ oxidative degradation of formaldehyde with hydrogen peroxide electrogenerated on the modified graphites”. J. App. Electrochem. 24 (1994): 936–942.
  • [5] Do, J-S., and C-P. Chen. “In situ oxidative degradation of formaldehyde with electrogenerated hydrogen peroxide”. J. Electrochem. Soc. 140 (1993): 1632–1637.
  • [6] Do, J-S., and W-C. Yeh. “In situ Paired electrooxidative degradation of formaldehyde with electrogenerated hydrogen peroxide and hypochlorite Ion”. J. Appl. Electrochem. 28 (1998): 703–710.
  • [7] Murphy, A.P., et al. “A Fenton-like reaction to neutralise formaldehyde waste solutions”. ES& T. 23 (1989): 166--169.
  • [8] Parisheva, Z., L. Nusheva, and N. Danova. “Advanced oxidation of solutions containing formaldehyde”. Environ. Protect. Eng. 29 (2003): 5–14.
  • [9] Parisheva, Z., L. Nusheva, and P. Licheva. “Comparison of the eff ect of ozone, ozone-hydrogen peroxide system and catalytic ozonation on formaldehyde removal from aqueous model solutions”. Environ. Protect. Eng. 30 (2004): 5–10.
  • [10] Moussavi, G., A. Yazdanbakhsh, and M. Heidarizad. “The removal of formaldehyde from concentrated synthetic wastewater using O3/MgO/H2O2 process integrated with the biological treatment”. J. Hazard. Mater. 171 (2009): 907–913.
  • [11] Christoskova, T., and M. Stoyanova. “Catalytic degradation of formaldehyde and benzyl alcohol in wastewaters”. Wat. Res. 36 (2002): 2297–2303.
  • [12] Gracia, R., J.L. Aragües, and J.L. Ovelleiro. “Study of the catalytic ozonation of humic substances in water and their ozonation byproducts”. Ozone Sci. Eng. 18 (1996): 195--208.
  • [13] Cortes, S., et al. ”Comparative effi ciency of the systems O3/high pH and O3/catalyst for the oxidation of chlorobenzenes in water”. Ozone Sci. Eng. 22 (2000): 415–426.
  • [14] Beltran, F.J., F.J. Rivas, and R. Montero-de-Espinosa. “Catalytic ozonation of oxalic acid in an aqueous TiO2 slurry reactor”. Appl. Catal. B 39 (2002): 221–231.
  • [15] Ni, C.H., and J.N. Chen. „Heterogeneous catalytic ozonation of 2-chlorophenol aqueous solution with alumina as a catalyst”. Water Sci. Technol. 43 (2001): 213.
  • [16] Ma., J., and N.J.D. Graham. „Preliminary investigation of manganese-catalysed ozonation for the destruction of atrazine”. Ozone Sci. Eng. 19 (1997): 227–240.
  • [17] Andreozzi, R., et al. “The use of manganese dioxide as a heterogeneous catalyst for oxalic acid ozonation in aqueous solution”. Appl. Catal. A 138 (1996): 75--81.
  • [18] Andreozzi, R., et al. “The ozonation of pyruvic acid in aqueous solutions catalysed by suspended and dissolved manganese”. Water Res. 32 (1998): 1492–1496.
  • [19] Tong, S-P., et al. “Characteristics of MnO2 catalytic ozonation of sulfosalicylic acid and propionic acid in water”. Chemosphere 50 (2003): 1359–1364.
  • [20] Hayek, N.A., B. Legube, and M. Dore. Environmental Technol. Lett. 10 (1989): 415.
  • [21] Gracia, R., et al. “Heterogenous catalytic ozonation with supported titanium dioxide in model and natural waters”. Ozone Sci. Eng. 22 (2000): 461–471.
  • [22] Cooper, C., and R. Burch. “An investigation of catalytic ozonation of halocarbons in drinking water preparation”. Water Res. 33 (1999): 3695–3700.
  • [23] “Titrimetric method of formaldehyde determination — methodology according to the laboratory of the Nitrogen Plant Tarnów–Mościce”.
  • [24] Shirley, D.A. Organic chemistry. Warsaw: Technical and Scientific Publishing, 1964.
  • [25] Kowalik, P., and J. Naumczyk. “The removal of formaldehyde from wastewater using chemical methods”. Rzeszow University of Technology Research Papers [Article accepted for printing].
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-5eb77642-e87b-43f1-bae0-ec7cb1606886
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