Separation of cobalt from nickel using novel ultrasound-prepared supported liquid membranes containing Cyanex 272 as carrier

• Autorzy: Leon G. , Martinez G. , Leon L. , Guzman M. A.

Identyfikatory

DOI

10.5277/ppmp160107

• Języki publikacji: EN

Abstrakty

EN

The demand for cobalt has increased significantly in recent years due to its use in a wide variety of products and processes. Cobalt and nickel often accompany each other in nature and close physicochemical properties of both metals make their separation a complicated practical problem. Organophosphorous extractants have been widely used to separate cobalt from nickel. This paper presents the preliminary results obtained for separation of cobalt from nickel using Cyanex 272 containing supported liquid membranes prepared by a novel ultrasound-assisted method. The results show that this novel supported liquid membrane preparation method leads to higher separation factors than those described in the literature under similar separation conditions.

Słowa kluczowe

EN

cobalt; nickel; separation; supported liquid membranes; ultrasound; facilitated counter-transport; Cyanex 272

• Wydawca: Oficyna Wydawnicza Politechniki Wrocławskiej
• Czasopismo: Physicochemical Problems of Mineral Processing
• Rocznik: 2016
• Tom: Vol. 52, iss. 1
• Strony: 77--86
• Opis fizyczny: Bibliogr. 29 poz., rys.

Twórcy

autor

Leon G.

• Departamento de Ingenieria Quimica y Ambiental, Universidad Politecnica de Cartagena, 30203 Cartagena, Spain

autor

Martinez G.

• Departamento de Ingenieria Quimica y Ambiental, Universidad Politecnica de Cartagena, 30203 Cartagena, Spain

autor

Leon L.

• Departamento de Ciencias Politécnicas, UCAM, Campus de los Jeronimos, Guadalupe, 30107 Murcia, Spain

autor

Guzman M. A.

• Departamento de Ingenieria Quimica y Ambiental, Universidad Politecnica de Cartagena, 30203 Cartagena, Spain

Bibliografia

• COBALT DEVELOPMENT INSTITUTE, 2013. First Half Production Statistics. Cobalt News. 13, 3-4.
• COTE G., 2000. Hydrometallurgy of strategic materials, Solv. Extr. Ion Exch. 18, 703-727.
• EVANS H.A., VU L., BAHRI P.A., BARNARD K.R., 2012. Development of an integrated model for cobalt solvent extraction using Cyanex 272. Comput. Aid. Chem. Eng. 31, 550-554.
• FLETT D.S., 2005. Solvent extraction in hydrometallurgy: The role of organophosphorus extractants. J. Organometallic Chem. 690, 2426-2438.
• GANDHI M.N. DEORKAR N.V., KHOPKAR S.M., 1993. Solvent extraction separation of cobalt(II) from nickel and other metals with cyanex 272. Talanta 40, 1535-1539.
• GEGA J., WALKOWIAK W., GAJDA B., 2001. Separation of Co(II) and Ni(II) ions by supported and hybrid liquid membranes. Sep. Purif. Technol. 22-23, 551-558.
• HOR M., RIAD A., BENIJJAR A., LEBRUM L., HLAÏBI M., 2010. Technique of supported liquid membranes (SLMs) for the facilitated transport of vanadium ions (VO2+). Parameters and mechanism on the transport. Desalination 255, 188-195.
• JUANG R.S., 1993. Modelling of the competitive permeation of cobalt and nickel in a di(2-ethylhexyl)phosphoric acid supported liquid membrane process. J. Membr. Sci. 85, 157-166.
• KAPUSCA J.P.T., 2007; Cobalt production and markets: A brief overview. Cobalt News 7, 9-12.
• KUMBASAR R.A., 2009a. Selective extraction and concentration of cobalt from acidic leach solution containing cobalt and nickel through emulsion liquid membrane using PC-88A as extractant. Sep. Purif. Technol. 64, 273-279.
• KUMBASAR R.A., 2009b. Cobalt–nickel separation from acidic thiocyanate leach solutions by emulsion liquid membranes (ELMs) using TOPO as carrier. Sep. Purif. Technol. 68, 208-215.
• KUMBASAR R.A., 2012. Selective transport of cobalt (II) from ammoniacal solutions containing cobalt and nickel by emulsion liquid membranes using 8-hydroxyquinoline. J. Ind. Eng. Chem. 18, 145-151.
• KUMBASAR R.A., TUTKUN O. 2008. Separation of cobalt and nickel from acidic leach solutions by emulsion liquid membranes using Alamine 300 (TOA) as a mobile carrier. Desalination 224, 201-208.
• KYLLONEN, H.M., PIRKONEN, P., NYSTROM, M., 2005. Membrane filtration enhanced by ultrasound: a review. Desalination 181, 319-335.
• LEÓN G., MARTÍNEZ G., GUZMÁN M.A., MORENO J.I., MIGUEL B., FERNÁNDEZ-LÓPEZ J.A., 2013. Increasing stability and transport efficiency of supported liquid membranes through a novel ultrasound-assisted preparation method: Its application to cobalt(II) removal. Ultrason. Sonochem. 20, 650-654.
• LI B., LIU F., WANG J., LING C., LI L., HOU P., LI A., BAI Z., 2012. Efficient separation and high selectivity for nickel from cobalt-solution by a novel chelating resin: Batch, column and competition investigation. Chem. Eng. J. 195-196, 31-39.
• LINDELL E., JÄÄSKELÄINEN E., PAATERO E., NYMAN B., 2000. Effect of reversed micelles on Co/Ni separation by Cyanex 272. Hydrometallurgy 56, 337-357.
• LONGQUAN L., CHENG W., YADONG L. 1997. Separation of cobalt and nickel by emulsion liquid membrane with the use of EDTA as masking reagent. J. Membr. Sci. 135, 173-177.
• MASSELIN I., CHASSERAY X., DURAND-BOURLIER L., LAINE J.M., SYZARET P.Y., LEMORDANT D., 2001. Effect of sonication on polymeric membranes. J. Membr. Sci. 181, 213-220.
• MENDES F.D., MARTINS A.H., 2004. Selective sorption of nickel and cobalt from sulphate solutions using chelating resins. Int. J. Min. Proc. 74, 359-371.
• PARHI P.K., SARANGI K., 2008. Separation of copper, zinc, cobalt and nickel ions by supported liquid membrane technique using LIX 84I, TOPS-99 and CYANEX 272. Sep. Purif. Technol. 59, 169-174.
• REDDY B.R., PRIYA D.N., 2006. Chloride leaching and solvent extraction of cadmium, cobalt and nickel from spent nickel-cadmium batteries using Cyanex 923 and 272. J. Power Sources 161, 1428-1434.
• REDDY B.R., RAO S.V., PARK K.H., 2009. Solvent extraction separation and recovery of cobalt and nickel from sulphate medium using mixtures of TOPS 99 and TIBPS extractants. Min. Eng. 22, 500-505.
• RIBEIRO C.P., COSTA A.O.S., LOPES I.P.B., CAMPOS F.F., FERREIRA A.A., SALUD A., 2004. Cobalt extraction and cobalt–nickel separation from a simulated industrial leaching liquor by liquid surfactant membranes using Cyanex 302 as carrier. J. Membr. Sci. 241, 45-54.
• SASTRE A.M., KUMAR A., SHUKLA J.P., SINGH R.K., 1998. Improved techniques in liquid membrane separations: An overview. Sep. Purif. Meth. 27, 213-298.
• SUN X., JI Y., ZHANG L., CHEN J., LI D., 2010. Separation of cobalt and nickel using inner synergistic extraction from bifunctional ionic liquid extractant (Bif-ILE). J. Hazard. Mater. 182, 447-452.
• SURUCU A., EYUPOGLU V., TUTKUN O., 2012. Selective separation of cobalt and nickel by flat sheet supported liquid membrane using Alamine 300 as carrier. J. Ind. Eng. Chem. 18, 629-634.
• VANDERGRIFT C.F., HOROWITZ E.P., 1980. Interfacial activity of liquid-liquid extraction reagents-I: Dialkyl phosphorous based acids. J. Inorg. Nucl. Chem. 42, 119-125.
• YOUN I.J., LEE Y., JEONG J., LEE W.H., 1997. Analysis of Co-Ni separation by a supported liquid membrane containing HEH(EHP). J. Membr. Sci. 125, 231-236.

Uwagi

Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę.