Improvement of Thermophysical Characteristics of Polymer Coatings for Protecting Water Transport by Using a Mixture of Discrete Organic Fibers

• Autorzy: Sapronov Oleksandr , Buketov Andriy , Sapronova Lyudmila , Mokiy Oleksandr , Vorobiov Pavlo , Banha Mykhailo , Straka Ľuboslav

Identyfikatory

DOI

10.2478/mspe-2025-0060

• Języki publikacji: EN

Abstrakty

EN

This work presents the technological aspects of the reinforcement of the thermosetting binder to improve the thermophysical characteristics of polymeric materials and protective coatings based on them. Epoxy binder ED-20 was used to form polymer materials, which were polymerized with polyethylene polyamine (PEPA) in the ratio: 100 parts by weight of ED-20 epoxy oligomer and 10 parts by weight of PEPA hardener. A mixture of discrete organic fibers with the content of q = 0.25-2.00 wt.% was used to improve the thermophysical properties of polymer materials. The key parameters for determining the temperature range for the future operation of the designed composite materials without changing their properties were defined by thermogravimetric analysis (TGA) and differential thermal analysis (DTA). The maximum temperature of the mass loss beginning is Т0 = 624.0°K; the relative mass loss is εm = 65.7%; the initial temperature of the exoeffect is Тn = 475.5°K; and the maximum temperature of the exoeffect peak is Tmax = 545.5°K. The mathematical calculation of the activation energy of thermal destruction was performed to determine the resistance to the degradation of chemical bonds under the temperature influence. It has been proven that composites filled with a discrete organic fiber mixture with the content of q = 0.75 wt.% are characterized by the maximum activation energy (Ea = 167.2 kJ/mol), which indicates the thermal stability of reinforced composites.

Słowa kluczowe

EN

epoxy binder; hardener; a mixture of discrete organic fibers; polymer material; heat resistance; destruction; relative mass loss; activation energy

• Wydawca: STE GROUP
• Czasopismo: Management Systems in Production Engineering
• Rocznik: 2025
• Tom: nr 4 (33)
• Strony: 576--585
• Opis fizyczny: Bibliogr. 58 poz., rys., tab.

Twórcy

autor

Sapronov Oleksandr

• Kherson State Maritime Academy Department of Transport Technologies and Mechanical Engineering Independence Ave 20, 73000 Kherson, Ukraine

• https://orcid.org/0000-0003-1115-6556

autor

Buketov Andriy

• Kherson State Maritime Academy Department of Transport Technologies and Mechanical Engineering Independence Ave 20, 73000 Kherson, Ukraine

• https://orcid.org/0000-0001-9836-3296

autor

Sapronova Lyudmila

• Kherson State Maritime Academy Department of Transport Technologies and Mechanical Engineering Independence Ave 20, 73000 Kherson, Ukraine

autor

Mokiy Oleksandr

• Odessa National Polytechnic University, Shevchenko, 1, Odesa, Ukraine, 65044

autor

Vorobiov Pavlo

• Kherson State Maritime Academy Vessel’s Power Plants Operation Department Independence Ave 20, 73000 Kherson, Ukraine

• https://orcid.org/0000-0003-4120-2023

autor

Banha Mykhailo

• Kherson State Maritime Academy Department of Transport Technologies and Mechanical Engineering Independence Ave 20, 73000 Kherson, Ukraine

autor

Straka Ľuboslav

• Technical University of Košice Faculty of Manufacturing Technologies with a seat in Prešov Bayerova 1, 080 01 Prešov, Slovak Republic

• https://orcid.org/0000-0003-0914-2155

Bibliografia

• 1. P.D. Stukhlyak, O.S.Holotenko, R.Z.Zolotyi, A.G.Mykytyshyn. “Investigation of superhigh-frequency treatment influence on structuring of epoxy composites by infrared- and electron paramagnetic resonance spectroscopy analyses.” Functional Materials, vol. 28, no. 2, pp. 394-402, 2021
• 2. P.D. Stukhlyak, O.S. Holotenko, I.H. Dobrotvor, M.M. Mytnyk. “Investigation of the Adhesive Strength and Residual Stresses in Epoxy Composites Modified by Microwave Electromagnetic Treatment.” Mater. Sci., vol. 51, no. 2, pp. 208-212, 2015. https://doi.org/10.1007/s11003-015-9830-z
• 3. L.F. Sukhodub, K. Dyadyura. “Design and fabrication of polymer-ceramic nanocomposites materials for bone tissue engineering.” J. of Nano- and Electronic Physics, vol. 10, no. 6, 06003, 2018
• 4. V. Nahornyi, A. Panda, J. Valíček, M. Harničárová, M. Kušnerová, I. Pandová, S. Legutko, Z. Palková and O. Lukáč. “Method of Using the Correlation between the Surface Roughness of Metallic Materials and the Sound Generated during the Controlled Machining Process.” Materials, vol. 15, 823, 2022. https://doi.org/10.3390/ma15030823
• 5. A. Panda, V. Nahornyi, J. Valíček et al. “A novel method for online monitoring of surface quality and predicting tool wear conditions in machining of materials.” Int J Adv Manuf Technol., vol. 123, pp. 3599-3612, 2022. https://doi.org/10.1007/s00170-022-10391-0
• 6. L. Sukhodub, A. Panda, K. Dyadyura, I. Pandova and T. Krenicky. “The design criteria for biodegradable magnesium alloy implants.“ MM Science Journal, pp. 2673-2679, 2018. DOI: 10.17973/MMSJ.2018_12_201867
• 7. A. Panda, M. Prislupčák and I. Pandová. “Progressive technology diagnostics and factors affecting machinability.” Applied Mechanics and Materials, vol. 616, pp. 183-190, 2014. DOI: 10.4028/www.scientific.net/AMM.616.183
• 8. A. Panda, V.M. Anisimov, V. V. Anisimov, K. Dyadyura and I. Pandova. “Increasing of wear resistance of linear block-polyurethanes by thermal processing methods.” MM Science Journal, vol. 21, pp. 4731-4735, 2021. http://doi.org/10.17973/MMSJ.2021_10_2021018
• 9. P.D. Stukhlyak, M.M. Mytnyk, V.O. Orlov. “Influence of boundary interlayers on properties of composite polymeric materials (A review).” Materials Science, vol. 37, no. 1, pp. 80-86, 2001. https://doi.org/10.1023/A:1012338422984
• 10. P.Stukhlyak, A.Mykytyshyn, I. Chykhira. “Investigation of Heat Stepping Process for Epoxy-Amine Binders.” Advances in Materials Science and Engineering, 4973673, 2020
• 11. V. Kindrachuk, N. Wanderka, J. Banhart, D. Mukherji, D. Del Genovesse, and J. Rösier. “Intragranular Precipitation in Inconel 706: 3D Atom-Probe and HRTEM Investigations.” Steel Research International, vol. 75, pp. 74-78, 2004. https://doi.org/10.1002/srin.200405929
• 12. K.O. Dyadyura, F. Sukhodub. “Magnesium-based matrix composites reinforced with nanoparticles for biomedical applications”. Proceedings of the 2017 IEEE 7th International Conference on Nanomaterials: Applications and Properties, NAP 2017, 04NB14, 2017
• 13. K. Dyadyura, T.P. Hovorun, O.V. Pylypenko, M.V. Hovorun, V.I. Pererva. “Influence of roughness of the substrate on the structure and mechanical properties of TiAlN nano-coating condensed by DCMS. 2017 IEEE 7th International Conference Nanomaterials: Application & Properties (NAP), Odessa, Ukraine, pp. 01FNC10-1-01FNC10-4, 2017. doi: 10.1109/NAP.2017.8190202
• 14. K.A. Dyadyura, K.V. Berladir, P.V. Rudenko, O.A. Budnik and V.A. Sviderskij. “Research of properties of composite material based on polytetrafluoroethylene filled with carbon fiber with titanium nanocoating.” Proceedings of the 6th International Conference Nanomaterials: Applications and Properties, NAP 2016 14-19 September 2016, vol. 5, no. 2, 02NNSA04
• 15. A. Panda, K. Dyadyura, J. Valíček, M. Harničárová, M. Kušnerová, T. Ivakhniuk, L. Hrebenyk, O. Sapronov, V. Sotsenko, P. Vorobiov, V. Levytskyi and A. Buketov. „Ecotoxicity Study of New Composite Materials Based on Epoxy Matrix DER-331 Filled with Biocides Used for Industrial Applications.“ Polymers, vol. 14, 3275, 2022. https://doi.org/10.3390/polym14163275
• 16. J. Fan, & J. Njuguna. “An introduction to lightweight composite materials and their use in transport structures.” Lightweight Composite Structures in Transport, pp. 3-34, 2016. DOI: 10.1016/B978-1-78242-325-6.00001-3
• 17. P.P. Savchuk, A.G. Kostornov, V.P. Kashitskii, O.L. Sadova. “Friction Wear of Modified Epoxy Composites.” Powder Metallurgy and Metal Ceramics, vol. 53, pp. 205-209, 2014
• 18. R. Egala, G.V. Jagadeesh, & S.G. Setti. “Experimental investigation and prediction of tribological behavior of unidirectional short castor oil fiber reinforced epoxy composites.” Friction, vol. 9, pp. 250-272, 2021. https://doi.org/10.1007/s40544-019-0332-0
• 19. E.A. Lysenkov, N.G. Leonova, S.V. Zhiltsova. “Effect of the Silicon-Containing Phase on the Hierarchy of the Structure of Epoxy-Silica Nanocomposites.” Theoretical and Experimental Chemistry, vol. 55, pp. 250-257, 2019. https://doi.org/10.1007/s11237-019-09616-3
• 20. A. Buketov, O. Sapronov, A. Menou, O. Syzonenko, A. Sapronova, S. Panin. “Resistance to impact of loads of shock nature of protective coatings intended for protection of boat devices of water transport.” Lecture Notes in Intelligent Transportation and Infrastructure. Springer, Cham, 2022. https://doi.org/10.1007/978-3-030-94774-3_21
• 21. V. Kashytskyi, P. Savchuk, V. Malets, Y. Herasymiuk, S. Shchehlov. “Examining the effect of physical fields on the adhesive strength of protective epoxy composite coatings.” Eastern-European Journal of Enterprise Technologies, vol. 3, no. 12, pp. 16-22, 2017. https://doi.org/10.15587/1729-4061.2017.103128
• 22. Т.P. Hоvоrun, O.V. Pylypenko, M.V. Hovorun, K.O. Dyadyura. “Methods of obtaining and properties of wear-resistant coatings Ti and N and Ti, Al and N.” J. Nano- Electron. Phys., vol. 9, no. 2, 02026, 2017
• 23. L. Sukhodub, A. Panda, L. Sukhodub, M. Kumeda and P. Baron. “Hydroxyapatite and zinc oxide based two-layer coating, deposited on Ti6Al4V substrate.” MM Science Journal, pp. 3494-3499, 2019. DOI: 10.17973/MMSJ.2019_12_2019030
• 24. V.M. Anisimov, V.V. Anisimov, T. Krenicky. “Properties Prediction of Linear Block-Polyurethanes Based on the Mixtures of Simple Oligoethers. “ Management Systems in Production Engineering, vol. 27, issue 4, pp. 217-220, 2019. DOI: https://doi.org/10.1515/mspe-2019-0034
• 25. O. Grytsenko, E. Spišák, Ľ. Dulebová, V. Moravskii and O. Suberlyak. “Sorption Capable Film Coatings with Variable Conductivity.” Materials Science Forum, vol. 818, pp. 97-100, 2015. DOI: 10.4028/www.scientific.net/MSF.818.97
• 26. О. Sapronov, P. Maruschak, V. Sotsenko, N. Buketova, A. Bertem, A. Sapronova, O. Prentkovskis. “Development and Use of New Polymer Adhesives for the Restoration of Marine Equipment Units.” J. Mar. Sci. Eng., vol. 8, no. 7, 527, 2020. https://doi.org/10.3390/jmse8070527
• 27. J. Summerscales. “Materials selection for marine composites.” Marine Composites, pp. 3-30, 2019. http://dx.doi.org/10.1016/B978-0-08-102264-1.00001-7
• 28. A.V. Buketov, N.A. Dolgov, A.A. Sapronov, V.D. Nigalatii. “Adhesive pull and shear strength of epoxy nanocompo-site coatings filled with ultradispersed diamond.” Strength of Materials, vol. 50, pp. 425-431, 2018. DOI:10.1007/s11223-018-9986-5
• 29. A.W. Momber, L. Fröck, T. Marquardt. “Effects of accelerated ageing on the mechanical properties of adhesive joints between stainless steel and polymeric top coat materials for marine applications.” International Journal of Adhesion and Adhesives, 102699, 2020. https://doi.org/10.1016/j.ijadhadh.2020.102699
• 30. A.V. Buketov, A.V. Sapronova, O.O. Sapronov, et al. “Influence of the structure of epoxy composite filled with discrete fibers on impact fracture of vehicle parts.” Composites: Mechanics, Computations, Applications: An International Journal, vol. 11, pp. 113-127, 2020. DOI: 10.1615/CompMechComputApplIntJ.2020031192
• 31. R.D. Brooker, A.J. Kinloch, A.C. Taylor. “The morphology and fracture properties of thermoplastic-toughened epoxy polymers.” Journal of Adhesion, vol. 86, pp. 726-741, 2010. DOI: 10.1080/00218464.2010.482415
• 32. M. Iurzhenko, Y. Mamunya, G. Seytre, G. Boiteux, E. Lebedev. “The anomalous behavior of physical-chemical parameters during polymerization of organic-inorganic polymer systems based on reactive oligomers.” E-Polymers, vol. 11, no. 1, 2011. https://doi.org/10.1515/epoly.2011.11.1.285
• 33. A. Buketov, P. Maruschak, O. Sapronov, M. Brailo, O. Leshchenko, L. Bencheikh, A. Menou. “Investigation of thermo-physical properties of epoxy Nanocomposites.” Molecular Crystals and Liquid Crystals, vol. 628, pp. 167-179, 2016. https://doi.org/10.1080/15421406.2015.1137122
• 34. R.K. Prusty, D.K. Rathore, B.C. Ray. “Evaluation of the role of functionalized CNT in glass fiber/epoxy composite at above- and sub-zero temperatures: Emphasizing interfacial microstructures.” Composites Part A: Applied Science and Manufacturing, vol. 101, pp. 215-226, 2017. https://doi.org/10.1016/j.compositesa.2017.06.020
• 35. S.N. Dub, C. Haftaoglu, V.M. Kindrachuk. “Estimate of theoretical shear strength of C60 single crystal by nanoindentation.” J Mater Sci., vol. 56, pp. 10905-10914, 2021. https://doi.org/10.1007/s10853-021-05991-2
• 36. O.O. Sapronov, A.V. Buketov, P.O. Maruschak, S.V. Panin, M.V. Brailo, S.V. Yakushchenko, A.V. Sapronova, O.V. Leshchenko, A. Menou. “Research of crack initiation and propagation under loading for providing impact resilience of protective coating.” Funct. Mater., vol. 26, no. 1, pp. 114-120, 2019. DOI: https://doi.org/10.15407/fm26.01.114
• 37. W. Chen, H. Shen, M.L. Auad, C. Huang, S. Nutt. “Basalt fiber-epoxy laminates with functionalized multi-walled carbon nanotubes.” Compos Part Appl Sci Manuf., vol. 40, pp. 1082-1089, 2009. https://doi.org/10.1016/j.compositesa.2009.04.027
• 38. M. Stănescu, D. Bolcu. “A Study of Some Mechanical Properties of a Category of Composites with a Hybrid Matrix and Nat-ural Reinforcements.” Polymers, vol. 11, no. 3, 478, 2019. https://doi.org/10.3390/polym11030478
• 39. K.K. Chawla. “Composite materials: science and engineering.” Springer New York, pp. 137-195, 2012. https://doi.org/10.1007/978-0-387-74365-3_5
• 40. P. Tran, Q.T. Nguyen, K.T. Lau. “Fire performance of polymer-based composites for maritime infrastructure.” Composites Part B: Engineering, vol. 155, pp. 31-48, 2018. https://doi.org/10.1016/j.compositesb.2018.06.037
• 41. M. Davies, Y. Wang, P. Wong. “Polymer composites in fire.” Composites Part A: Applied Science and Manufacturing, vol. 37, no. 8, pp. 1131-1141, 2006. DOI: 10.1016/j.compositesa.2005.05.032
• 42. A.P. Mouritz, C.P. Gardiner. “Compression properties of fire-damaged polymer sandwich composites.” Composites Part A: Applied Science and Manufacturing, vol. 33, no. 5, pp. 609-620, 2002. DOI: 10.1016/j.compositesa.2005.05.032
• 43. A. Buketov, P. Maruschak, O. Sapronov, D. Zinchenko, V. Yatsyuk, S. Panin. “Enhancing performance characteristics of equipment of sea and river transport by using epoxy composites.” Transport, vol. 31, no. 3, pp. 333-342, 2016. DOI: 10.3846/16484142.2016.1212267
• 44. A.V. Buketov, N.A. Dolgov, A.A. Sapronov, V.D. Nigalati, N.V. Babich. “Mechanical Characteristics of Epoxy Nanocompo-site Coatings with Ultradisperse Diamond Particles.” Strength of Materials, vol. 49, pp. 473-480, 2017. https://doi.org/10.1007/s11223-017-9888-y
• 45. А.V. Buketov, А.А. Sapronov, N.N. Buketova, M.V. Brailo, P.О. Marushak, S.V. Panin, M. Yu. “Amelin Impact toughness of nanocomposite materials filled with fullerene С60 particles.” Composites: Mechanics, Computations, Applications, vol. 9, no. 2, pp. 141-161, 2018. DOI: 10.1615/CompMechComputApplIntJ.v9.i2.30
• 46. O. Sapronov, A.V. Buketov, А.V. Sapronova, et al. “The Influence of the Content and Nature of the Dispersive Filler at the Formation of Coatings for Protection of the Equipment of River and Sea Transport.” SAE Int. J. Mater. Manf., vol. 13, no. 1, 11, 2020. DOI:10.4271/05-13-01-0006
• 47. A.V. Buketov, О.О. Sapronov, M.V. Brailo, P.О. Maruschak, S.V. Yakushchenko, S.V. Panin, V.D. Nigalatiy. “Dynamics of destruction of epoxy composites filled with ultra-dispersed diamond under impact conditions.” Mechanics of Advanced Materials and Structures, vol. 27, pp. 725-733, 2020. https://doi.org/10.1080/15376494.2018.1495788
• 48. A. Buketov, S. Smetankin, P. Maruschak, K. Yurenin, O. Sapronov, V. Matvyeyev, A. Menou. “New black-filled epoxy coatings for repairing surface of equipment of marine ships.” Transport, vol. 35, no. 6, pp. 679-690, 2020. DOI: 10.3846/transport.2020.14286
• 49. A. Broido. “A simple sensitive graphical method of treating thermo gravimetric analyze data.” J. Polym. Sci. Part A., vol. 7, pp. 1761-1773, 1969. https://doi.org/10.1002/pol.1969.160071012
• 50. S.V. Yakushchenko, M.V. Brailo, A.V. Buketov, O.O. Sapronov, V. Popovych, L. Dulebova. “Investigation of the properties and structure of epoxy–polyester composites with two-component bidispersed filler.” Composites: Mechanics, Computations, Applications, vol. 13, no. 1, pp. 81-95, 2022. DOI: 10.1615/CompMechComputApplIntJ.2022041578
• 51. A.V. Buketov, S.А. Smetankin, А.V. Akimov, А.G. Kulinich. “Epoxy composite modifications influence on the energy activation’s of thermal destruction.” Funct. Mater., vol. 26, pp. 403-411, 2019. https://doi.org/10.15407/fm26.02.403
• 52. M.K. Lila, G.K. Saini, M. Kannan, I.Singh. “Effect of Fiber Type on Thermal and Mechanical Behavior of Epoxy Based Com-posites.” Fibers and Polymers, vol. 18, pp. 806-810, 2017. DOI: 10.1007/s00289-018-2431-x
• 53. Z.N. Azwa, B.F. Yousif. “Characteristics of kenaf fibre/epoxy composites subjected to thermal degradation.” Polymer Degradation and Stability, vol. 98, pp. 2752-2759, 2013. https://doi.org/10.1016/j.polymdegrad-stab.2013.10.008
• 54. O.O. Sapronov, A.V. Buketov, D.О. Zinchenko, V.M. Yatsyuk. “Features of structural processes in epoxy composites filled with silver carbonate on increase in temperature.” Composites: Mechanics, Computations, Applications. vol. 8, no. 1, pp. 47-65, 2017. DOI: 10.1615/Comp-MechComputApplIntJ.v8.i1.30
• 55. I. Pandová, M. Rimár, A. Panda, J. Valíček, M. Kušnerová and M. Harničárová. „A study of using natural sorbent to reduce iron cations from aqueous solutions.“ International Journal of Environmental Research and Public Health, vol. 17, 2020. https://doi.org/10.3390/ijerph17103686
• 56. M. Harničárová, J. Valíček, M. Kušnerová, J. Kmec, Z. Palková, I. Kopal, J. Krmela, A. Panda. „Study of the influence of the structural grain size on the mechanical properties of technical materials.“ Materialwissenschaft und Werkstofftechnik, vol. 5, 2019. https://doi.org/10.1002/mawe.201800177
• 57. Kamiński P., Niedbalski Z., Małkowski P., Božič D.: Application of composite materials in underground mining industry – fore-shaft closing platform. Min. Mach. 2022, vol. 40 issue 1, pp. 19-31. https://doi.org/10.32056/KOMAG2022.1.3
• 58. Baron R., Friebe P., Kowol D., Matusiak P.: Concept of a technological system for manufacturing the composite products based on impregnated wood waste. Min. Mach. 2023, vol. 41 issue 4, pp. 248-260. https://doi.org/10.32056/KOMAG2023.4.4

Uwagi

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