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Wear mechanisms of multilayer TiN/Ti/a-C:H coatings investigated by transmission electron microscopy technique

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Języki publikacji
EN
Abstrakty
EN
Wear mechanisms of multilayer TiN/Ti/a-C:H coatings were investigated by transmission electron microscopy technique. Mechanical properties of the TiN/Ti/a-C:H multilayer coating were tested by a ball-on-disk. Microstructure of the coatings was analyzed after the mechanical treatment. Two types of wear mechanisms were discovered: cracking layer by layer remove and tribofilm formation. Cracking was performed by the ‘layers motion’ mechanism. After a one layer step movement they were fixed again. Tribofilm was built of two types of fractions. One was homogenous, the second one had layered structure. The qualitative chemical EDS analysis showed, that titanium oxide dominated in the homogenous area, while in the layered structure partial graphitization process was found. The graphite formation during the wear process, from the carbon phase presented in the coating, is a beneficial phenomenon due to the fact that graphite is a very good lubricant. The presence of the graphite phase in the tribofilm has been confirmed by the qualitative EDS chemical analysis, electron diffraction pattern and the high resolution technique. The article presents new ideas and techniques in materials science, especially in surface engineering, as well as in mechanics and mechanisms of wear of multilayer coatings.
Rocznik
Strony
615--621
Opis fizyczny
Bibliogr. 19 poz., rys., wykr.
Twórcy
autor
  • Institute of Metallurgy and Materials Sciences Polish Academy of Sciences, 25 Reymonta Street, PL-30-059 Krakow, Poland
Bibliografia
  • [1] R.F. Bunshah, Handbook of Hard Coatings. NP, William Andrew publishing, New Jersey, USA, 2001,ISBN 0-8155-1438-7.
  • [2] D.S. Rickerby, A. Matthews, Advanced Surface Coatings. Handbook of Surface Engineering, Chapman and Hall, NY, USA, 1991.
  • [3] J. Adamus, J.M. Lackner, L. Major, A study of the impact of anti- adhesive coatings on the sheet-titanium forming processes, Archives of Civil and Mechanical Engineering 13 (2013) 64–71.
  • [4] R. Major, F. Bruckert, J.M. Lackner, W. Waldhauser, M. Pietrzyk, B. Major, Kinetics of eukaryote cells adhesion under shear flow detachment on the PLD deposited surfaces, Bulletin of the Polish Academy of Sciences 56 (2008) 223–228.
  • [5] J.M. Lackner, Ł. Major, M. Kot, Microscale interpretation of tribological phenomena in Ti/TiN soft-hard multilayer coatings on soft austenite steel substrates, Bulletin of the Polish Academy of Sciences 59 (3) (2011) 343–355.
  • [6] L. Major, J.M. Lackner, J. Morgiel, TEM Investigations of Wear Mechanisms of Single and Multilayer Coatings, The Transmission Electron Microscope, 2012, pp. 179–1962 ISBN 979-953-307-311-7.
  • [7] L. Major, W. Tirry, G. Van Tendeloo, Microstructure and defect characterization at interfacesin TiN/CrN multilayer coatings, Surface & Coatings Technology 202 (2008) 6075–6080.
  • [8] L. Major, J. Morgiel, J.M. Lackner, M.J. Szczerba, M. Kot, B. Major, Microstructure design and tribological properties of Cr/CrN and TiN/CrN multilayer films, Advanced Engineering Materials 10 (7) (2008) 617–621.
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  • [10] L. Major, J. Morgiel, TEM analysis of wear of Ti/TiN multi- layer coatings in ball-on-disc test, Key Engineering Materials 409 (2009) 123–127.
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  • [12] M. Kot, Contact mechanics of coating-substrate systems: monolayer and multilayer coatings, Archives of Civil and Mechanical Engineering 12 (2012) 464–470.
  • [13] M. Kot, P. Lacki, Contact mechanics of coating-substrate systems. I. Methods of analysis and FEM modeling of nanoindentation tests, Journal of the Balkan Tribological Association 18 (2012) 598–614.
  • [14] P. Wiecinski, J. Smolik, H. Garbacz, K.J. Kurzydlowski, Microstructure and mechanical properties of nanostructure multilayer CrN/Cr coatings on titanium alloy, Thin Solid Films 519 (2011) 4069–4073.
  • [15] V. Kumar, A.A. Bergman, A.A. Gorokhovsky, A.M. Zaitsev, Formation of carbon nanofilms on diamond for all-carbon based temperature and chemical sensor application, Carbon 49 (2011) 1385–1394.
  • [16] P. Lacki, Friction conditions in the friction brake system of Mi-2 helicopter, Archives of Civil and Mechanical Engineering (2013) http://dx.doi.org/10.1016/j.acme.2013.04.005.
  • [17] U. Wiklund, P. Hedenqvist, S. Hogmark, Multilayer cracking resistance in bending, Surface and Coatings Technology 97 (1997) 773–778.
  • [18] J. Olofsson, S. Jacobson, The influence of grain size and surface treatment on the tribofilm formation on alumina components, Wear 292–293 (2012) 17–24.
  • [19] Y. Liu, E.I. Meletis, Evidence of graphitization of diamond-like carbon films during sliding wear, Journal of Materials Science 32 (1997) 3491–3495.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-5d1e3a11-a91e-46b1-893a-8218aa2b1e1f
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