External Mass Transfer Model for Hydrogen Peroxide Decomposition by Terminox Ultra Catalase in a Packed-Bed Reactor

Grubecki, I.

doi:307--319

Artykuł - szczegóły

Tytuł artykułu

External Mass Transfer Model for Hydrogen Peroxide Decomposition by Terminox Ultra Catalase in a Packed-Bed Reactor

Autorzy

Grubecki I.

Treść / Zawartość

Pełne teksty:

External Mass Transfer Model for Hydrogen Peroxide Decomposition by Terminox Ultra Catalase in a Packed-Bed Reactor.pdf

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Identyfikatory

DOI

307--319

Warianty tytułu

Języki publikacji

Abstrakty

It is known that external diffusional resistances are significant in immobilized enzyme packed-bed reactors, especially at large scales. Thus, the external mass transfer effects were analyzed for hydrogen peroxide decomposition by immobilized Terminox Ultra catalase in a packed-bed bioreactor. For this purpose the apparent reaction rate constants, kP, were determined by conducting experimental works at different superficial velocities, U, and temperatures. To develop an external mass transfer model the correlation between the Colburn factor, JD, and the Reynolds number, Re, of the type JD = K Re(n-1) was assessed and related to the mass transfer coefficient, kmL. The values of K and n were calculated from the dependence (am kp-1 - kR-1) vs. Re-1 making use of the intrinsic reaction rate constants, kR, determined before. Based on statistical analysis it was found that the mass transfer correlation JD = 0.972 Re-0.368 predicts experimental data accurately. The proposed model would be useful for the design and optimization of industrial-scale reactors

Słowa kluczowe

hydrogen peroxide decomposition immobilized terminox ultra catalase packed bed reactor external film diffusion mass transfer coefficient

nadtlenek wodoru reaktor dyfuzja współczynnik przenikania masy

Wydawca

Komitet Inżynierii Chemicznej i Procesowej Polskiej Akademii Nauk

Czasopismo

Chemical and Process Engineering

Rocznik

2017

Tom

Vol. 38, nr 2

Strony

307--319

Opis fizyczny

Bibliogr. 26 poz., tab., wykr.

Twórcy

autor

Grubecki I.

ireneusz.grubecki@utp.edu.pl

UTP University of Science and Technology, Faculty of Chemical Technology and Engineering, 3 Seminaryjna Street, 85-326 Bydgoszcz, Poland

Bibliografia

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Uwagi

Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę (zadania 2017)

Typ dokumentu

Bibliografia

Identyfikator YADDA

bwmeta1.element.baztech-5cda4784-e1f8-4bf6-af04-da9a9e554a69