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PCDDs/Fs Pollution from Metallurgical Processes in the Town of Sisak, Croatia

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PL
Zanieczyszczenia PCDD/PCDF z technologii metalurgicznych w mieście Sisak w Chorwacji
Języki publikacji
EN
Abstrakty
EN
In order to calculate the emission of polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans from metallurgical processes located in the town of Sisak, Croatia, this research has built on experiences from developed countries, where the emission factor values from individual metallurgical processes have been taken from the reference data and used for the estimate of the emission of these pollutions in the European countries. The calculation of the emission polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans from metallurgical processes located in the town of Sisak took into account annual outputs of sinter, pig iron, steel blooms and steel billets, as well as steel casts. The metallurgical processes installed in the town of Sisak between 1950 and 2010 emitted from Q1-TEQ =17 mg a-1 PCDDs/Fs in 2001 to Q1-TEQ =5823 mg a-1 in 1989, depending on the activity of these processes. Within the observed period, the largest source of PCDDs/Fs emission was the iron ore sintering plant. Within the observed timeframe, the town of Sisak did not experience any excessive air, soil or water pollution by polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans from the local metallurgical processes.
PL
W celu obliczenia emisji wielochlorowych dibenzo-[1,4)-dioksyn (PCDD) i wielochlorowych dibenzofuranów (PCDF) z technologii metalurgicznych w miejscowości Sisak, Chorwacja, badania przedstawione w tej pracy oparte zostały nadoświadczeniach z krajów rozwiniętych, gdzie wartości wskaźnika emisji z poszczególnych technologii metalurgicznych, zostały wzięte z danych referencyjnych i użyte w celu oszacowania emisji tych zanieczyszczeń w krajach europejskich. W obliczeniach emisji wielochlorowych dibenzo-[l,4]-dioksyn i wielochlorowych dibenzofuranów z technologii metalurgicznych w miejscowości Sisak wzięto pod uwagę roczną produkcję spieku, surówki i odlewów. Technologie metalurgiczne zainstalowane w mieście Sisak pomiędzy 1950 a 2010 rokiem emitowały od Q1-TEQ = 17 mg a-1 PCDD/PCDF w 2001 r. do Q1-TEQ = 5823 mg a-1 w 1989 roku, w zależności od aktywności tych procesów. W obserwowanym okresie, największym źródłem emisji PCDD/PCDF było spiekanie rudy żelaza. W obserwowanym czasie, miasto Sisak nie odczuwało nadmierne zanieczyszczenia powietrza, gleby lub wody przez polichlorowane dibenzo-p-dioksyny i polichlorowanych dibenzofuranów z lokalnych technologii metalurgicznych.
Twórcy
autor
  • CMC Sisak D.O.O., Braće Kavurić 12, 44 010 Sisak, Croatia
  • Hanibala Lucica 5, 44 000 Sisak, Croatia
Bibliografia
  • [1] EUROPEAN COMMISSION, Integrated Pollution Prevention and Control (IPPC), Best Available Techniques Reference Document on the Production of Iron and Steel, December, 12-40, 230-281 (2001).
  • [2] T. Wang, D. R. Anderson, D. Thompson, M. Clench, R. Fisher, Studies into formation of dioxins in the iron and steel industry. 1. Characterisation of isomer profiles in particulate and gaseous emissions, Chemosphere 51, 7, 585-594 (2003).
  • [3] A. Buekenes, L. Stieglitz, K. Hell, H. Huang, P. Segres, Dioxins from thermal and metallurgical processes: recent studies for the iron and steel industry, Chemosphere 42, 5-7, 729-735 (2001), DOI:10.1016/S0045-6535(00)00247-2.
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  • [6] S. Kakareka, T. Kukharchyk, Expert Estimates of PCDD/F and PCB Emissions for some European Countries, Institute for Problems of Natural Resources Use and Ecology, Minsk, Belarus, MSC-E Technical Note 2/2002, 13, June 2002.
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  • [8] W. Lemmon, Standards pancanadiens relatifs aux dioxines et uax furannes, Reunion sur les standards d’emission, Toronto, 52 (1999).
  • [9] T. C. Henriksen, J. B. Illerup, O.-K. Nielsen, Dioxin Air Emission Inventory 1990-2004, National Environmental Research Institute, Ministry of the Environment – Denmark, 90 pp. – NERI Technical report no 602. http://www.dmu.dk/Pub/FR602.pdf
  • [10] UN ENVIRONMENT PROGRAMME, Standardized Toolkit for Identifiication and Qantification of Dioxin and Furan Releases, Prepared by UNEP Chemicals, Geneva, Switzerland, January 2001.
  • [11] S. J. Buckland, H. K. Ellis, P. Dyke, Nerw Zealand inventory of dioxin emission to air, land and water, and reservoir sources, Pbs. Ministry for the Environment, Wellington, March 2000.
  • [12] M. Coutinho, R. Rodrigues, C. Borrego, Caracterizacao das Emissoes Atmosfericas de Dioxina e Furanos em Portugal: 1999-2000, 1_ Encontro Nacional de Dioxinas e Compostos Similares na Saude e no Ambiente: uma abordagem intersectorial. Lisboa, 245 (2003).
  • [13] B. Krauthacker, V. Drevenkar, Z. Vasilic, S. Herceg Romanic, Izvjestaj o izvorima, raspodjeli i ucincima POPs spojeva na okolis i zdravlje ljudi, IMI HCCP-1, Institut za medicinska istrazivanja i medicinu rada, Zagreb, 2003, p.7. (in Croatian). http://www.jelena-suran.com/joomla/images/stories/izvjetaj IMI.pdf
  • [14] Z. Cepo, Zeljezara Sisak 1938-1978, Izdavac: SOURMK- ZS, Sisak 1978, p.286 (in Croatian).
  • [15] Commission Decision of 17 July 2000 on the implementation of a European pollutant emission register (EPER) according to Article 15 of Council Directive 96/61/EC concerning integrated pollution prevention and control (IPPC), Official Journal, 2000; Vol. L 192, pp 0036, 28/07/2000.
  • [16] US Environmental Protection Agency, SCREEN3 Dispersion Model, Version Dated 95250, Sept. 1995.
  • [17] T. Sofilic, J. Jendricko, Z. Kovacevic, M. Cosic, Measurement of Polychlorinated Dibenzo-p-dioxin and Dibenzofuran Emission from EAF Steel Making Process (accepted for publication).
  • [18] U. S. EPA. Dioxins Reassessment. Exposure and Human Health Reassessment of 2,3,7,8 Tetrachlorodibenzo-p-Dioxin (TCDD) and Related Compounds. Levels of CDD, CDF and PCB congeners in environmental media and food. http://www.epa.gov/ncea/pdfs/dioxin/nas-review/pdfs/part1 vol2/dioxin pt1 vol2 ch03 dec2003.pdf
  • [19] Compilation of EU Dioxin Exposure and Health Data, Task 6 – Trends, European Commission DG Environment, October 1999. ttp://ec.europa.eu/environment/dioxin/pdf/task6.pdf
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-5c83c863-0c9d-4566-b48f-dbe04c9a1b18
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