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Tytuł artykułu

Microstructure and electrochemical properties of the vanadium alloys after low-temperature nitrogen plasma treatment

Treść / Zawartość
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Purpose: The proposed research aims to determine the expediency of surface treatment of vanadium alloys of V-Cr and V-Ti systems due to irradiation of their surfaces with low- temperature nitrogen plasma using plasma torch NO-01. Design/methodology/approach: The investigation of microstructure and X-ray fluorescence analysis (XRF) of the samples were performed using an electron microscope TESCAN Vega3. The microhardness (Vickers hardness) of the samples was measured before and after surface treatment. The study of corrosive properties of the surface layers was performed by an electrochemical impedance spectroscopy (EIS) method. Corrosion damages were identified using impedance dependences. Findings: The microstructure of the surface layers of the V-8Ti, V-15Cr, and V-35Cr alloys in the initial state and after plasma treatment have been investigated. The chemical composition of the surface layers is determined and comparative measurements of the microhardness of these alloys are carried out. Corrosion-electrochemical properties (corrosion potentials, electrochemical impedance spectroscopy and constructed potential-dynamic polarization curves) of investigated alloys after treatment with nitrogen plasma are evaluated. Research limitations/implications: The results obtained using laboratory samples should be checked at the conditions of power equipment operation. Practical implications: This treatment has advantages over other methods of surface engineering since it provides strong surface plastic deformation and the possibility of formation of secondary phases resulting in increases in surface hardness and corrosion resistance. Originality/value: Vanadium alloys have significant advantages over other structural materials due to their high thermal conductivity and swelling resistance, high strength and plasticity up to temperatures of 700-800°C, and good weldability.
Rocznik
Strony
5--12
Opis fizyczny
Bibliogr. 17 poz.
Twórcy
  • Lviv Polytechnic National University, 12 Bandera St., Lviv, 79013, Ukraine
  • The John Paul II Catholic University of Lublin, 14 Racławickie Av., 20-950 Lublin, Poland
autor
  • Lviv Polytechnic National University, 12 Bandera St., Lviv, 79013, Ukraine
autor
  • Lviv Polytechnic National University, 12 Bandera St., Lviv, 79013, Ukraine
autor
  • Lviv Polytechnic National University, 12 Bandera St., Lviv, 79013, Ukraine
  • Lviv Polytechnic National University, 12 Bandera St., Lviv, 79013, Ukraine
autor
  • Lviv Polytechnic National University, 12 Bandera St., Lviv, 79013, Ukraine
Bibliografia
  • [1] Z.A. Duriagina, T.L. Tepla, Modification of surfaces of special alloys by nitrogen for power engineering, Ukrainian Journal of Mechanical Engineering and Materials Science 1/1 (2015) 99-104.
  • [2] Z.A. Duryagina, S.A. Bespalov, V.Ya. Pidkova, D.Yu. Polockyj, Examination of the dielectric layers on the structural materials formed by hybrid ion-plasma discharge system, Metallofizika i Noveishie Tekhnologii 33/Spec. iss. (2011) 393-400.
  • [3] M.I. Pashechko, V.V. Shyrokov, Z.A. Duryahina, Kh.B. Vasyliv, Structure and corrosion-mechanical properties of the surface layers of steels after laser alloying, Materials Science 39/1 (2003) 108-117, DOI: https://doi.org/10.1023/A:1026134714719
  • [4] Z.A. Duryagina, E.R. Bondar', V.I. Zyryanov, Protection of chromium steel from corrosive effect of Li17Pb83 eutectic by diffusion coating, Fizika i Khimiya Obrabotki Materialov 4 (1991) 107-110.
  • [5] T. Muroga, J.M. Chen, V.M. Chernov, R.J. Kurtz, M.Le Flem, Present status of vanadium alloys for fusion applications, Journal of Nuclear Materials 455/1-3 (2014) 263-268, DOI: https://doi.org/10.1016/jjnucmat.2014.06.025.
  • [6] H. Serizawa, H. Ogura, Y. Morisada, H. Fujii, H. Mori, T. Nagasaka, Influence of friction stir welding conditions on joinability of V-alloy/SUS316L dissimilar joint, Nuclear Materials and Energy 15 (2018) 43-47, DOI: https://doi.org/10.1016/j.nme.2018.05.020
  • [7] R. Li, P. Zhang, X. Li, C. Zhang, J. Zhao, First- principles study of the behavior of O, N and C impurities in vanadium solids, Journal of Nuclear Materials 435/1-3 (2013) 71-76, DOI: https://doi.org/10.1016/jjnucmat.2012.12.022
  • [8] P. Zhang, J. Zhao, B. Wen, Vacancy trapping mechanism for multiple hydrogen and helium in beryllium: a first-principles study, Journal of Physics: Condensed Matter 24/9 (2012) 095004, DOI: https://doi.org/10.1088/0953-8984/24/9/095004
  • [9] X. Wu, X.-S. Kong, Y.-W. You, W. Liu, C.S. Liu, J.-L. Chen, G.-N. Luo, Effect of transition metal impurities on the strength of grain boundaries in vanadium, Journal of Applied Physics 120 (2016) 095901, DOI: https://doi.org/10.1063/1.4961867
  • [10] P.L. Fauchais, J.V.R. Heberlein, M.I. Boulos, Thermal Spray Fundamentals, Springer, New York, 2014, DOI: https://doi.org/10.1007/978-0-387-68991-3
  • [11] M. Roy, V.K. Balla, A. Bandyopadhyay, S. Bose, Compositionally graded hydroxyapatite/tricalcium phosphate coating on Ti by laser and induction plasma, Acta Biomaterialia 7/2 (2011) 866-873, DOI: https://doi.org/10.1016/j.actbio.2010.09.016
  • [12] Z. Xu, X. Liu, P. Zhang, Y. Zhang, G. Zhang, Z. He, Double glow plasma surface alloying and plasma nitriding, Surface and Coatings Technology 201/9-11 (2007) 4822-4825, DOI: https://doi.org/10.1016/j.surfcoat.2006.07.187
  • [13] H. Kawasumi, Metal surface hardening CO2 laser, in: E.A. Metzbower (Ed.), Source Book on Applications of the Laser in Metalworking, ASM, Metals Park, Ohio, 1981, 185-195.
  • [14] M. Popovie, M. Noeakoeić. A. Traverse, K. Zhang, N. Bibie, H. Hofsass, K.P. Lieb, Modifications of reactively sputtered titanium nitride films by argon and vanadium ion implantation: Microstructural and opto-electric properties, Thin Solid Films 531/15 (2013) 189-196, DOI: https://doi.org/10.1016Zj.tsf.2013.01.045
  • [15] J.L. Murray, The Ti-V (Titanium-Vanadium) system, Bulletin of Alloy Phase Diagrams 2 (1981) 48-55, DOI: https://doi.org/10.1007/BF02873703
  • [16] VEGA 3 SEM Instruction for use, Brno, TESCAN, 2013.
  • [17] O. Kanoun, Lecture Notes on Impedance Spectroscopy: Measurement, Modeling and Applications, Taylor & Francis Group, London, 2018.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-5c3f8418-0a94-4f67-846b-87fcd314238c
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