Effect of kaolinite modified with Co(II), Cu(II), and Ni(II) salts on selected properties of tread rubber blend

• Autorzy: Pajtášová Mariana , Pecušová Beáta , Ondrušová Darina , Vavro Ján , Feriancová Andrea , Ďurišová Silvia , Dubec Andrej , Mičicová Zuzana , Klepka Tomasz Waldemar , Czarnecka-Komorowska Dorota

Identyfikatory

DOI

10.14314/polimery.2024.4.6

Warianty tytułu

PL

Wpływ kaolinitu modyfikowanego solami Co(II), Cu(II) i Ni(II) na wybrane właściwości mieszanki gumowej bieżnika

• Języki publikacji: EN

Abstrakty

EN

Effect of kaolinite modified with Cu(II), Co(II) and Ni(II) salts as a partial replacement for carbon black (1 and 8 phr) on the properties of the model tread rubber blend was examined. The blends were prepared in a two-stage process in a Brabender mixer at temperatures of 120°C and 100°C, respectively, with a constant mixing speed of 50 rpm. FT-IR confirmed the formation of copper hydroxyacetate monohydrate complex, which may indicate chemical interactions between rubber components and modified kaolinite. The filler improved technological parameters, tensile properties and hardness. Resistance to thermal aging has also increased.

PL

Zbadano wpływ kaolinitu modyfikowanego solami Cu(II), Co(II) i Ni(II) jako częściowego zamiennika sadzy (1 i 8 phr) na właściwości modelowej mieszanki gumowej bieżnika. Mieszanki przygotowano w dwuetapowym procesie w mieszalniku Brabender w temperaturze odpowiednio 120°C i 100°C, przy stałej prędkości mieszania 50 obr./min. Metodą FT-IR potwierdzono utworzenie kompleksu monohydratu hydroksyoctanu miedzi, co może świadczyć o oddziaływaniach chemicznych pomiędzy składnikami kauczuku i modyfikowanym kaolinitem. Napełniacz poprawił parametry przetwórcze, właściwości mechaniczne przy rozciąganiu i twardość. Zwiększyła się również odporność na starzenie termiczne.

Słowa kluczowe

EN

kaolinite; rubber blend; FT-IR spectroscopy; curing; mechanical properties

PL

kaolinit; mieszanka gumowa; spektroskopia FT-IR; wulkanizacja; właściwości mechaniczne

• Wydawca: Sieć Badawcza Łukasiewicz – Instytut Chemii Przemysłowej
• Czasopismo: Polimery
• Rocznik: 2024
• Tom: Vol. 69, nr 4
• Strony: 254--263
• Opis fizyczny: Bibliogr. 50 poz., fot., rys., tab., wykr.

Twórcy

autor

Pajtášová Mariana

• Alexander Dubček University of Trenčín, Faculty of Industrial Technologies in Púchov, I. Krasku 491/30, 020 01 Púchov, Slovak Republic

• https://orcid.org/0000-0001-7834-977X

autor

Pecušová Beáta

• Centre for Functional and Surface Functionalized Glass, Alexander Dubček University of Trenčín, Študentská 2, 91150 Trenčín, Slovak Republic

• https://orcid.org/0000-0002-7547-5700

autor

Ondrušová Darina

• Alexander Dubček University of Trenčín, Faculty of Industrial Technologies in Púchov, I. Krasku 491/30, 020 01 Púchov, Slovak Republic

• https://orcid.org/0000-0003-2167-9174

autor

Vavro Ján

• Alexander Dubček University of Trenčín, Faculty of Industrial Technologies in Púchov, I. Krasku 491/30, 020 01 Púchov, Slovak Republic

• https://orcid.org/0009-0009-6787-9041

autor

Feriancová Andrea

• Alexander Dubček University of Trenčín, Faculty of Industrial Technologies in Púchov, I. Krasku 491/30, 020 01 Púchov, Slovak Republic

• https://orcid.org/0000-0003-2293-5213

autor

Ďurišová Silvia

• Alexander Dubček University of Trenčín, Faculty of Industrial Technologies in Púchov, I. Krasku 491/30, 020 01 Púchov, Slovak Republic

• https://orcid.org/0000-0002-2268-7742

autor

Dubec Andrej

• Alexander Dubček University of Trenčín, Faculty of Industrial Technologies in Púchov, I. Krasku 491/30, 020 01 Púchov, Slovak Republic

• https://orcid.org/0009-0001-6145-6357

autor

Mičicová Zuzana

• Alexander Dubček University of Trenčín, Faculty of Industrial Technologies in Púchov, I. Krasku 491/30, 020 01 Púchov, Slovak Republic

• https://orcid.org/0000-0002-8803-834X

autor

Klepka Tomasz Waldemar

• Department of Technology and Polymer Processing, Faculty of Mechanical Engineering, Lublin University of Technology, ul. Nadbystrzycka 38d, 20-618 Lublin, Poland

• https://orcid.org/0000-0001-9182-0845

autor

Czarnecka-Komorowska Dorota

• Faculty of Mechanical Engineering, Poznan University of Technology, ul. Piotrowo 3, 60-965 Poznan, Poland

• https://orcid.org/0000-0002-5027-7484

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