The influence of holmium on catalytic properties of Fe or Cu-modified vermiculites

• Autorzy: Samojeden Bogdan , Grzybek Teresa , Kowal Joanna , Szymaszek Agnieszka , Jabłońska Magdalena , Gläser Roger , Motak Monika

Identyfikatory

DOI

10.5277/ppmp19074

• Języki publikacji: EN

Abstrakty

EN

Natural layered clay, vermiculite, was modified and tested as catalyst for the selective catalytic reduction of NO_x with ammonia (NH₃-SCR). Its modification included the application of the blowing agent (azodicarbonamide), acid treatment and pillaring with Al₂O₃. Active phase (transition metals: Cu or Fe) was introduced via impregnation. The obtained materials were characterized by N₂ sorption (texture), XRD (structure), DR-UV-Vis (oxidation state and aggregation of the active phase), H₂-TPR (reducibility of the active phase), in situ DRIFTS (types of adsorbed species due to contact of the sample NH₃) and NH₃-TPD (type/strength of the acidic sites). The initial modification procedures (treatment with azodicarboamide) resulted in the increase of specific surface area of vermiculite. The introduction of transition metal ions provided a significant amount of acidic sites. The promoting impact of holmium was confirmed by the increased strength of the sites. The highest catalytic activity was exhibited by the sample Fe-containing vermiculite and doped with Ho.

Słowa kluczowe

EN

selective catalytic reduction; deNOx; holmium; vermiculite

• Wydawca: Oficyna Wydawnicza Politechniki Wrocławskiej
• Czasopismo: Physicochemical Problems of Mineral Processing
• Rocznik: 2019
• Tom: Vol. 55, iss. 6
• Strony: 1484--1495
• Opis fizyczny: Bibliogr. 63 poz., rys., tab., wykr.

Twórcy

autor

Samojeden Bogdan

• AGH University of Science and Technology, Faculty of Energy and Fuels, Al. Mickiewicza 30, PL-30059, Kraków, Poland

autor

Grzybek Teresa

• AGH University of Science and Technology, Faculty of Energy and Fuels, Al. Mickiewicza 30, PL-30059, Kraków, Poland

autor

Kowal Joanna

• AGH University of Science and Technology, Faculty of Energy and Fuels, Al. Mickiewicza 30, PL-30059, Kraków, Poland

autor

Szymaszek Agnieszka

• AGH University of Science and Technology, Faculty of Energy and Fuels, Al. Mickiewicza 30, PL-30059, Kraków, Poland

autor

Jabłońska Magdalena

• Institute of Chemical Technology, Universität Leipzig, Linnéstr. 3, 04103 Leipzig, Germany

autor

Gläser Roger

• Institute of Chemical Technology, Universität Leipzig, Linnéstr. 3, 04103 Leipzig, Germany

autor

Motak Monika

• AGH University of Science and Technology, Faculty of Energy and Fuels, Al. Mickiewicza 30, PL-30059, Kraków, Poland

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Uwagi

1. The research was financed by AGH Grant 16.16.210.476.

2. Opracowanie rekordu ze środków MNiSW, umowa Nr 461252 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2020).