Synthesis of Hexabenzylhexaazaisowurtzitane (HBIW) under Ultrasound Irradiation with Fe3O4@PCA Nanoparticles as an Efficient and Reusable Nanomagnetic Catalyst

• Autorzy: Malekzadeh A. M. , Shokrollahi S. , Ramazani A. , Rezaei S. J. T. , Asiabi P. A. , Joo S. W.

Identyfikatory

DOI

10.22211/cejem/68475

• Języki publikacji: EN

Abstrakty

EN

Magnetic Fe3O4@polycitric acid (Fe3O4@PCA) nanoparticles were prepared by the reaction of Fe3O4 nanoparticles with an excess amount of citric acid at 100-160 °C. The magnetic Fe3O4@PCA nanoparticles were characterized by infrared spectroscopy (FTIR), scanning electron microscope (SEM), Transmission Electron Microscopy (TEM), Thermogravimetric Analysis (TGA) and powder X-ray diffraction (XRD). Finally, the synthesized magnetic Fe3O4@PCA nanoparticles were used as a heterogeneous solid acid catalyst for the synthesis of HBIW from benzylamine and glyoxal in acetonitrile-water solvent under ultrasonic irradiation conditions. The catalyst could be reused up to 6 times without significant loss of activity.

Słowa kluczowe

EN

hexabenzylhexaazaisowurtzitane (HBIW); nanomagnetic catalyst; solid acid; Fe3O4@PCA; ultrasound irradiation

• Wydawca: Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
• Czasopismo: Central European Journal of Energetic Materials
• Rocznik: 2017
• Tom: Vol. 14, no. 2
• Strony: 336--350
• Opis fizyczny: Bibliogr. 34 poz., rys., tab.

Twórcy

autor

Malekzadeh A. M.

• Department of Chemistry, University of Zanjan, PO Box 45195-313, Zanjan, Iran

autor

Shokrollahi S.

• Department of Chemistry, University of Zanjan, PO Box 45195-313, Zanjan, Iran

autor

Ramazani A.

• Department of Chemistry, University of Zanjan, PO Box 45195-313, Zanjan, Iran

autor

Rezaei S. J. T.

• Department of Chemistry, University of Zanjan, PO Box 45195-313, Zanjan, Iran

autor

Asiabi P. A.

• Department of Chemistry, University of Zanjan, PO Box 45195-313, Zanjan, Iran

autor

Joo S. W.

• School of Mechanical Engineering, Yeungnam University, Gyeongsan 712-749, Republic of Korea

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