Electron-transfer complexation of morpholine donor molecule with some π – acceptors: Synthesis and spectroscopic characterizations

• Autorzy: Al-Wasidi Asma S. , Al-Jafshar Nawal M. , Al-Anazi Amal M. , Alosaimi Eid H. , Refat Moamen S. , El-Zayat Lamia , Al-Omar Mohamed A. , Naglah Ahmed M. , El-Nour K.M. Abou

Identyfikatory

DOI

10.2478/pjct-2019-0043

• Języki publikacji: EN

Abstrakty

EN

Morpholine is an interesting moiety that used widely in several organic syntheses. The intermolecular charge-transfer (CT) complexity associated between morpholine (Morp) donor with (monoiodobromide “IBr”, 2,3-dichloro-5,6-dicyano-1,4-benzoquinone “DDQ”, 2,6-dichloroquinone-4-chloroimide “DCQ” and 2,6-dibromoquinone-4-chloroimide “DBQ”) π–acceptors have been spectrophotometrically investigated in CHCl3 and/or MeOH solvents. The structures of the intermolecular charge-transfer (CT) were elucidated by spectroscopic methods like, infrared spectroscopy. Also, different analyses techniques such as UV-Vis and elemental analyses were performed to characterize the four morpholine [(Morp)(IBr)], [(Morp)(DDQ)], [(Morp)(DCQ)] and [(Morp)(DBQ)] CT-complexes which reveals that the stoichiometry of the reactions is 1:1. The modified Benesi-Hildebrand equation was utilized to determine the physical spectroscopic parameters such as association constant (K) and the molar extinction coefficient (ε).

Słowa kluczowe

EN

Morpholine; π-acceptor; CT complex; photometric titration; infrared; Benesi-Hildebrand

• Wydawca: West Pomeranian University of Technology. Publishing House
• Czasopismo: Polish Journal of Chemical Technology
• Rocznik: 2019
• Tom: Vol. 21, nr 4
• Strony: 82--88
• Opis fizyczny: Bibliogr. 39 poz., rys., tab.

Twórcy

autor

Al-Wasidi Asma S.

• Department of Chemistry, College of Science, Princess Nourah Bint Abdulrahman University, Riyadh 11671, Saudi Arabia

autor

Al-Jafshar Nawal M.

• Department of Chemistry, College of Science, Princess Nourah Bint Abdulrahman University, Riyadh 11671, Saudi Arabia

autor

Al-Anazi Amal M.

• Department of Chemistry, College of Science, Princess Nourah Bint Abdulrahman University, Riyadh 11671, Saudi Arabia

autor

Alosaimi Eid H.

• Department of Chemistry, Faculty of Science, Bisha University, Bisha 61922, Saudi Arabia

autor

Refat Moamen S.

• Department of Chemistry, Faculty of Science, Taif University, Al-Haweiah, 21974, Taif, Saudi Arabia
• Department of Chemistry, Faculty of Science, Port Said University, Port Said, 42521, Egyp

autor

El-Zayat Lamia

• Department of Chemistry, Faculty of Science, Port Said University, Port Said, 42521, Egyp

autor

Al-Omar Mohamed A.

• Drug Exploration and Development Chair (DEDC), Department of Pharmaceutical Chemistry, College of Pharmacy, King Saud University, Riyadh 11451, Saudi Arabia

autor

Naglah Ahmed M.

• Drug Exploration and Development Chair (DEDC), Department of Pharmaceutical Chemistry, College of Pharmacy, King Saud University, Riyadh 11451, Saudi Arabia
• Peptide Chemistry Department, Chemical Industries Research Division, National Research Centre, 12622-Dokki, Cairo, Egypt

autor

El-Nour K.M. Abou

• Chemistry Department, Faculty of Science, Suez Canal University, Ismailia, Egypt

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