Magnesium silicate conjugated with calcium lignosulfonate: In situ synthesis and comprehensive physicochemical evaluations

• Autorzy: Klapiszewski Ł. , Zietek J. , Ciesielczyk F. , Siwinska-Stefanska K. , Jesionowski T.

Identyfikatory

DOI

https://doi.org/10.5277/ppmp1875

• Języki publikacji: EN

Abstrakty

EN

The aim of this study was to effectively combine synthetic magnesium silicate with the lignin-derived biopolymer calcium lignosulfonate, using the in situ sol-gel route. Magnesium ethoxide and tetraethoxysilane were used as precursors of MgO and SiO2. The synthesis was carried out in alcoholic solution with the addition of ammonia solution as a promoter of hydrolysis. Calcium lignosulfonate was introduced to the reaction medium prior to the synthesis of magnesium silicate. The resulting hybrid powder material was thoroughly characterized, including morphology and particle sizes (SEM microscopy and the DLS technique), porous structure parameters (the BET method and BJH model), thermal stability (TG analysis) and electrokinetic stability (LDV measurements). FTIR spectral analysis was carried out to confirm the effectiveness of the proposed synthesis methodology. Based on the results, a mechanism is proposed for the MgSiO3/lignosulfonate interactions. The resulting novel type of hybrid material combines the multifunctional nature of the biopolymer (diversity of functional groups) with the well-developed porous structure of synthetic magnesium silicate. Its physicochemical parameters were found to depend significantly on the quantity of lignosulfonate used in the synthesis.

Słowa kluczowe

EN

biopolymers; hybrid materials; synthetic magnesium silicate; calcium lignosulfonate; in situ sol-gel route

• Wydawca: Oficyna Wydawnicza Politechniki Wrocławskiej
• Czasopismo: Physicochemical Problems of Mineral Processing
• Rocznik: 2018
• Tom: Vol. 54, iss. 3
• Strony: 793--802
• Opis fizyczny: Bibliogr. 22 poz., rys. kolor.

Twórcy

autor

Klapiszewski Ł.

• Poznan University of Technology

autor

Zietek J.

• Poznan University of Technology

autor

Ciesielczyk F.

• Poznan University of Technology, M. Sklodowskiej-Curie 2, PL-60965 Poznan, Poland

autor

Siwinska-Stefanska K.

• Poznan University of Technology

autor

Jesionowski T.

• Poznan University of Technology

Bibliografia

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