Mechanism of the oxidation of nitric oxide with oxygen

• Autorzy: Głowiński Józef , Hoffmann Józef , Wilk Marcin

Identyfikatory

DOI

10.2478/pjct-2021-0005

• Języki publikacji: EN

Abstrakty

EN

Very fast reactions of forming higher nitrogen oxides set out an equilibrium framework for the course of the reaction of nitrogen monoxide oxidation. The slow course of reaction of nitrogen monoxide with oxygen permanently violates the created equilibria. In particular, the equilibrium of the oxidation reaction of nitrogen monoxide with nitrogen dioxide. The contribution of this reaction to the transformation of nitrogen monoxide in the conditions of nitrogen trioxide removal from the gas phase was estimated.

Słowa kluczowe

EN

nitrogen monoxide; oxygen; mechanism; kinetic; equilibrium; nitrogen trioxide

• Wydawca: West Pomeranian University of Technology. Publishing House
• Czasopismo: Polish Journal of Chemical Technology
• Rocznik: 2021
• Tom: Vol. 23, nr 1
• Strony: 31--36
• Opis fizyczny: Bibliogr. 7 poz., rys., tab., wz.

Twórcy

autor

Głowiński Józef

• Wroclaw University of Science and Technology Wroclaw, Poland

autor

Hoffmann Józef

• Wroclaw University of Science and Technology Wroclaw, Poland

autor

Wilk Marcin

• Łukasiewicz Research Network – New Chemical Syntheses Institute Pulawy, Poland

Bibliografia

• 1. Atkins, P.W. (1990). Phys.Chem., Oxford Univ. Press, Oxford
• 2. Pigoń, K. & Ruziewicz, Z. (1986). Phys. Chem., PWN, Warsaw, (in Polish).
• 3. Olbregts, J. (1985). Thermolecular reaction of nitrogen monoxide with oxygen; A still unsolved problem, Inter. J. Chem. Kinet., 17, 835–845.
• 4. Patwardhan, J.A. & Joshi, J.B. (2003). Unified model for NOx absorption in aqueous alkaline and dilute acidic solutions, AIChE J. 49(11), 2728–2748. DOI: 10.1002/aic.690491106.
• 5. NIST Chemical Kinetics Database, User’s Guide (https://kinetics.nist.gov/).
• 6. POLYMATH 6.1 Professional Use Version (http://www.polymathsoftware.com/).
• 7. Głowiński, J., Hałat, A., Biskupski, A., Kędzior, R. & Nieweś, D. (2018). Role of nitrogen trioxide in the oxidation of nitric oxide with oxygen, Chem. Industry, 97(9), 1000–1004. (in Polish).

Uwagi

Opracowanie rekordu ze środków MNiSW, umowa Nr 461252 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2021).