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The grafting of metallocene ethyle-octene copolymer to higher polarity with acrylic acid. Metallocene polyolefins (MePO) were grafted in melt due to increasing their surface free energy and adhesive properties. MePO modification with ozone was used to initiate the creation of peroxides on the surface of the polymer with subsequently grafting of acrylic acid in polymer melt. The efficiency of grafting in melt is high, ranging between 0.77 and 0.97.
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Tom
Strony
60--64
Opis fizyczny
Bibliogr. 12 poz., rys., tab.
Twórcy
autor
- Polymer Institute Slovak Academy of Sciences, Dúbravská cesta 9, 845 41 Bratislava, Slovakia
autor
- Polymer Institute Slovak Academy of Sciences, Dúbravská cesta 9, 845 41 Bratislava, Slovakia
autor
- Polymer Institute Slovak Academy of Sciences, Dúbravská cesta 9, 845 41 Bratislava, Slovakia
autor
- Polymer Institute Slovak Academy of Sciences, Dúbravská cesta 9, 845 41 Bratislava, Slovakia
autor
- VIPO a.s., Gen. Svobodu 1069/4, 958 01 Partizánske, Slovakia
autor
- VIPO a.s., Gen. Svobodu 1069/4, 958 01 Partizánske, Slovakia
Bibliografia
- 1. YALVAC S., KARJALA T., O´BRYAN E. 2005: Adhesives & Sealants Industry,2005, vol. 12, p. 34.
- 2. PATEL J. B., EODICE A. K., LOW Y G. 2010: Low application temperature hot meltadhesive. PCT/US 2010/043804 (2010).
- 3. LAZÁR M., RADO R., PAVLINEC J., 1961: Grafting of methyl methacrylate topolypropylene and polyethylene. Journal of Polymer Science, vol. 53(158), pp. 163–171.
- 4. BUCHENSKA J., 2002: Polypropylene fibres grafted with poly(acrylic acid). Journalof Applied Polymer Science, vol. 83(11), pp. 2295–2299.
- 5. KAUFMAN M. S. 2008: Radical-Mediated Modification of Polyolefins, Thesis,Queen s Univ. Kingston, Ontario, Canada, May 2008, p. 1.
- 6. NOVÁK, I., POPELKA A., LUYT, A. S. et al., 2013: Adhesive properties ofpolyester treated by cold plasma in oxygen and nitrogen atmospheres. Surface andCoatings Technology, vol. 235, pp. 407–416.
- 7. NOVÁK, I., POLLÁK, V., CHODÁK, I., 2006: Study of Surface Properties ofPolyolefins Modified by Corona Discharge Plasma. Plasma Processes and Polymers,vol. 3(4-5), pp. 355–364.
- 8. ZAKI A.J.J.I., 2015: Grafting of polyethylene films with N-vinyl imidazole andacrylic acid for potential use in wastewater treatment. Revue Roumaine de Chimie,vol. 60(9), pp. 867–873.
- 9. WANG H., BROWN H. R., 2004: UV grafting of methacrylic acid and acrylic acid onhigh-density polyethylene in different solvents and the wettability of grafted highdensitypolyethylene. II. Wettability. Journal of Polymer Science Part A: PolymerChemistry, vol. 42(2), pp. 263–270.
- 10. STEFFENS G.C.H., NOTHDURFT L., BUSE G., THISSEN H., HŐCKER H., KLEED. 2002, vol. 23, p. 3523.
- 11. LAZÁR M., PAVLINEC J., MAŇÁSEK Z., MIČKO M., BEREK D., 1963:Ozonation of Atactic Polypropylene. Rubber Chemistry and Technology, vol. 36(2),pp. 527–531.
- 12. RICHAUD, E.; FARCAS, F.; FAYOLLE, B.; AUDOUIN, L.; VERDU, J., 2006,Hydroperoxide titration by DSC in thermally oxidized polypropylene. PolymerTesting, vol. 25(6), pp. 829–838.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-58b5875b-624b-4fa0-90ae-bf345ae1ca33