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Effect of polyacrylamide on the process of removing impurities in the rare earth leachate

Treść / Zawartość
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The impurity removal process of the rare earth (RE) leachate is usually accompanied by the formation of flocs, and a certain amount of polyacrylamide flocculant needs to be added in this process. However, few studies have investigated the effect of the flocculant on the impurity removal process. Therefore, this paper compares the influence on the process of removing impurities with or without the adding of polyacrylamide (PAM). The results showed that the addition of PAM had little effect on the removal rate of impurities, but it was conducive to the recovery of RE. When ammonium bicarbonate was firstly adopted to regulate the solution pH to 5.0, and then sodium sulfide was used to adjust the pH to 5.2, and 0.5 mL/100 mL of PAM was added to the leachate, 96% Al3+ and 98% Zn2+ were removed from the leachate, while 95% RE was maintained. In addition, PAM could accelerate the settlement of flocs and then shorten the production cycle. The increase in RE recovery rate may be due to the addition of PAM to shorten the settling time of the flocs, thereby reducing the RE ions adsorbed during the flocculation process and increasing the recovery rate of the RE.
Słowa kluczowe
Rocznik
Strony
182--191
Opis fizyczny
Bibliogr. 34 poz., rys., wykr.
Twórcy
autor
  • Central South University
autor
  • Wuhan Institute of Technology
autor
  • Wuhan Institute of Technology
autor
  • Wuhan Institute of Technology
  • Wuhan Institute of Technology
autor
  • Wuhan Institute of Technology
Bibliografia
  • BESRA, L., SENGUPTA, D. K., ROY, S. K., AY, P., 2002. Studies on flocculation and dewatering of kaolin suspensions by anionic polyacrylamide flocculant in the presence of some surfactants. Int. J. Miner. Process, 66, 1-28.
  • CÁNOVAS, C. R., MACÍAS, F., LÓPEZ, R. P., NIETO, J. M., 2018. Mobility of rare earth elements, yttrium and scandium from a phosphogypsum stack: environmental and economic implications. Sci. Total Environ., 618, 847–857.
  • CHANG, Q., 2011. Water treatment by flocculation. Beijing: Chemical Industry Press.
  • CHI, R. A., HU, Y., ZHU, G., XU, S., ZHOU, Z., XU, Z., 2003. Solution-Chemistry Analysis of Ammonium Bicarbonate Consumption in Rare-Earth-Element Precipitation. Metall. Mater. Trans B, 34B, 611-617.
  • CHI, R. A., TIAN, J., 2008. Weathered crust elution-deposited rare earth ores. New York: Nova Science Publishers.
  • CHI, R. A., WANG, D. Z., 1992. Theoretical Analysis and Experimental Study on the Consumption of Oxalic Acid in the Rare Earth Precipitation Process of a Complex Solution. Rare Earth (in Chinese), 13(4): 11-15.
  • CHI, R. A., WANG, D. Z., 2014. Rare Earth Mineral Processing. Beijing: Science Press.
  • FENG, J., ZHOU, F., CHI, R. A., LIU, X., XU, Y. L., LIU, Q., 2018. Effect of a novel compound on leaching process of weathered crust elution deposited rare earth ore. Miner. Eng, 129, 63-70.
  • GUPTA, C.K., KRISHNAMURTHY, N., 2005. Extractive Metallurgy of Rare Earths. New York: CRC Press.
  • GREGORY, J., BARANY, S., 2011. Adsorption and flocculation by polymers and polymer mixtures. Adv. Colloid Interface Sci, 169, 1–12.
  • HABASHI, F., 1985. The recovery of the lanthanides from phosphate rock. J. Chem. Technol. Biotechnol., 35, 5-14.
  • HAMMAS-NASRI, I., HORCHANI-NAIFER, K., FÉRID, Mokhtar., BARCA, D., 2016. Rare earths concentration from phosphogypsum waste by two-step leaching method. Int. J. Miner. Process, 149, 78-83.
  • HAMZA, M.F., EL-AASSY, I.E., GUIBAL, E., 2019. Integrated treatment of tailing material for the selective recovery of uranium, rare earth elements and heavy metals. Miner. Eng., 133, 138–148.
  • HE, Z. Y., ZHANG, Z. Y., YU, J. X., XU, Z. G., CHI, R. A., 2016a. Process optimization of rare earth and aluminum leaching from weathered crust elution-deposited rare earth ore with compound ammonium salts. J. Rare Earths, 34(4), 413-419.
  • HE Z. Y., ZHANG Z. Y., YU J. X., ZHOU F., XU Y. L., XU Z. G., CHEN Z., CHI R. A., 2016b. Kinetics of column leaching of rare earth and aluminum from weathered crust elution-deposited rare earth ore with ammonium salt solutions. Hydrometallurgy, 163, 33-39.
  • JAROSINISKI, A., KOWALCZYK, J., MAZANEK, C.Z., 1993. Development of the Polish wasteless technology of apatite phosphogypsum utilization with recovery of rare earths. J. Alloys Compd., 200, 147–150.
  • JARVIS, P., JEFFERSON, B., GREGORY, J., PARSONS, S. A., 2005. A review of floc strength and breakage. Water Res., 39(14), 3121-3137.
  • JOHN, B., 2016. Coagulation and flocculation in water and wastewater treatment- third edition. London: IWA Publishing.
  • KOLAR, E., CATTHOOR, R.P., KRIEL, F.H., SEDEV, R., MIDDLEMAS, S., KLIER, E., HATCH, G., PRIEST, C., 2016. Microfluidic solvent extraction of rare earth elements from a mixed oxide concentrate leach solution using Cyanex® 572. Chem. Eng. Sci. 148, 212–218.
  • LI, X. F., 2000. Removing heavy metal ions from rare earth ore leachate by sodium sulfide. Util. Miner. Resour (in Chinese), 3, 46-47.
  • LI, X. F., CHI, R. A., 1997. Study on removing impurities in the exchanged liquor of rare earth. Comprehen. Util. Miner (in Chinese), 2, 10-13.
  • LUO, X. P., ZOU, L. P., MA, P. L., LUO, C. G., XU, J., TANG, X. K., 2015. Removing aluminum from a low-concentration lixivium of weathered crust elution-deposited rare earth ore with neutralizing hydrolysis. Rare Met, 36 (8), 685-690.
  • MOLDOVEANU, G. A., PAPANGELAKIS, V. G., 2016. An overview of rare-earth recovery by ion-exchange leaching from ion-adsorption clays of various origins. Mineral. Mag. 80(1), 63–76.
  • MORUZZ, R. B., de OLIVEIRA, A. L., da CONCEICAO, F. T., GREGORY, J., CAMPOS, L. C., 2017. Fractal dimension of large aggregates under different flocculation conditions. Sci. Total Environ., 609, 807-814.
  • SVAROVSKY, L., 2001. Solid-Liquid Separation- fourth edition. Oxford: Butterworth-Heinemann.
  • TADROS, T., 2013. Encyclopedia of Colloid and Interface Science. Berlin: Springer Berlin Heidelberg.
  • TIAN, J., YIN, J., CHEN, K., RAO, G., JIANG, M., CHI, R., 2011. Extraction of rare earths from the leach liquor of the weathered crust elution-deposited rare earth ore with non-precipitation. Int. J. Miner. Process, 3-4 (98), 125-131.
  • TIAN, J., YIN, J. Q., TANG, X. K., CHEN, J., LUO, X. P., RAO, G. H., 2013a. Enhanced leaching process of a low-grade weathered crust elution-deposited rare earth ore with carboxymethyl sesbania gum. Hydrometallurgy, 139, 124–131.
  • TIAN, J., TANG, X. K., YIN, J. Q., LUO, X. P., RAO, G. H., 2013b. Process optimization on leaching of a lean weathered crust elution-deposited rare earth ores. Int. J. Miner. Process, 119, 83–88.
  • XIAO, Y. F., HUANG, L., LONG, Z. Q., FENG, Z. Y., WANG, L. S., 2016. Adsorption ability of rare earth elements on clay minerals and its practical performance. J. Rare Earths, 34, 543-548.
  • YU, Q. H., ZHU, H.Y., LEI, H., LI, X.B., 1993. Precipitation of rare earth carbonate from low grade leachate of rare earth ore. Chin. Rare Earths, (in Chinese), 14, 14-17.
  • ZHANG, L. Y., WU, Z. H., ZHANG, H. J., 1996. Preparation of the mixed crystalline rare earth carbonate. Chin. Rare Earths, (in Chinese), 17, 61-63.
  • ZHOU, F., FENG, J., WANG, Z. Q., XU, Y. L., ZHANG, Z. Y., CHI, R. A., 2017. One step purification of impurities in the leachate of weathered crust elution-deposited rare earth ores. Physicochemical Problems of Mineral Processing, 53, 2, 1188−1199.
  • ZHOU, F., LIU, Q., FENG, J., SU, J., LIU, X., CHI, R. A., 2019. Role of initial moisture content on the leaching process of weathered crust elution-deposited rare earth ores. Sep. Purif. Technol., 217, 24-30.
Uwagi
Opracowanie rekordu ze środków MNiSW, umowa Nr 461252 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2021).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-574a9eb2-1c86-4b82-a66a-6efaa78374bc
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