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Assessing influence of hydrochloric acid leaching on structural changes and bleaching performance of Nigerian clay from Udi

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Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Clay from Udi in Nigeria was mined, ground, and acid-leached at different concentrations of hydrochloric acid to produce adsorbents of varying properties. The raw and acid-leached samples were characterized using x-ray fluorescence (XRF) and Fourier transforms infra-red spectroscopy (FTIR) to examine the structural modifications in the clay as a result of acid-leaching. The analysis showed that the acid-leaching process caused several modifications of the clay samples. The surface area, Si/[Al + Fe + Mg] ratio, adsorption capacity were found to have increased in the acid-leached samples. The acid-leached samples were tested in order to ascertain their performance in bleaching palm oil and it was observed that the bleaching efficiency increased from 29.8% to 66.7%. The acid-leached sample prepared with 7M hydrochloric acid yielded an adsorbent that was efficient in bleaching palm oil under the experimental conditions. The isotherm analysis showed that the bleaching process followed the Freundlich equation.
Słowa kluczowe
Rocznik
Strony
349--358
Opis fizyczny
Bibliogr. 31 poz., rys., tab.
Twórcy
autor
  • Department of Chemical Engineering, Nnamdi Azikiwe University, P. M. B. 5025, Awka, Anambra State, Nigeria
  • Department of Chemical Engineering, Nnamdi Azikiwe University, P. M. B. 5025, Awka, Anambra State, Nigeria
Bibliografia
  • 1. AJEMBA R.O., 2012, Characterization, dissolution, and adsorptive applications of Ukpor, Udi, and Nteje clays, PhD. Thesis, Nnamdi Azikiwe University, Awka, Anambra, Nigeria.
  • 2. AL-ZAHRANI A.A., AL-SHAHRANI S.S., AL-TAWIL Y.A., 2000, Study on the activation of Saudi natural bentonite, part II: characterization of the produced active clay and its test as an adsorbing agent, J. King Saud Univ., 13, Eng. Sci. (2), 193 – 203.
  • 3. AYARI, F., SRASRA, E., TRABELSI-AYADI, M., 2005, Characterization of bentonitic clays and their use as adsorbent, Desalination, 185, 391 – 397.
  • 4. AYARI F., SRASRA E., TRABELSI-AYADI M., 2007, Retention of organic molecule by bentonitic clay saturated with different cations, Desalination, 206, 499–506.
  • 5. BAKHTYAR K.A., MUHAMMAD A.A., KARIM J.J., 2011, Acid activation and bleaching capacity of some local clays for decolourizing used oils, Asian J. Chem., 23 (6), 113–122.
  • 6. CHRISTIDIS G.E., SCOTT P.W., DUNHAM A.C., 1997, Acid activation and bleaching capacity of bentonite from the Islands of Milos and Chios, Aegean, Greece, Appl. Clay Sci., 12, 329–347.
  • 7. DIAZ F.R.C., SANCTOS P.S., 2001, Studies on the acid activation of Brazilian smectitic clays, Quim. Nova, 24 (3), 345–353.
  • 8. ENGELHARD, 1996, Raising performance standards in catalysts and sorbents for fats and oils; Engelhard; Houston.
  • 9. EZE K.A., NWADIOGBU J.O., NWAMKWERE E.T., 2012, Effect of acid treatment on the physicochemical properties of kaolin clay, Archives Appl. Sci. Res., 4 (2), 792–794.
  • 10. FOLETTO E.L., VOLZONE C., PORTO L.M., 2003, Performance of an Argentinian acid-activated bentonite in the bleaching of soybean oil, Brazilian J. Chem. Eng., 20, 139–145.
  • 11. FOLETTO E.L., COLAZZO G.C., VOLZONE C., PORTO L.M., 2011, Sunflower oil bleaching by adsorption onto acid-activated bentonite, Brazilian J. Chem. Eng., 28 (1), 169–174.
  • 12. HULA N., MUSERRET O., YUKSEL S., 2007, The effect of sulphuric acid activation on crystallinity, surface area, porosity, surface acidity, and bleaching power of bentonite, Food Chem., 105, 156–163.
  • 13. TOPALLAR H., 1998, Bleaching kinetics of sunflower seed oil, JAOCS, 75 (4), 531–533.
  • 14. INGLETHORPE S.D.J., MORGAN D.J., HIGHLEY D.E., BLOODWORTH A. J., 1993, Industrial mineral laboratory manual- bentonite, British Geological Survey Technical Report. WG/93/20.
  • 15. KIRALI E.G., LACIN O., 2006, Statistical modeling of acid activation on cotton oil bleaching by Turkish bentonite, J. Food Eng., 75, 137–141.
  • 16. LOW S.K., LEE C.K., KONG L.Y., 1998, Decolourization of crude palm oil by activated spent bleaching earth, J. of Chem. Tech. Biotechnol., 72, 67–73.
  • 17. MAKHOUKHI B., DIDI M.A., VILLEMIN D., AZZOUZ A., 2009, Acid activation of bentonite for use as a vegetable oil bleaching agent, Grasas Y. Aceites, 60 (4), 343–349.
  • 18. MOHAMEDBAKR M., BURKITBAEV M., 2009, Elaboration and characterization of natural diatomite in Aktyubinsk/Kazakhstan, The Open Mineral Journal, 3, 12–16.
  • 19. MOTLAGH M.M.K., YOUZBASHI A.A., RIGI Z.A., 2011, Effect of acid activation on structural and bleaching properties of a bentonite, Iranian J. Mat. Sci. Eng., 8 (4), 50–56.
  • 20. MOTLAGH M.M.K., Z. RIGI Z.A., YUZBASHI A.A., 2008, To evaluate an acid activated bentonite from Khorasan (Iran) for use as bleaching clay, Int. J. Eng. Sci., 19 (5-2), 83–87.
  • 21. NGUETNKAM J.P., KAMGA R., VILLIERAS F., EKODECK G.E., YVON J., 2008, Assessing the bleaching capacity of some Cameroonian clays on vegetable oils, Appl. Clay Sci., 39, 113–121.
  • 22. ONAL M., SARIKAYA Y., ALEMDAROGLU T., 2002, The effect of acid activation on some physicochemical properties of a bentonite, Turk. J. Chem., 26, 409–416.
  • 23. ROZIC L., NOVKOVIC T., PETROVIC S., 2010, Modeling and optimization process parameters of acid activation of bentonite by response surface methodology, Appl. Clay Sci., 48, 154–158.
  • 24. SALAWUDEEN T.O., DADA E.O., ALAGBE S.O., 2007, Performance evaluation of acid treated clays for palm oil bleaching, J. Eng. Appl. Sci., 2 (11), 1677–1680.
  • 25. TAHA K.K., TAGELSIR M.S., MUSA A.M., 2011, Performance of Sudanese activated bentonite in bleaching cotton seed oil, J. Bangladesh Chem. Soc., 24 (2), 191–201.
  • 26. TEMUUJIN J., JADAMBAA T., AMARSANAA J., MACKENZIE K.J.D., 2004, Characterization of acid activated montmorillonite clay from Tuulant (Mongolia), Ceramics Int., 30. 251–255.
  • 27. TEMUUJIN J., SENNA M., JADAMBAA T., BURMAA D., ERDENECHIMEG S., MACKENZIE K.J.D., 2006, Characterization and bleaching properties of acid-leached montmorillonite, J. Chem. Technol. Biotechnol., 81, 688–693.
  • 28. TOMIC Z.P., MLADENOVI S.B., BABIE B.M., LOGAR V.A., DORDEVIC A.R., CUPAC S.B., 2011, Modification of smectite structure by sulphuric acid and characteristics of the modified smectite, J. Agric. Sci., 56 (1), 25–35.
  • 29. USMAN M.A., EKWUEME V.I., ALAJE T.O., MOHAMMED A.O., 2012, Characterization, acid activation, and bleaching performance of Ibeshe clay, Lagos, Nigeria, ISRN Ceramics, doi:10.5402/2012/658508.
  • 30. WOUMFO D., KAMGA R., FIGUERAS F., NJOPWOUO D., 2007, Acid activation and bleaching capacity of some Cameroonian smectite soil clays, Appl. Clay Sci., 37, 149–156.
  • 31. ZHANSHENG W., LI C., XIFANG S., XIAOLIN X, DAI B., JIN’E L., HONGSHENG Z., 2006, Characterization, acid activation, and bleaching performance of bentonite from Xinjiang, Chinese J. Chem. Eng., 14 (2), 253–258.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-57263703-0aac-4427-8e62-8bbdab197578
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