Effect of magnesium substitution on structural and dielectric properties of LiNiPO4

• Autorzy: Anand K. , Ramamurthy B. , Veeraiah V. , Babu K. V.

Identyfikatory

DOI

10.1515/msp-2017-0008

• Języki publikacji: EN

Abstrakty

EN

The aim of this paper is to study the effect of Mg²⁺ doping in place of Ni in LiNiPO₄ compounds synthesized by solid state reaction method. As Mg is a relatively light and cheap, and is expected to stabilize the structure, it has been considered as a substituent for Ni. The structural and conductivity studies of the substituted phases are discussed in comparison with LiNiPO₄. In this study, we have proposed cation-substituted compounds, LiNi_1–xMg_xPO₄ (x = 0, 0.05, 0.1 and 0.15) where a part of the divalent state of Ni²⁺ is replaced with the corresponding amount of Mg²⁺ and where the charge compensation is maintained by lithium deficiency. It is possible to obtain the mentioned compounds because the pristine LiNiPO₄ compound is stable in ambient atmosphere, which differs considerably from the LiCoPO4 compound.

Słowa kluczowe

EN

cathode materials; XRD; FT-IR; modulus analysis

• Wydawca: De Gruyter
• Czasopismo: Materials Science Poland
• Rocznik: 2017
• Tom: Vol. 35, No. 1
• Strony: 66--80
• Opis fizyczny: Bibliogr. 43 poz., rys., tab.

Twórcy

autor

Anand K.

• Department of Instrumentation and USIC, Sri Krishnadevaraya University, Anantapur, India

autor

Ramamurthy B.

• Department of Instrumentation and USIC, Sri Krishnadevaraya University, Anantapur, India

autor

Veeraiah V.

• Department of Physics, Andhra University, Visakhapatnam, India

autor

Babu K. V.

• Advanced Analytical Laboratory, Andhra University, Visakhapatnam, India

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Uwagi

Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę (zadania 2017).