Developing of buffer-precipitation method for lead metaborate (Pb(BO2)2∙H2O) nanostructures

• Autorzy: Bulbul Berna , Beyaz Seda

Identyfikatory

DOI

10.2478/msp-2019-0092

• Języki publikacji: EN

Abstrakty

EN

Amorphous lead metaborate (Pb(BO₂)₂∙H₂O) nanostructures were synthesized by a simpl and cost-effective synthesis method which is based on precipitation of lead ions using boric acid/sodium hydroxide buffer (pH 9.2) in the presence of polyethylene glycol (PEG). Scanning electron microscopy images showed that the average particle size is 30±9 nm and the particle shape is mostly spherical. The chemical formulation of (Pb(BO₂)₂∙H₂O) was confirmed by infrared spectroscopy, inductively coupled plasma and thermal gravimetric analysis (TGA). The percentage of PEG molecules on the particle surface equal to 2.5 % was determined by TGA. Optical reflectance measurement was performed by UV-Vis spectroscopy. Based on the Kubelka-Munk function, it was calculated that the (Pb(BO₂)₂∙H₂O) nanostructures have a direct band gap of 4.6 eV.

Słowa kluczowe

EN

lead metaborate; nanomaterials; chemical synthesis

• Wydawca: De Gruyter
• Czasopismo: Materials Science Poland
• Rocznik: 2020
• Tom: Vol. 38, No. 1
• Strony: 138--142
• Opis fizyczny: Bibliogr. 31 poz., rys.

Twórcy

autor

Bulbul Berna

• Department of Chemistry, Faculty of Science & Literature, Balikesir University, Balikesir, Turkey

autor

Beyaz Seda

• Department of Chemistry, Faculty of Science & Literature, Balikesir University, Balikesir, Turkey

Bibliografia

• [1] CHEN C., SASAKI T., LI R., WU Y., LIN Z., MORI Y., HU Z., WANG J., AKA G., YOSHIMURA M., Nonlinear optical borate crystals: Principals and applications, Wiley-VCH, 2012.
• [2] JANSSEN Y., MIDDLEMISS D.S., BO S.-H., GREY C.P., KHALIFAH P.G., J. Am. Chem. Soc., 134 (30) (2012), 12516.
• [3] GAO W., JING Y., YANG J., ZHOU Z., YANG D., SUN J., LIN J., CONG R., YANG T., Inorg. Chem., 53 (5) (2014), 2364.
• [4] KESZLER D.A., Curr. Opin. Solid State Mater. Sci, 1 (2) (1996), 204.
• [5] PISARSKA J., J. Phys. Cond. Matter, 21 (28) (2009), 285101.
• [6] SONTAKKE A.D., BISWAS K., TARAFDER A., SEN R., ANNAPURNA K., Opt. Mater. Express, 1 (3) (2011), 344.
• [7] SINGH N., SINGH K. J., SINGH K., SINGH H., Nucl. Instrum. Meth. B, 225 (3) (2004), 305.
• [8] WU Y., ZHANG Q.-P., ZHOU D., ZHOU Y.-L., ZHENG J., J. Alloy. Compd., 727 (2017), 1027.
• [9] ZHANG Q. P., SUN N., ZHENG J., WANG S.W., WU Y., LUO D.L., ZHOU Y.L., Adv. Eng. Mater., 19 (3) (2017), 1600650.
• [10] DAVIDOVICH R.L., STAVILA V., MARININ D.V., VOIT E.I., WHITMIRE K.H., Coord. Chem. Rev., 253 (9 – 10) (2009), 1316.
• [11] LI D.-S., WU Y.-P., ZHANG P., DU M., ZHAO J., LI C.-P., WANG Y.-Y., Cryst. Growth Des., 10 (5) (2010), 2037.
• [12] TIAN H.-R., WANG W.-H., GAO Y.-E., DENG T.-T., WANG J.-Y., FENG Y.-L., CHENG J.-W., Inorg. Chem., 52 (11) (2013), 6242.
• [13] TIAN H.-R., WANG W.-H., ZHANG X.-P., FENG Y.-L., CHENG J.-W., Dalton T., 42 (4) (2013), 894.
• [14] CORKER D., GLAZER A., Acta Crystallogr. B, 52 (2) (1996), 260.
• [15] KROGH-MOE J., WOLD-HANSEN P., Acta Crystallogr. B, 29 (10) (1973), 2242.
• [16] BELOKONEVA E., DIMITROVA O., KORCHEMKINA T., STEFANOVICH S.Y., Crystallogr. Rep., 43 (5) (1998), 810.
• [17] RASTSVETAEVA R., ARAKCHEEVA A., PUSHCHAROVSKY D.Y., VINOGRADOVA S., DIMITROVA O., STEFANOVICH S.Y., Z. Krist-Cryst. Mater., 213 (1998), 240.
• [18] SCHOENEGGER S., ORTNER T.S., WURST K., HEYMANN G., HUPPERTZ H., Z. Naturforsch. B, 71 (8) (2016), 925.
• [19] LAURENCE R., BLAIR G., KARLIE L.J.S.N., Hydrated lead borate products, US3126351A, 1964.
• [20] STOCKDALE S.W., WEAVER E.F., PAUL T.S., Manufacture of lead borate, US2104549A, 1938.
• [21] XIAOTIAN P., Microwave coprecipitation method for preparing nano glaze of lead metaborate, CN1562840A, 2004.
• [22] SONG J.-L., HU C.-L., XU X., KONG F., MAO J.-G., Inorg. Chem., 52 (15) (2013), 8979.
• [23] ABDULLAH M., HUSSIN W. M. H.W., KASSIM A., YAHYA N., Konaka, 56 (2015), 380.
• [24] SHAJAN D., MURUGASEN P., SAGADEVAN S., Dig. J. Nanomater. Biostruct., 11 (1) (2016), 177.
• [25] OTHMAN H., ELKHOLY H., HAGER I., J. Mol. Struc., 1106 (2016), 286.
• [26] WANG P.-P., HUANG H.-S., LI P., LIU Z.-H., Therm. Acta, 512 (1) (2011), 124.
• [27] HAN S., KIM C., KWON D., Polym. Degrad. Stab., 47 (2) (1995), 2003.
• [28] LÓPEZ R., GÓMEZ R., J. Sol-Gel Sci. Techn., 61 (1) (2012), 1.
• [29] SCHEVCIW O., WHITE W.B.T., Mater. Res. Bull., 18 (9) (1983), 1059.
• [30] MC LEAN T., Prog. Semiconduct., 5 (1960), 53.
• [31] RODUNER E., Chem. Soc. Rev., 35 (7) (2006), 583.

Uwagi

Opracowanie rekordu ze środków MNiSW, umowa Nr 461252 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2020).