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The process of sorption of chromium(III) ions with a stationary sorbent layer of bentonite clays was investigated. The main advantages of using bentonites in water purification technologies are described: powerful geological reserves, cheap process of rock extraction, easy preparation for transportation and use, possibility of using waste sorbents in other technologies that is why there is no need in costly regeneration. The influence of various factors (process duration, an adsorbent layer) on the degree of wastewater purification from chromium ions, the effect of pumping speed on the dynamic capacity of the sorbent was studied and the effective volume was determined. The adsorption efficacy increases with the increase of the adsorbent layer, what can be explained by the development of the active sorption surface. As the initial concentration of chromium ions increases, the time of appearance of the first traces of the contaminant at the exit of the column increases, as well as the total time to channeling. The results of the studies indicate a higher adsorption capacity of modified bentonite with respect to Cr3+ ions compared to its natural formula. The cleaning efficacy of the solution with a concentration of chromium ions of 0.5 g∙dm–3 is increased by 5% when using 15 g of modified bentonite and 6,5% in the case one uses 20 g compared to the natural form.
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Tom
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99--104
Opis fizyczny
Bibliogr. 23 poz., rys., tab.
Twórcy
autor
- Lviv Polytechnic National University, Viacheslav Chornovil Institute of Sustainable Development, Department of Ecology and Sustainable Environmental Management, Lviv, Ukraine
autor
- Lviv Polytechnic National University, Viacheslav Chornovil Institute of Sustainable Development, Department of Ecology and Sustainable Environmental Management, Lviv, Ukraine
autor
- Vinnytsia Mykhajlo Kotsiubynskyi State Pedagogical University, Educational and Scientific Institute of Pedagogy, Psychology, Department of Psychology and Social Work, Vinnitsa, Ukraine
autor
- Vinnytsia National Technical University, Institute for Environmental Safety and Environmental Monitoring, Department of Ecology and Environmental Safety, Vinnitsa, Ukraine
autor
- Vinnytsia Mykhajlo Kotsiubynskyi State Pedagogical University, Faculty of Natural and Geography, Department of Chemistry, Vinnitsa, Ukraine
autor
- Vinnytsia Mykhajlo Kotsiubynskyi State Pedagogical University, Faculty of Natural and Geography, Department of Chemistry, Vinnitsa, Ukraine
autor
- Vinnytsia Mykhajlo Kotsiubynskyi State Pedagogical University, Faculty of Natural and Geography, Department of Chemistry, Vinnitsa, Ukraine
autor
- Lviv Polytechnic National University, Viacheslav Chornovil Institute of Sustainable Development, Department of Ecology and Sustainable Environmental Management, Lviv, Ukraine
Bibliografia
- ANNAN E., AGYEI-TUFFOUR B., BENSAH Y.D., KONADU D.S., YAYA A., ONWONA-AGYEMAN B., NYANKSON E. 2018. Application of clay ceramics and nanotechnology in water treatment: A review. Cogent Engineering. Vol. 5 (1) p. 1–35. DOI 10.1080/23311916.2018.1476017.
- ILANGO A.K., NATRAYASAMY V. 2018. Hydrothermal fabrication of zirconium oxyhydroxide capped chitosan/kaolin framework for highly selective nitrate and phosphate retention. Industrial & Engineering Chemistry Research. Vol. 57 (43) p. 14470–14481. DOI 10.1021/acs.iecr.8b01859.
- KASHIF UDDIN M. 2017. A review on the adsorption of heavy metals by clay minerals, with special focus on the past decade. Chemical Engineering Journal. Vol. 308 p. 438–462. DOI 10.1016/j.cej.2016.09.029.
- KOŁODYŃSKA D., GĘCA M., HUBICKI Z. 2017. Zastosowanie sorbentów naturalnych w procesie usuwania jonów metali ciężkich [Use of natural sorbents for removal of heavy metal ions]. Przemysł Chemiczny. T. 96. Nr 5 p. 1139–1145. DOI 10.15199/62.2017.5.33.
- KONEFAŁ M., PETRUS R., WARCHOŁ J.K. 2015. Equilibrium study of heavy metals adsorption on kaolin. Industrial and Engineering Chemistry Research. Vol 54, 27 p. 6975–6984. DOI 10.1021/acs.iecr. 5b00880.
- MALOVANYY M., SAKALOVA H., MALOVANYY M., VASYLINYCH T., PALAMARCHUK O., SEMCHUK J. 2019. Treatment of effluents from ions of heavy metals as display of environmentally responsible activity of modern businessman. Journal of Ecological Engineering. Vol. 4 (20) p. 167–176. DOI 10.12911/ 22998993/102841.
- MENG F. YUAN G., WEI J., BI D., WANG H. 2017. Leonardite-derived humic substances are great adsorbents for cadmium. Environmental Science and Pollution Research. Vol. 24 (29) p. 23006–23014. DOI 10.1007/s11356-017-9947-8.
- PALAMAR V., MARUKHLENKO M., MOKROUSOVA. O. 2015. Zastosuvannya khrommodyfikovanykh dyspersiy montmorylonitu dlya stabilizatsiyi kolahenovoyi struktury dermy [Chromium-modified montmorillonite dispersions in stabiblizing derma collagen structure]. Eastern-European Journal of Enterprise Technologies. Vol. 6(75) р. 36–41. DOI 10.15587/ 1729-4061.2015.44238.
- PALAMARCHUK O. 2011. Ekolohichna vidpovidal’nist’ yak osnova funktsionuvannya suchasnoho suspil’stva [Environmental responsibility as the basis for the functioning of modern society]. Aktualni problemy psykholohii : zb. nauk. pr. In-tu psykholohii im. H. S. Kostiuka NAPN Ukrainy. Zhytomyr: Vyd-vo ZhDU im. I. Franka. T. 7. Ekolohichna psykholohiia. Vyp. 26 р. 401–411.
- PETRUS R., WARCHOŁ J.K. 2005. Heavy metal removal by clinoptilolite. An equilibrium study in multi-component systems. Water Research. Vol. 39 (5) p. 819–830. DOI 10.1016/ j.watres.2004.12.003.
- PETRUSHKA I. YATCHYSHYN YU., PETRUSHKA K. 2014. Intensyfikatsiya sorbtsiyi tseziyu kompleksnymy pryrodnymy sorbentamy z ridkykh radioaktyvnykh seredovyshch [Cesium sorption intensification by complex natural sorbents from liquid radioactive media]. Eastern-European Journal of Enterprise Technologies. Vol. 5. 10(71) p. 47–50. DOI 10.15587/1729-4061.2014.28066.
- QIN L. YAN L., CHEN J., LIU T., YU H., DU B. 2016. Enhanced removal of Pb2+, Cu2+, and Cd2+ by amino-functionalized magnetite/kaolin clay. Industrial & Engineering Chemistry Research. Vol. 55 (27) p. 7344–7354. DOI 10.1021/acs.iecr. 6b00657.
- REPO E. WARCHOL J., BHATNAGAR A., MUDHOO A., SILLANPАА M. 2013. Aminopolycarboxylic acid functionalized adsorbents for heavy metals removal from water. Water Research. Vol. 47. Iss. 14 p. 4812–4832 DOI 10.1016/j.watres.2013. 06.020
- REPO E. PETRUS R., SILLANPАА M., WARCHOL J. 2011. Equilibrium studies on the adsorption of Co(II) and Ni(II) by modified silica gels: One-component and binary systems. Chemical Engineering Journal. Vol. 172. Iss. 1 p. 376–385. DOI 10.1016/j.cej.2011.06.019
- REPO E. WARCHOL J., SILLANPАА M. 2017. Metal recovery and preconcentration by aminopolycarboxylic acid modified silica surfaces. Journal of Sustainable Development of Energy, Water and Environment Systems. Vol. 5. Iss. 1 p. 89–100. DOI 10.13044/j.sdewes.d5.0135.
- SABADASH V. GUMNITSKYY JA., MYLIANYK O., ROMANIUK L. 2017. Concurrent sorption of copper and chromium cations by natural zeolite. Environmental Problems. Vol. 2. Iss. 1 p. 159–162.
- SAKALOVA Н., VASYLINYCZ T., KOVAL N., KASHCHEI V. 2017. Investigation of the method of chemical desorption for extraction of nikel ions(II) from bentonite clays. Environmental Problems. Vol. 2. Iss. 4 p. 187–190.
- SAKALOVA Н., PALAMARCHUK O., VASYLINYCZ T., PETRUSHKA K., ZAHARKO JA., STOKALYUK O. 2019. Socio-psychological essence of attractiveness for the subjects of entrepreneurial activities of adsorption extraction of nickel ions(II) by bentonite clays. Environmental Problems. Vol. 4. Iss. 2 p. 68–74. DOI 10.23939/ep2019.02.068.
- SATHVIKA T., MANASI, RAJESH V., RAJESH N. 2015. Prospective application of Aspergillus species immobilized in sodium montmorillonite to remove toxic hexavalent chromium from wastewater. RSC Advances. Vol. 5 (129) p. 107031–107044. DOI 10.1039/C5RA22778J.
- VASYLECHKO V., GRYSHCHOUK G., KUZMA YU., ZAKORDONSKIY V., VASYLECHKO L., LEBEDYNETS L., KALYTOVSKA M. 2003. Adsorption of cadmium on acid-modified Transcarpathian clinoptilolite. Microporous and Mesoporous Materials. Vol. 60(1–3) p. 183–196. DOI 10.1016/s1387-1811(03)00376-7.
- WARCHOŁ J., PETRUS R. 2015. Modeling of heavy metal removal dynamics in clinoptilolite packed beds. Microporous and Mesoporous Materials. Vol. 93. Iss. 1–3 p. 29–39. DOI 10.1016/j.micromeso.2006.01.021.
- WOŁOWIEC M., BAJDA T. 2017. Current stage of knowledge relating to the use ferruginous sludge from water treatment plants – a preliminary review of the literature. Mineralogia. Vol. 48. Iss. 1–4 p. 39–45. DOI 10.1515/mipo-2017-0010.
- YILDIZ S., SEVINС S. 2018. Heavy metal adsorption by dewatered iron-containing waste sludge. Ecological Chemistry and Engineering. Vol. 25. Iss. 3 p. 431–455. DOI 10.1515/eces-2018-0030.
Uwagi
Opracowanie rekordu ze środków MNiSW, umowa Nr 461252 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2021).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-5533e0ea-ada6-4f2d-9056-be3d87826d5a