Synthesis of new carbon-nitrogen composites based on waste sweet drinks

• Autorzy: Kaźmierczak-Raźna Justyna , Pietrzak Robert , Nowicki Piotr

Identyfikatory

DOI

10.5277/ppmp19052

• Języki publikacji: EN

Abstrakty

EN

The materials under investigation were new carbon-nitrogen composites obtained via pyrolysis and CO₂ activation of sweet drinks destined for utilization. Waste Pepsi Cola® has been examined as an alternative and renewable carbon source for composite materials. Nitrogen was introduced into the Pepsi Cola® solution via the addition of guanidine carbonate, before the pyrolysis process. The physicochemical properties of the materials studied were characterized by low- temperature nitrogen adsorption (using BET and BJH methods), elemental analysis, FTIR spectroscopy, scanning electron microscopy (SEM) as well as determination of pH_PZC and the number of surface functional groups. Additionally, thermal properties of the samples were investigated by thermogravimetric analysis (TG) and differential thermogravimetry (DTG). The final products were new carbon-nitrogen composites characterized by a very high content of nitrogen (11.2 - 21.6 wt.%) as well as relatively low surface area and pore volume reaching 198 m²/g and 0.16 cm³/g, respectively. Results of FT-IR study and Boehm titration indicated that the composites surface has clearly basic character, which was confirmed by pH_pzc values above 8.0.

Słowa kluczowe

EN

carbon-nitrogen composites; waste sweet drinks; activated carbon; physical activation; physico-chemical properties

• Wydawca: Oficyna Wydawnicza Politechniki Wrocławskiej
• Czasopismo: Physicochemical Problems of Mineral Processing
• Rocznik: 2019
• Tom: Vol. 55, iss. 6
• Strony: 1366--1374
• Opis fizyczny: Bibliogr. 28 poz., rys., tab., wykr.

Twórcy

autor

Kaźmierczak-Raźna Justyna

• Adam Mickiewicz University in Poznań, Faculty of Chemistry, Laboratory of Applied Chemistry, ul. Uniwersytetu Poznańskiego 8, 61-614 Poznań, Poland

autor

Pietrzak Robert

• Adam Mickiewicz University in Poznań, Faculty of Chemistry, Laboratory of Applied Chemistry, ul. Uniwersytetu Poznańskiego 8, 61-614 Poznań, Poland

autor

Nowicki Piotr

• Adam Mickiewicz University in Poznań, Faculty of Chemistry, Laboratory of Applied Chemistry, ul. Uniwersytetu Poznańskiego 8, 61-614 Poznań, Poland

Bibliografia

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Uwagi

Opracowanie rekordu ze środków MNiSW, umowa Nr 461252 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2020).