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Porosity, characterization and structural properties of natural zeolite - clinoptilolite - as a sorbent

Treść / Zawartość
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The characterization and porous structure of raw and modified clinoptilolite as a sorbent has been investigated by nitrogen adsorption, X-ray diffraction, X-ray fluorescence, Fourier transform infrared spectroscopy, differential thermal analysis, scanning electron microscopy and atomic force microscopy methods. The nitrogen adsorption data revealed that the total pore volume and specific surface area were increased after modification. The nitrogen adsorption was used to determine percent of mesoporosity. The TG data show that 14 wt. % of clinoptilolite is lost after heating up to 1200 °C. Two types of porosities - primary porosity (microporosity) and secondary one (meso- and macroporosity) have been observed.
Rocznik
Strony
139--152
Opis fizyczny
Bibliogr. 25 poz., tab., rys., wykr.
Twórcy
autor
  • Department of Environment and Energy, Science and Research Branch, Islamic Azad University, Tehran, Iran
autor
  • Department of Environment and Energy, Science and Research Branch, Islamic Azad University, Tehran, Iran
autor
  • Department of Chemistry, Islamic Azad University, Central Tehran Branch, Tehran, Iran
autor
  • Department of Environment and Energy, Science and Research Branch, Islamic Azad University, Tehran, Iran
  • Iranian Mineral Processing Research Center (IMPRC), Karaj, Iran
Bibliografia
  • [1] BRECK D.W., Zeolite molecular sieves, Wiley, NewYork, 1974.
  • [2] ACKLEY M.W.,REGE S.U.,SAXENA H., Application of natural zeolites in the purification and separation of gases, Microporous Mesoporous Mater., 2003, 61, 25.
  • [3] COOMBS D.S., ALBERTI A., ARMBRUSTER TH., ARTIOLI G., COLELLA C., GALLI E., GRICE J.D.,LIEBAU F.,MINATO H.,NICKEL E.H.,ESSAGLIA E.,PEACOR D.R.,QUARTIERI S.,RINALDI M.,ROSS R.,SHEPPARD R.A., TILLMANNS E., VERZZALINI G., Recommended nomenclature for zeolite minerals: reports of the subcommittee on zeolites of the international mineralogical association, commission on new minerals and mineral names, Can. Mineral., 1997, 35, 1571.
  • [4] ALIETTI A., Polymorphism and crystal- chemistry of heulandites and clinoptilolites, Am. Mineral., 1972, 57, 1448.
  • [5] BOLES J.R., Composition, optical properties, cell dimensions and thermal Stability of some heulandite group zeolites, Am. Mineral., 1972, 57, 1463.
  • [6] KOYAMA K.,TAKEUCHI Y.,Clinoptilolite: the distribution of potassium atoms and its role in thermal stability, Z. Kristallogr., 1977, 145, 216.
  • [7] ALBERTI A., On the crystal structure of the zeolite heulandite, Min. Petr. Mitt., 1972, 18, 129.
  • [8] BAERLOCHER CH., MEIER W.M., OLSON D.N., Atlas of zeolite structure types, 6th Ed., Elsevier, Amsterdam, 2007.
  • [9] SPRYNSKYY M., GOLEMBIEWSKI R., TRYKOWSKI G., BUSZEWSKI B., Heterogeneity and hierarchy of clinoptilolite porosity, J. Phys. Chem. Solids., 2010, 71, 1269.
  • [10] HERNANDES-HUESCA R., DIAZ L., AGUILAR-ARMENTA G., Adsorption equilibrium and kinetics of CO2, CH4 and N2 in natural zeolite, Sep. Purif. Technol., 1999, 15, 163.
  • [11] KORKUNA O., LEBODA R., SKUBISZEWSKA-ZIEMBA J., VRUBLEVSKA T., GUNKO V.M., RYCZKOWSKI J., Structural and physicochemical properties of natural zeolites: clinoptilolite and mordenite, Microporous Mesoporous Mater., 2006, 87, 243.
  • [12] JCPDS files card Nos. 025-1349 (2000).
  • [13] SAITO A., FOLEY H.C., Curvature and parametric sensitivity in models for adsorption in micropores, AIChE J., 1991, 37, 429.
  • [14] IUPAC reporting physisorption data for gas/solid systems, Pure Appl. Chem., 1985, 57, 611.
  • [15] HERNANDEZ M.A., ROJAS F., LARA V.H., Nitrogen-sorption characterization of the microporous structure of clinoptilolite-type zeolites, J. Porous Mater., 2000, 7, 443.
  • [16] OLIVEIRA C.R.,RUBIO J., Isopropylxanthate ions uptake by modified natural zeolite and removal by dissolved air flotation, Int. J. Miner. Process., 2000, 90, 21.
  • [17] BARRER R.M., MAICICI M.B., Molecular sieve sorbents from clinoptilolite, Can. J. Chem., 1964, 42, 1461.
  • [18] CAKICIOGLU-OZKAN F.,ULKU S.,The effect of HCl treatment on water vapor adsorption characteristics of clinoptilolite rich natural zeolite, Microporous Mesoporous Mater., 2005, 77, 47.
  • [19] WILSON M.J., Clay Mineralogy: Spectroscopic and Chemical Determinative Methods, Chapman and Hall, New York, 1994.
  • [20] TANAKA H., YAMASAKI N., MURATANI M., HINO R., Structure and formation process of (K, Na)- clinoptilolite, Mater. Res. Bull., 2003, 38, 713.
  • [21] OLAD A., NASERI B., Preparation, characterization and anticorrosive properties of a novel polyaniline/clinoptilolite nanocomposite, Prog. Org. Coatings, 2010, 67, 233.
  • [22] PERRAKI T.,ORFANOUDAKI A., Mineralogical study of zeolites from Pentalofos area, Appl. Clay Sci., 2004, 25, 9.
  • [23] TARASEVICH YU.I., POLYAKOVA I.G, POLYAKOV V.E., Microcalorimetric study of the interaction between water and cation-substituted clinoptilolite, Colloid J., 2003, 65, 493.
  • [24] KOWALCZYK P.,SPRYNSKYY M.,TERZYK A.P.,LEBEDYNETS M.,NAMIESNIK J.,BUSZEWSKI B.,Porous structure of natural and modified clinoptilolites, J. Colloid Interface Sci., 2006, 297, 77.
  • [25] YAMAMOTO S., SUGIYAMA S., MATSUOKA O., KOHMURA K., HONDA T.,BANNO Y., NOZOYE H., Dissolution of zeolite in acidic and alkalin eaqueous solutions as revealed by AFM imaging, J. Phys.Chem., 1996, 100, 18474.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-54593e96-a775-4615-97b2-ee4c23d65013
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