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Warianty tytułu
Bezodpadowe spalania węgla ekibastuz i utylizacja dwutlenku węgla w gazach odlotowych
Języki publikacji
Abstrakty
The production activity of mankind using high-ash fossil fuels for electricity generation is steadily increasing ash waste and carbon dioxide emissions into the environment. The article proposes a variant of wasteless combustion of Ekibastuz coal in a melting reactor installed under the boiler; it is envisaged to obtain, in addition to steam of energy parameters, a melt suitable for the production of building materials, sublimates of zinc, gallium and germanium, to reduce emissions of CO2 into the atmosphere and return to the process a part of carbon in CO2. An energy-saving thermal diagram of a power plant boiler has been developed on the basis of the proposed technology for the reduction of СО2, Н2О of reactor waste gases with zinc vapor to СО, Н2. The resulting excessive hydrogen will be used to displace elemental carbon from CO. The spent reagent, zinc oxide, after recovering into zinc will be used again in the process. In case of implementation, CO2 emissions into the atmosphere will be cut up to 50%, the expected payback period of the proposed system will be 1.0 - 1.5 years.
Działalność produkcyjna ludzkości wykorzystująca wysokopopiołowe paliwa kopalne do produkcji energii elektrycznej stale zwiększa ilość odpadów popiołowych i emisję dwutlenku węgla do środowiska. W artykule zaproponowano wariant bezodpadowego spalania węgla Ekibastuz w reaktorze zainstalowanym pod kotłem; przewiduje się uzyskanie, oprócz pary o parametrach energetycznych, stopu odpowiedniego do produkcji materiałów budowlanych, sublimatów cynku, galu i germanu, a w celu zmniejszenia emisji CO2 do atmosfery i powrotu do procesu części węgla zawartego w CO2. Na podstawie zaproponowanej technologii redukcji СО2 i Н2О w gazach odlotowych z reaktora z parą cynku do СО i Н2 opracowany został energooszczędny schemat cieplny kotła w elektrowni. Powstała nadmierna ilość wodoru zostanie wykorzystana do wyparcia węgla pierwiastkowego z CO. Zużyty reagent, tlenek cynku, po odzyskaniu cynku zostanie ponownie wykorzystany w procesie. W przypadku wdrożenia, emisja CO2 do atmosfery zostanie zmniejszona do 50%, oczekiwany okres zwrotu z proponowanego systemu będzie wynosić 1,0 - 1,5 roku.
Wydawca
Czasopismo
Rocznik
Tom
Strony
71--76
Opis fizyczny
Bibliogr. 24 poz., fig.
Twórcy
autor
- Department of Thermal Power Engineering, S. Seifullin Kazakh Agro Technical University, Nur-Sultan, Kazakhstan
autor
- Warsaw University of Technology, Power and Aeronautical Engineering Faculty, Institute of Heat Engineering
autor
- Department of Heat Power Engineering, University of Energy and Communications, Almaty, Kazakhstan
autor
- Energy Department, S. Seifullin Kazakh Agrotechnical University, Astana, Republic of Kasakhstan
Bibliografia
- [1] Blyda I. A., Slyusarenko L. I., Abisheva Z.: Ash and slag waste from the power industry - raw material for the production of rare metals and alumina. Complex use of mineral raw materials. - No. 4. - 2008. - P. 39-51. (in Russ).
- [2] Koshumbaev M. B.: Processing of industrial and household waste. Tutorial. - Astana. 2018.270p. (in Russ).
- [3] Composition and slagging properties of Ekibastuz Coal’s ash A.N. Alekhanovich, V.V. Bogomolov; Heat Power Engineering. 1999.- No. 5.- P.29-31. (in Russ).
- [4] Mikhailov Yuri Leonidovich.: Physicochemical studies of the processes of leaching of microcomponents of ash from coal combustion in the Ekibastuz basin. Abstract of the thesis for the degree of candidate of chemical sciences. - 2008. - Omsk. 29p. (in Russ).
- [5] Dikhanbaev B.I., Zharmenov A.A., Telbaev S.A., Romanov G.A., Terlikbaeva A.Zh., Saveliev A.G., Dikhanbaev A.B.: Method of processing zinc-containing products. A.C. No. 30040. Republic of Kazakhstan. publ. May 21, 2002. (in Russ).
- [6] Dikhanbaev A.B., Dikhanbaev B.I.: Predictive characteristics of the installation for the processing of dump zinc-containing slag. Proceedings of the international scientific research, practical conf. Perspective directions of development of chemistry and chemical technology. –Shymkent, 1999. –P.137-138 (in Russ).
- [7] Dikhanbaev B., DikhanbaevА., Chandima G. Energy Efficient System for Galena Concentrate Processing. IEEEAccess, Volume 7, 2019. NewJersey, USA. PP. 23388-23395Digital Object Identifier 10.1109/ACCESS.2019.2895591.
- [8] Dikhanbaev B., DikhanbaevА., Chandima G.Energy-saving method for technogenic waste processing. Journal PLoS ONE 12(12):e0187790. IF – 3.54. - San Francisco, California, USA. 2017. – December 27, – P.1-16.https://doi.org/10.1371/journal.pone.0187790
- [9] Dikhanbaev A.B. Dikhanbaev B. Prospects of waste-free combustion of Ekibastuz coal under the boiler of thermal power plants. Proceedings of the VII International scientific and practical conference "Academic science - problems and achievements - 2015, - North Charleston, USA, -V.2 - P .211-217. (in Russ).
- [10] Fanchi, John R; Fanchi, Christopher J (2016). Energy in the 21st Century. World Scientific Publishing Co Inc. p. 350. ISBN 978-981-314-480-4.
- [11] [IPCC, 2005] IPCC special report on Carbon Dioxide Capture and Storage. Prepared by working group III of the Intergovernmental Panel on Climate Change. Metz, B., O. Davidson, H. C. de Coninck, M. Loos, and L.A. Meyer (eds.). Cambridge University Press, Cambridge, United Kingdom and New York, NY, USA, 442 pp. Available in full at www.ipcc.chArchived 2010-02-10 at the Wayback Machine (PDF - 22.8MB). Grantham 2019, p. 9.
- [12] Rhodes, J. S.; Keith, D. W. (2008). Biomass with capture: Negative emissions within social and environmental constraints: An editorial comment. Climatic Change. 87 (3–4): 321–328. doi:10.1007/s10584-007-9387-4.
- [13] Werner, Constanze; Schmidt, Hans-Peter; Gerten, Dieter; Lucht, Wolfgang; Kammann, Claudia (2018). Biogeochemical potential of biomass pyrolysis systems for limiting global warming to 1.5° C. Environmental Research Letters. 13 (4): 044036. doi:10.1088/1748-9326/aabb0e.
- [14] Phelps, J; Blackford, J; Holt, J; Polton, J (2015), Modelling Large-Scale CO2 Leakages in the North Sea, International Journal of Greenhouse Gas Control, 38: 210–220, doi:10.1016/j.ijggc.2014.10.013
- [15] Sumida, Kenji; Rogow, David L.; Mason, Jarad A.; McDonald, Thomas M.; Bloch, Eric D.; Herm, Zoey R.; Bae, Tae-Hyun; Long, Jeffrey R. (2012). Carbon Dioxide Capture in Metal–Organic Frameworks. Chemical Reviews. 112 (2): 724–781. doi:10.1021/cr2003272. PMID 22204561.
- [16] Bryngelsson, Mårten; Westermark, Mats (2009). CO2 capture pilot test at a pressurized coal fired CHP plant. Energy Procedia. 1: 1403–1413. doi:10.1016/j.egypro.2009.01.184.
- [17] Michael E. Wieser, Norman Holden, Tyler B. Coplen, John K. Böhlke, Michael Berglund, Willi A. Brand, Paul De Bièvre, Manfred Gröning, Robert D. Loss, Juris Meija, Takafumi Hirata, Thomas Prohaska, Ronny Schoenberg, Glenda O’Connor, Thomas Walczyk, Shige Yoneda, Xiang‑Kun Zhu. Atomic weights of the elements 2011 (IUPAC Technical Report) (англ.). Pure and Applied Chemistry. — 2013. — Vol. 85, no. 5. — P. 1047—1078. — doi:10.1351/PAC-REP-13-03-02
- [18] OutokumpuHSC Chemistry for Windows. Chemical Reaction and Equilibrium Software with Extensive Thermochemical Database. Version 5.1. October 31, 2002.
- [19] Application No. 67883 - RK patent for invention. Method of utilization of carbon dioxide in waste gases of units. A.B. Dikhanbaev, B.I. Dikhanbaev. Publ. 07/01/2020. (in Russ).
- [20] Baubekov K.T. Hazardous emissions in combustion products of gas-oil boilers (correlation analysis and pilot studies). - Astana: KATU named after S. Seifullin, 2017 .-- 384 p. (in Russ).
- [21] Baubekov K.T. Technological methods for reducing the toxicity of emissions and prospects for the development of environmentally friendly gas-oil boilers (review of problems, analytical and industrial research). - Astana: KATU named after S. Seifullin, 2016 .-- 237 p. (in Russ).
- [22] Baubekov K.T. Improving the environmental safety of gas-oil boilers. Lambert Academic Publishing. Germany, 2018 .-- 283 p. (in Russ).
- [23] Baubekov K.T. Innovative combustion technologies in gas-oil boilers (review of problems, analytical and industrial studies). Lambert Academic Publishing. Germany, 2018 .-- 384 p. (in Russ).
- [24] Dikhanbaev, B., DIKHANBAEV, A. B., Sultan, I., & Rusowicz, A.: Development of hydrogen-enriched water gas production technology by processing Ekibastuz coal with technogenic waste. Archive of Mechanical Engineering, LXV(2), 2018, 221–231. http://doi.org/10.24425/123022
Typ dokumentu
Bibliografia
Identyfikator YADDA
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