Anchoring tri(8-quinolinolato)iron onto SBA-15 for partial oxidation of benzyl alcohol using water as the solvent

• Autorzy: Yang X. , Liu J. , Kan Q , Guan J.

Identyfikatory

DOI

10.2478/pjct-2014-0043

• Języki publikacji: EN

Abstrakty

EN

Tri(8-quinolinolato)iron complex immobilized onto SBA-15 catalyst has been synthesized through a stepwise procedure. The characterization results indicated that the BET surface area, total pore volume and average pore width decrease after stepwise modification of SBA-15, while the structure keeps intact. Catalytic tests showed that FeQ3-SBA-15 catalyzes the oxidation reaction well with 34.8% conversion of benzyl alcohol and 74.7% selectivity to benzaldehyde when water is used as the solvent after 1 h reaction. In addition, homogeneous catalyst tri(8-quinolinolato)iron exhibits very bad catalytic behavior using water as the solvent.

Słowa kluczowe

EN

SBA-15; 8-quinolinol; iron; benzyl alcohol; benzaldehyde

• Wydawca: West Pomeranian University of Technology. Publishing House
• Czasopismo: Polish Journal of Chemical Technology
• Rocznik: 2014
• Tom: Vol. 16, nr 3
• Strony: 12--17
• Opis fizyczny: Bibliogr. 34 poz., wykr., wz.

Twórcy

autor

Yang X.

• Jilin University, Key Laboratory of Surface and Interface Chemistry of Jilin Province, College of Chemistry, Changchun,130023, PR China

autor

Liu J.

• Jilin University, Key Laboratory of Surface and Interface Chemistry of Jilin Province, College of Chemistry, Changchun,130023, PR China

autor

Kan Q

• Jilin University, Key Laboratory of Surface and Interface Chemistry of Jilin Province, College of Chemistry, Changchun,130023, PR China

autor

Guan J.

• Jilin University, Key Laboratory of Surface and Interface Chemistry of Jilin Province, College of Chemistry, Changchun,130023, PR China

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