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Anchoring tri(8-quinolinolato)iron onto SBA-15 for partial oxidation of benzyl alcohol using water as the solvent

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Języki publikacji
EN
Abstrakty
EN
Tri(8-quinolinolato)iron complex immobilized onto SBA-15 catalyst has been synthesized through a stepwise procedure. The characterization results indicated that the BET surface area, total pore volume and average pore width decrease after stepwise modification of SBA-15, while the structure keeps intact. Catalytic tests showed that FeQ3-SBA-15 catalyzes the oxidation reaction well with 34.8% conversion of benzyl alcohol and 74.7% selectivity to benzaldehyde when water is used as the solvent after 1 h reaction. In addition, homogeneous catalyst tri(8-quinolinolato)iron exhibits very bad catalytic behavior using water as the solvent.
Słowa kluczowe
Rocznik
Strony
12--17
Opis fizyczny
Bibliogr. 34 poz., wykr., wz.
Twórcy
autor
  • Jilin University, Key Laboratory of Surface and Interface Chemistry of Jilin Province, College of Chemistry, Changchun,130023, PR China
autor
  • Jilin University, Key Laboratory of Surface and Interface Chemistry of Jilin Province, College of Chemistry, Changchun,130023, PR China
autor
  • Jilin University, Key Laboratory of Surface and Interface Chemistry of Jilin Province, College of Chemistry, Changchun,130023, PR China
autor
  • Jilin University, Key Laboratory of Surface and Interface Chemistry of Jilin Province, College of Chemistry, Changchun,130023, PR China
Bibliografia
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Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-52668779-5555-44eb-8219-56f905ce4775
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