Synthesis of molecularly printed methyl methacrylate-based polymers for the detection of di(2-ethylhexyl) phthalate and dibutyl phthalate

• Autorzy: Fauziah St , Soekamto Nunuk Hariani , Prastawa Budi , Rasyid Herlina , Haedar Nur , Hustim Muraalia , Marlina Marlina , Sulaiman Magfirah , Sapar Ajuk

Identyfikatory

DOI

10.14314/polimery.2023.7.7

Warianty tytułu

PL

Synteza polimerów na bazie metakrylanu metylu z nadrukiem molekularnym do wykrywania ftalanu di(2-etyloheksylu) i ftalanu dibutylu

• Języki publikacji: EN

Abstrakty

EN

Molecularly imprinted polymers (MIP) were obtained by precipitation polymerization for the detection of DEHP and DBP from polymer packaging in drinking water. MIP was obtained by cross-linking DEHP and DBP with methyl methacrylate (MMA) and trimethylolpropane trimethacrylate (TRIM). FTIR, SEM-EDS, UV-Vis and SAA were used to determine properties of polymers (MIP_DEHP, MIP_DBP). The obtained materials were characterized by a mesoporous structure with small, uniform, and porous grains. The surface area and total pore volume of MIP_DEHP were more than twice smaller than MIP_DBP, with a slightly larger pore diameter. Lower C content may indicate the formation of MIP_DEHP and MIP_DBP. The FTIR method confirmed the presence of functional groups –CH, –CO, –C=C and –C=O. The adsorption capacity of MIP_DEHP and MIP_DBP was 0.68 mg/g and 1.06 mg/g, respectively, and was consistent with the Freundlich isothermal adsorption model.

PL

Streszczenie: Metodą polimeryzacji strąceniowej otrzymano polimery z nadrukiem molekularnym (MIP) do wykrywania DEHP i DBP z opakowań polimerowych w wodzie pitnej. MIP otrzymano poprzez sieciowanie DEHP i DBP metakrylanem metylu (MMA) i trimetakrylanem trimetylolopropanu (TRIM). Do oceny właściwości polimerów (MIP_DEHP, MIP_DBP) zastosowano FTIR, SEM-EDS, UV-Vis i SAA. Otrzymane materiały charakteryzowały się mezoporowatą strukturą o małych, jednolitych i porowatych ziarnach. Pole powierzchni i całkowita objętość porów MIP_DEHP były ponad dwukrotnie mniejsze niż MIP_DBP, przy nieznacznie większej średnicy porów. Mniejsza zawartość C może świadczyć o tworzeniu się MIP_DEHP i MIP_DBP. Metodą FTIR potwierdzono obecność grup funkcyjnych -CH, –CO, –C=C i –C=O. Zdolność adsorpcyjna MIP_DEHP i MIP_DBP wynosiła odpowiednio 0,68 mg/g i 1,06 mg/g i była zgodna z izotermicznym modelem adsorpcji Freundlicha.

Słowa kluczowe

EN

molecularly imprinted polymers; phthalates; methyl methacrylate; trimethylolpropane trimethacrylate

PL

polimery z nadrukiem molekularnym; ftalany; metakrylan metylu; trimetakrylan trimetylolopropanu

• Wydawca: Sieć Badawcza Łukasiewicz – Instytut Chemii Przemysłowej
• Czasopismo: Polimery
• Rocznik: 2023
• Tom: Vol. 68, nr 7-8
• Strony: 413--423
• Opis fizyczny: Bibliogr. 34 poz., rys., tab., wykr.

Twórcy

autor

Fauziah St

• Department of Chemistry, Faculty of Mathematics and Natural Sciences, University of Hasanuddin, Makassar, 90245 Indonesia

• https://orcid.org/0000-0002-0599-4011

autor

Soekamto Nunuk Hariani

• Department of Chemistry, Faculty of Mathematics and Natural Sciences, University of Hasanuddin, Makassar, 90245 Indonesia

• https://orcid.org/0000-0001-8281-1752

autor

Prastawa Budi

• Department of Chemistry, Faculty of Mathematics and Natural Sciences, University of Hasanuddin, Makassar, 90245 Indonesia

• https://orcid.org/0000-0002-1266-5232

autor

Rasyid Herlina

• Department of Chemistry, Faculty of Mathematics and Natural Sciences, University of Hasanuddin, Makassar, 90245 Indonesia

• https://orcid.org/0000-0001-9136-9716

autor

Haedar Nur

• Department of Biology, Faculty of Mathematics and Natural Sciences, University of Hasanuddin, Makassar, 90245 Indonesia

• https://orcid.org/0000-0002-6200-298X

autor

Hustim Muraalia

• Department of Environmental Engineering, Faculty of Engineering, University of Hasanuddin, Makassar, 90245 Indonesia

• https://orcid.org/0000-0001-8323-1549

autor

Marlina Marlina

• Department of Chemistry, Faculty of Mathematics and Natural Sciences, University of Hasanuddin, Makassar, 90245 Indonesia

• https://orcid.org/0009-0008-0629-7614

autor

Sulaiman Magfirah

• Department of Chemistry, Faculty of Mathematics and Natural Sciences, University of Hasanuddin, Makassar, 90245 Indonesia

• https://orcid.org/0009-0009-5156-7844

autor

Sapar Ajuk

• Department of Chemistry, Faculty of Mathematics and Natural Sciences, University of Tanjungpura, Pontianak, 78124 Indonesia

• https://orcid.org/0000-0002-7278-6159

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Uwagi

Opracowanie rekordu ze środków MNiSW, umowa nr SONP/SP/546092/2022 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2024).