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Vibrational, electrical, dielectric and optical properties of PVA-LiPF6 solid polymer electrolytes

Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Solid polymer electrolytes based on polyvinyl alcohol (PVA) doped with LiPF6 have been prepared using solution casting technique. Electrical properties of prepared electrolyte films were analyzed using AC impedance spectroscopy. The ionic conductivity was found to increase with increasing salt concentration. The maximum conductivity of 8.94 × 10-3 S∙cm-1 was obtained at ambient temperature for the film containing 20 mol% of LiPF6. The conductivity enhancement was correlated to the enhancement of available charge carriers. The formation of a complex between the polymer and salt was confirmed by Fourier transform infrared spectroscopy (FT-IR). The optical nature of the polymer electrolyte films was analyzed through UV-Visspectroscopy.
Wydawca
Rocznik
Strony
331--337
Opis fizyczny
Bibliogr. 25 poz., tab., rys.
Twórcy
autor
  • Centre for Scientific and Applied Research, PSN College of Engineering and Technology, Melathediyoor, Tirunelveli 627 152, Tamil Nadu, India
  • Centre for Scientific and Applied Research, PSN College of Engineering and Technology, Melathediyoor, Tirunelveli 627 152, Tamil Nadu, India
Bibliografia
  • [1] VITO D.N., SANDRA L., GUINEVERE A., GIFFIN E.N., Electrochim. Acta, 57 (2011), 4.
  • [2] AWALENDRA K.T., HASHMI S.A., Solid State Ionics, 181 (2010), 1270.
  • [3] HIRANKUMAR G., SELVASEKARAPANDIAN S., KUWATA N., KAWAMURA J., HATTORI T., J. Power Sources, 144 (2005), 262.
  • [4] HIRANKUAMR G., SELVASEKARAPANDIAN S., BHUVANESHWARI M.S., BASKARAN R., VIJAYAKUMAR M.S., Ionics, 10 (2004), 135.
  • [5] HEMA M., SELVASEKERAPANDIAN S., HIRANKUMAR G., Ionics, 13 (2007), 483.
  • [6] HEMA M., SELVASEKERAPANDIAN S., HIRANKUMAR G., SAKUNTHALA A., ARUNKUMAR D., NITHYA H., J. Phys. Chem. Solids, 70 (2009), 1098.
  • [7] RAJESWARI N., SELVASEKARAPANDIAN S., KARTHIKEYAN S., SANJEEVIRAJA C., IWAI Y., KAWAMURA J., Ionics, 19 (2013), 1105.
  • [8] LAWAL S., HASHIM M.A., MASBUDI B.B., J. Mat. Sci. Res., 3 (2014), 48.
  • [9] ANJI R.P., RANVEER K., Chinese J. Polym. Sci., 31 (2013), 641.
  • [10] RAMYA C.S., SAVITHA T., SELVASEKARA PANDIAN S., HIRANKUMAR G., Ionics 11 (2005), 436.
  • [11] RATHOD S G., BHAJANTRI R.F., RAVINDRACHARY V., PUJARI P.K., SHEELA T., J. Adv. Dielect., 4 (2014), 145003.
  • [12] RAJESWARI N., SELVASEKARAPANDIAN S., KARTHIKEYAN S., NITHYA H., SANJEEVIRAJA C., Int. J. Polym. Mater. PO., 61 (2011), 1164.
  • [13] VARISHETTY M M., WEILIANG Q., YUAN G., WEN C., Polym. Eng. Sci., 50 (2010), 878.
  • [14] CHATTERJEE B., KULSHRESTHA N., GUPTA P.N., Int. J. Eng. Res. Appl., 5 (2015), 116.
  • [15] HIRANKUMAR G., SELVASEKARAPANDIAN S., BHUVANESWARI M.S., BASKARAN R., VIJAYAKUMAR M., J. Solid State Electrochem., 10 (2006), 193.
  • [16] MOUAD D., DAVID V., FOUAD G., JOHAN J., FRANC¸OIS T.V., DANIEL L., ME´RIE `M A., Ind. Eng. Chem. Res., 51 (2012), 5240.
  • [17] SURIANI I., MOHD R. J., Int. J. Electrochem. Sci., 6 (2011), 5565.
  • [18] IBRAHIM S., YASSIN M.M., AHMAD R., JOHAN M.R., Ionics 17, (2011) 399.
  • [19] LIEW C.W., RAMESH, S., RAMESH, K., AROF A.K., J. Solid State Electrochem., 16 (2012), 1869.
  • [20] AHN J.H., WANG G.X., LIU H.K., DOU S.X., J. Power Sources, 119 (2003), 422.
  • [21] VIJAYA N., SELVASEKARAPANDIAN S., HIRANKUMAR G., KARTHIKEYAN S., NITHYA H., RAMYA C. S., PRABU M., Ionics, 18 (2012), 91.
  • [22] MANINDRA K., NEELAM S., Ionics 21 (2014), 1301.
  • [23] AZIZ S. B., ABIDIN Z. H. Z., AROF A. K., Express Polym. Lett., 4 (2010), 300.
  • [24] GUOFA C., JIANGXIN W., POOI S. L., Acc. Chem. Res., 49 (2016), 1469.
  • [25] HAMED M. A., SABAH H. S., SARKAWT A. H., Asian Trans. Sci. Technol., 6 (2012), 16.
Uwagi
PL
Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2019).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-51675793-801b-4337-8ce1-0e4ea9a34082
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