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Investigation of glycerol doping on ignition delay times and laminar burning velocities of gasoline and diesel fuel

Treść / Zawartość
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Glycerol is a major by-product of biodiesel production. Per one tone of produced biodiesel, one hundred kilograms of glycerol is produced. Production of glycerol is increasing due to increase of demand for biodiesel. One of methods of glycerol utilization is combustion. Recent experimental studies with use of a diesel engine and a constant volume combustion chamber show that utilization of glycerol as a fuel results in lower NOx emissions in exhaust gases. It combusts slower than light fuel oil, what is explained by higher viscosity and density of glycerol. Glycerol has low cetane number, so to make combustion in a diesel engine possible at least one of the following conditions need to be fulfilled: a pilot injection, high temperature or high compression ratio. The aim of the paper is to compare glycerol to diesel and to assess influence of glycerol doping on gasoline and diesel fuel in dependence of pressure, temperature and equivalence ratio. The subject of this study is analysis of basic properties of flammable mixtures, such as ignition delay times and laminar burning velocities of primary reference fuels (diesel: n-heptane and gasoline: iso-octane). Calculations are performed with use of Cantera tool in Matlab and Python environments. Analyses of influence of glycerol on ignition delay times of n-heptane/air and iso-octane/air mixtures covered wide range of conditions: temperatures from 600 to 1600 K, pressure 10-200 bar, equivalence ratio 0.3 to 14, molar fraction of glycerol in fuel 0-1 in air. Simulations of LBV in air cover temperatures: 300 K and 500 K, pressures: 10, 40, 100, 200 bar and equivalence ratio from 0.3 to 1.9. Physicochemical properties of gasoline, diesel and glycerol are compared.
Czasopismo
Rocznik
Strony
167--175
Opis fizyczny
Bibliogr. 31 poz., wykr.
Twórcy
autor
  • Faculty of Power and Aeronautical Engineering at Warsaw University of Technology
autor
  • Faculty of Power and Aeronautical Engineering at Warsaw University of Technology
  • Faculty of Power and Aeronautical Engineering at Warsaw University of Technology
Bibliografia
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  • [12] DUPONT, C. et al. Biomass pyrolysis: kinetic modelling and experimental validation under high temperature and flash heating rate conditions. J. Anal. Appl. Pyrolysis. 2009, 85(1-2), 260-267.
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  • [14] HEMINGS, E.B., CAVALLOTTI, C., CUOCI, A. et al. A detailed kinetic study of pyrolysis and oxidation of glycerol (propane-1,2,3-triol). Combust. Sci. Technol. 2012, 184(7-8), 1164-1178.
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  • [18] HARTMANN, M., GUSHTEROVA, I., FIKRI, M. et al. Auto-ignition of toluene-doped n-heptane and iso-octane/air mixtures: high-pressure shock-tube experiments and kinetics modeling. Combust. Flame. 2011, 158(1), 172-178.
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  • [20] GOODWIN, D.G., MOFFAT, H., SPETH, R.L. Cantera: an object-oriented software toolkit for chemical kinetics, thermodynamics, and transport processes. 2017.
  • [21] JERZEMBECK, S., PETERS, N., PEPIOT-DESJARDINS, P., PITSCH, H. Laminar burning velocities at high pressure for primary reference fuels and gasoline: experimental and numerical investigation. Combust. Flame. 2009, 156(2), 292-301.
  • [22] LIU, Y., JIA, M., XIE, M., PANG, B. Improvement on a skeletal chemical kinetic model of iso-octane for internal combustion engine by using a practical methodology. Fuel. 2013, 103, 884-891.
  • [23] BARABÁS, I., TODORUŢ, I.A. Predicting the temperature dependent viscosity of biodiesel-diesel-bioethanol blends. Energy and Fuels. 2011, 25(12), 5767-5774.
  • [24] KUMAR, P., KISHAN, P.A., DHAR, A. Numerical investigation of pressure and temperature influence on flame speed in CH4-H2 premixed combustion. Int. J. Hydrogen Energy. 2016, 41(22), 9644-9652.
  • [25] CHENG N.-S. Formula for the viscosity of a glycerol−water mixture. Ind. Eng. Chem. Res. 2008, 47(9), 3285-3288.
  • [26] GRAB-ROGALINSKI, K., SZWAJA, S. The combustion properties analysis of various liquid fuels based on crude oil and renewables. IOP Conf. Ser. Mater. Sci. Eng. 2016, 148, 12066.
  • [27] KANAVELI, I.-P., ATZEMI, M., LOIS, E. Predicting the viscosity of diesel/biodiesel blends. Fuel. 2017, 199, 248-263.
  • [28] STEIN, R.A. et al. Effect of heat of vaporization, chemical octane, and sensitivity on knock limit for ethanol – gasoline blends. SAE Int. J. Fuels Lubr. 2012, 5(2), 2012-01-1277.
  • [29] QUISPE, C.A.G., CORONADO, C.J.R., CARVALHO, J.A. Glycerol: production, consumption, prices, characterization and new trends in combustion. Renew. Sustain. Energy Rev. 2013, 27, 475-493.
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  • [31] ALPTEKIN, E., CANAKCI, M. Characterization of the key fuel properties of methyl ester-diesel fuel blends. Fuel. 2009, 88(1), 75-80.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-50c6fff1-2da2-42f7-9a0f-d77ef17bd5b8
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