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Purpose: Application of plasma glow discharge to copper oxide nanostructure growth is studied. The simplicity of the proposed technique may be beneficial for the development of new plasma reactors for large-scale production of diverse metal oxide nanostructures. Design/methodology/approach: Copper sample was placed on anode of a setup designed to ignite plasma glow discharge. The proposed approach allows eliminating the negative effects of ion bombardment, like sputtering and generation of defects on a surface of the growing nanostructures, but preserves the advantages of thermal growth. The growth process was explained in terms of thermal processes interaction occurring on a surface of the anode with the glow discharge plasma. Findings: Plasma treatment resulted in generation of reach and diverse nanostructures that was confirmed by SEM images. Nanowire-like, flower-like, anemone-like nanostructures and nanodisks composed into the nanoassemblies are observed; the nanostructures are associated with microbabbles on CuO layer. These findings allow concluding about the possible implementation of the proposed method in industry. Research limitations/implications: The main limitation is conditioned by the lack of heat supplied to the anode, and absence of independent control of the heat and ion fluxes; thus, the additional heater should be installed under the anode in order to expand the nomenclature of the nanospecies in the future studies. Practical implications: High-productivity plasma process in copper oxide nanostructures synthesis was confirmed in this research. It may be applied for field emitter and supercapacitor manufacturing. Originality/value: Oxide nanostructure synthesis is conducted by use of a simple and well-known glow discharge technique in order to expand the production yield and diversity of nanostructure obtained in the processes of thermal growth.
Wydawca
Rocznik
Tom
Strony
24--33
Opis fizyczny
Bibliogr. 39 poz.
Twórcy
autor
- Plasma Laboratory, Faculty of Aircraft Engines, National Aerospace University, Kharkiv 61070, Ukraine
autor
- Plasma Laboratory, Faculty of Aircraft Engines, National Aerospace University, Kharkiv 61070, Ukraine
autor
- Plasma Laboratory, Faculty of Aircraft Engines, National Aerospace University, Kharkiv 61070, Ukraine
autor
- Plasma Laboratory, Faculty of Aircraft Engines, National Aerospace University, Kharkiv 61070, Ukraine
Bibliografia
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- [19] Q. Cheng, W. Yan, L. Randeniya, F. Zhang, K. Ostrikov, Plasma-produced phase-pure cuprous oxide nanowires for methane gas sensing, Journal of Applied Physics 115 (2014) 124310. DOI: https://doi.org/10.1063/1.4869435
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- [22] S.H. Mohamed, K.M. Al-Mokhtar, Characterization of Cu2O/CuO nanowire arrays synthesized by thermal method at various temperatures, Applied Physics A 124/7 (2018) 493. DOI: https://doi.org/10.1007/s00339-018-1914-9
- [23] R. Sondors, J. Kosmaca, G. Kunakova, L. Jasulaneca, M.M. Ramma, R. Meija, E. Kauranens, M. Antsov, D. Erts, Size Distribution, Mechanical and Electrical Properties of CuO Nanowires Grown by Modified Thermal Oxidation Methods, Nanomaterials 10/6 (2020) 1051. DOI: https://doi.org/10.3390/nano10061051
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- [27] A. Kumar, A.K. Srivastava, P. Tiwari, R.V. Nandedkar, The effect of growth parameters on the aspect ratio and number density of CuO nanorods, Journal of Physics: Condensed Matter 16 (2004) 8531-8543. DOI: https://doi.org/10.1088/0953-8984/16/47/007
- [28] A. Li, H. Song, J. Zhou, X. Chen, S. Liu, CuO Nanowire Growth on Cu2O by in situ Thermal Oxidation in Air, CrystEngComm 42/15 (2013) 8559- 8564. DOI: https://doi.org/10.1039/C3CE40985F
- [29] B.J. Hansen, H. Chan, J. Lu, G. Lu, J. Chen, Short- Circuit Diffusion Growth of Long Bi-Crystal CuO Nanowires, Chemical Physics Letters 504/1-3 (2011) 41-45. DOI: https://doi.org/10.1016/j.cplett.2011.01.040
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- [35] A. Altaweel, T. Gries, S. Migot, P. Boulet, A. Mézin, T. Belmonte, Localised growth of CuO nanowires by micro-afterglow oxidation at atmospheric pressure: Investigation of the role of stress, Surface and Coatings Technology 305 (2016) 254-263. DOI: https://doi.org/10.1016/j.surfcoat.2016.08.001
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Uwagi
PL
Opracowanie rekordu ze środków MEiN, umowa nr SONP/SP/546092/2022 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2022-2023).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-50b022cf-8db2-46bc-831d-d9e4e6ee04d1