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Immunizacja wełny metaglinianem sodu
Języki publikacji
Abstrakty
Since the environmental requirements for leather manufacture as well as for other industry branches are becoming stricter, investigations of unhairing have been directed towards conditions of the process which allow the saving of hair: enzymatic unhairing or unhairing with hair immunization conventionally achieved by using lime and sodium sulphide. The problem is that lime forms a big quantity of liquid waste which contains lime sludge polluted by sulphides and protein degradation products. The research is devoted to the replacement of Ca(OH)2 as hair immunization material with some other soluble non-hazardous material with a similar immunization effect. The preliminary tests showed that alkaline sodium aluminate suits this purpose very well. Its immunisation efficiency increases with prolonged treatment duration and increased concentration of the treatment solution. Treatment with 20 g/l of sodium silicate solution for 3 h allows to reach a high immunization ability almost the same as that of calcium hydroxide under the same conditions. The immunisation effect lasts when the pH is approx. 13.
Ponieważ normy dotyczące ochrony środowiska w przemyśle skórzanym, jak również w innych gałęziach przemysłu stają się coraz bardziej restrykcyjne, badano immunizację wełny wodorotlenkami wapnia i potasu oraz metaglinianem sodu, badając poziom degradacji wełny po obróbce. Efekt immunizacji został oszacowany na podstawie zmian utraty masy wełny i zawartości azotu w roztworze. Potwierdzono, że metaglinian sodu jest skutecznym środkiem immunizującym. Skuteczność immunizacji metaglinianem sodu zwiększa się wraz z wydłużeniem czasu obróbki i zwiększeniem stężenia roztworu.
Czasopismo
Rocznik
Strony
42--46
Opis fizyczny
Bibliogr. 25 poz., rys., tab.
Twórcy
autor
- JSC Plungės kooperatinė prekyba “Viciunai group”, Birutes str. 50, Plunge LT-90112, Lithuania
autor
- Kaunas University of Technology, Department of Polymer Chemistry and Technology, Radvilėnų pl. 19, Kaunas LT-50254, Lithuania
autor
- Kaunas University of Technology, Department of Physical and Inorganic Chemistry, Radvilėnų pl. 19, Kaunas LT-50254, Lithuania
autor
- Kaunas University of Technology, Department of Polymer Chemistry and Technology, Radvilėnų pl. 19, Kaunas LT-50254, Lithuania
autor
- Kaunas University of Technology, Department of Physical and Inorganic Chemistry, Radvilėnų pl. 19, Kaunas LT-50254, Lithuania
Bibliografia
- 1. Cranston RW, Davis M, Scroggie J.G. Development of the “sirolime” unhairing process. J Am Leather Chem As 1986; 81: 347-355.
- 2. Thanikaivelan P, Rao JR, Nair BU, Ramasami T. Zero Discharge Tanning: A Shift from Chemical to Biocatalytic Leather Processing. Environ Sci Technol 2002; 6: 4187-4194.
- 3. Karthikeyan R, Balaji S, Sehgal PK. Industrial applications of keratins – A review. J Sci Ind Res India 2007; 66: 710-715.
- 4. Dettmer A, Cavalli E, Ayub MAZ, Gutterres M. Environmentally friendly hide unhairing: enzymatic hide processing for the replacement of sodium sulfide and deliming. J Clean Prod 2013; 47: 11-18.
- 5. Wang R, Min C, Haiming C, Zhiqiang L. Enzyme unhairing – an eco-friendly biotechnological process. J Soc Leath Tech Ch 2009; 93: 51-55.
- 6. Thanikaivelan P, Rao JR, Nair BU, Ramasami T. Progress and recent trends in biotechnological methods for leather processing. Trends Biotechnol 2004; 22: 181-188.
- 7. Valeika V, Beleska K, Sirvaityte J. Alkali-free method of hide preparation to tanning. Braz J. Chem Eng 2012; 29: 315-323.
- 8. Frendrup W. Hair-save unhairing methods in leather processing (report), US/RAS/92/120. Regional Programme for Pollution Control in the Tanning Industry in South-East Asia, United Nations Industrial Development Organization, 12 September 2000, 7-8, 2000.
- 9. Bienkewicz K. Physical chemistry of leather making. Robert E. Krieger publishing Co. Inc., Malabar, Florida, 1983.
- 10. Heidemann E. Fundamentals of leather manufacturing, Eduard Roetger KG druckerei und Verlag, Darmstadt, 1993.
- 11. Cantera CS. Hair-saving unhairing process Part 2. Immunization phenomenon. J Soc Leath Tech Ch 2001; 85: 1-5.
- 12. Castiello D, Puccini M, Shelly D, Vitolo S. Studies of mono and divalent cations effects on hair immunization J Am Leather Chem As 2007; 102: 341-346.
- 13. Thanikaivelan P, Rao, JR, Nair BU and Ramasami, T. Approach towards zero discharge tanning: Exploration of NaOH based opening up method. J Am Leather Chem As 2001; 96: 222-233.
- 14. Sirvaityte J, Beleska K, Valeika V. Lime free unhairing: Sodium aluminate as an alternative towards a cleaner process J Am Leather Chem As 2016; 111: 406-412.
- 15. Saravanabhavan S, Thanikaivelan P, Rao JR, Nair BU and Ramasamit T. Sodium metasilicate based fiber opening for greener leather processing. Environ Sci Technol 2008; 42:1731-1739.
- 16. Valeika V, Sirvaityte J, Beleska K, Alaburdaite R, Valeikiene V. Immunization action of sodium silicate on hair. J Soc Leath Tech Ch 2015; 99: 223-230.
- 17. Sirvaityte J, Beleska K, Valeikiene V, Plavan V, Valeika V. Immunization action of sodium silicate on hair: Part 2, Hair-save process based on lime substitution by sodium silicate. J Soc Leath Tech Ch 2015; 99: 231-237.
- 18. Strazdas K, Raiselis J, Vaickelionis G. Tirpusis ir skystasis stiklas, Technologija, Kaunas, Lithuania, 2004 (in Lithuanian).
- 19. Golovteeva E, Kutsidi A, Sankin L. Laboratornyj praktikum po khimiyi i tekhnologiyi kozhy i mekha. Legkaiya i Pischevaiya Promyslenost, Moscow, 1982 (in Russian).
- 20. Buika G, Getautis V, Martynaitis V, Rutkauskas K. Spectroscopy of organic compounds. Vitae Litera, Kaunas, Lithuania, 2007 (in Lithuanian).
- 21. Bendit, EG. Infrared absorption spectrum of keratin. I. Spectra of alpha-, beta-, and supercontracted keratin. Biopolymers 1966; 4: 539.
- 22. Kong J and Yu S. Fourier transform infrared spectroscopic analysis of protein secondary structures. Acta Biochim Biophys Sin 2007; 39: 549-559.
- 23. Espinoza EO, Baker BW, Moores TD, Voin D. Forensic identification of elephant and giraffe hair artifacts using HATR FTIR spectroscopy and discriminant analysis, Endanger Species Res 2008; 9: 239-246.
- 24. Lipp-Symonowicz B, Sztajnowski S, Kułak A. (2012). IR Spectroscopy as a Possible Method of Analysing Fibre Structures and Their Changes Under Various Impacts, Infrared Radiation, Dr. Vasyl Morozhenko (Ed.), InTech, DOI: 10.5772/37155. Available from: http://www.intechopen.com/books/infrared-radiation/ir-spectroscopy-as-a-possible-method-of-analysing-fibre-structures-and-their-changes-under-various-i
- 25. Wojciechowska E, Wlochowicz A, Weselucha-Birczyriska A. Application of Fourier-transform infrared and Raman spectroscopy to study degradation of the wool fiber keratin. J Mol Struct 1999; 511-512: 307-318.
Typ dokumentu
Bibliografia
Identyfikator YADDA
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