Preparation and Characterization of Cationic Energetic Salts of 5-Amino-3-[(2,4,6-trinitrophenyl)amino]-1H-1,2,4-triazole (APATO)

• Autorzy: Šarlauskas Jonas , Tamulienė Jelena

Identyfikatory

DOI

10.22211/cejem/154973

• Języki publikacji: EN

Abstrakty

EN

The synthesis and properties of some 5-amino-3-[(2,4,6-trinitrophenyl) amino]-1H-1,2,4-triazole (APATO) cationic salts are described. A detailed structure of one of the salts obtained, 5-amino-3-[(2,4,6-trinitrophenyl)amino]-1H-1,2,4-triazol-4-ium perchlorate (APATO·HClO₄) was characterized using low temperature (173 K) single crystal X-ray diffraction: orthorhombic yellow block, space group ‘Pbc21’, crystal density at 173 K (calculated) and at 293 K (pycnom.) were 1.863 and 1.840 g/cm³, respectively. The APATO salts were characterized by spectroscopic methods and thermal analysis. Preliminary computer calculated energetic characteristics showed that the synthesized salts possess increased energetic characteristics, superior in comparison to the TNT. The APATO perchlorate salt may deserve special attention as a thermostable HEDM.

Słowa kluczowe

EN

1,2,4-triazole-3,5-diamine derivatives; nitrocompounds; X-ray diffraction; 2,4,6-trinitrophenyl derivatives; energetic salts

• Czasopismo: Central European Journal of Energetic Materials
• Rocznik: 2022
• Tom: Vol. 19, no. 3
• Strony: 311--325
• Opis fizyczny: Bibliogr. 25 poz., rys., tab., wykr.

Twórcy

autor

Šarlauskas Jonas

• Institute of Biochemistry, Life Science Center, Vilnius University, Sauletekio av. 7, Vilnius, 10257 Lithuania

• https://orcid.org/0000-0003-4268-1716

autor

Tamulienė Jelena

• Institute of Theoretical Physics and Astronomy, Vilnius University, Sauletekio av. 3, Vilnius, 10222 Lithuania

• https://orcid.org/0000-0002-9473-8932

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