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Purpose: The purpose of this article was to investigate the possibility of the production of Fe-Nb-B bulk metallic alloys with additions of yttrium and zirconium elements. Furthermore, this paper tends to present the structure and selected properties of obtained alloys. In this article the influence of an argon atmosphere on casting process was observed too. Design/methodology/approach: The production attempts were performed on Fe-Nb-B-Zr and Fe-Nb-B-Y system alloys in form of a plate. Master alloy ingots with compositions of Fe72B22Y4Nb2 and Fe71(Nb0.8Zr0.2)6B23 were prepared by induction melting of pure Fe, Nb, B, Y and Fe, Nb, B, Zr elements in an argon atmosphere. The ingots have been crushed and then the investigated material was cast with and without a protective atmosphere. The investigated materials were cast in form of a plate with thickness of 1 mm. The structure analysis of the studied materials in as-cast state was carried out using X-ray diffraction (XRD) and microscopic observation. The thermal properties of the alloys were examined by DSC methods. The measurments of the hardness were performed with the Vickers method. Findings: The Fe-Nb-B-Y and Fe-Nb-B-Zr system alloys in form of a plate were produced by die pressure casting method. The investigation methods revealed that the studied as-cast alloys were crystalline. The structure of the obtained plates is rather fine-grained and there were not found any impurities and undesirable phases inside the materials. The results of calorimetric curves confirm that all tested samples are crystalline. Practical implications: To extend the potential applications of the Fe-based BMGs, amorphous alloys with larger critical sizes and better processability are required. The Fe-Nb-B-Zr and Fe-Nb-B-Y bulk metallic glasses obtained by die pressure casting method can be used for production of telecommunications devices, sensors or low-energy transformers. These materials exhibit excellent mechanical and soft magnetic properties. Originality/value: An overall presentation of an influence of the yttrium and zirconium additions on the attempt of forming Fe72B22Y4Nb2 and Fe71(Nb0.8Zr0.2)6B23 alloys. The chemical composition of these alloys was tested in our laboratory for the first time.
Wydawca
Rocznik
Tom
Strony
222--228
Opis fizyczny
Bibliogr. 15 poz., rys., tab.
Twórcy
autor
- Institute of Engineering Materials and Biomaterials, Silesian University of Technology,ul. Konarskiego 18a, 44-100 Gliwice, Poland
autor
- Institute of Engineering Materials and Biomaterials, Silesian University of Technology,ul. Konarskiego 18a, 44-100 Gliwice, Poland
Bibliografia
- [1] A. Inoue, A. Takeuchi, Recent development and application products of bulk glassy alloy, Acta Materialia 59 (2011) 2243-2267.
- [2] W. Pilarczyk, The study of glass forming ability of Fe-based alloy for welding processes, Journal of Achievements in Materials and Manufacturing Engineering 52/2 (2012) 83-90.
- [3] W. Pilarczyk, J. Podwórny, The study of local structure of amorphous Fe-Co-B-Si-Nb alloy by atomic pair distribution function, Solid State Phenomena 203-204 (2013) 386-389.
- [4] W. Pilarczyk, A. Mucha, The influence of yttrium addition on the GFA of selected iron-based BMG, Archives of Materials Science and Engineering 44/2 (2010) 87-95.
- [5] M. Kucharczyk, The study of structure and properties of Fe-based bulk metallic glasses Fe-B-Zr-Nb and Fe-B-Y-Nb, Master’s Thesis, Silesian University of Technology Library, Gliwice, 2013 (in Polish).
- [6] C. Suryanarayana, A. Inoue, Iron-based bulk metallic glasses, International Materials Reviews 58/3 (2013) 131.
- [7] J.H. Yao, H. Yang, J. Zhang, J.Q. Wanga, The influence of Nb and Zr on glass-formation ability in the ternary Fe-Nb-B and Fe-Zr-B and quaternary Fe-(Nb,Zr)-B alloy systems, Materials Research Society 23/2 (2008) 392-401.
- [8] H.W. Chang, Y.C. Huang, C.W. Chang, C.C. Hsieh, W.C. Chang, Soft magnetic properties and glass formability of Y-Fe-B-M bulk metals (M = Al, Hf, Nb, Ta, and Ti), Journal of Alloys and Compounds, 472 (2009) 166-170.
- [9] X. Cheng, Q. Wang, W.R. Chen, C. Dong, Fe-B-Y-Nb bulk metallic glasses in relation to clusters, Science China Physics, Mechanics and Astronomy 51/4 (2008) 421-426.
- [10] A. Inoue, B. Shen, Formation and soft magnetic properties of Fe-B-Si-Zr bulk glassy alloys with high saturation magnetization above 1.5 T, Materials Transactions 43/9 (2002) 2350-2353.
- [11] D.S. Song, J.H. Kim, E. Fleury, W.T. Kim, D.H. Kim, Synthesis of ferromagnetic Fe-based bulk glassy alloys in the Fe-Nb-B-Y system, Journal of Alloys and Compounds 389 (2005) 159-164.
- [12] Z. Han, J. Zhang, Y. Li, Quaternary Fe-based bulk metallic glasses with a diameter of 5 mm, Intermetallics 15 (2007) 1447-1452.
- [13] N.H. Tariq, B. A. Hasan, J. I. Akhter, Mechanical and tribological properties of Zr-Al-Ni-Cu bulk metallic glasses, Journal of Alloys and Compounds 469 (2009) 179-185.
- [14] Y. Yokoyama, Ductility improvement of Zr-Cu-Ni-Al glassy alloy, Journal of Non-Crystalline Solids 316 (2003) 104-113.
- [15] M. Blicharski, Materials engineering steel, WNT Press, Warsaw, 2004 (in Polish).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-4fcb4841-edd1-449d-83af-c63c633fd5e7