Efficient phosphate removal in swine wastewatewater using Fe-Mn-modified pyro/hydrochar from swine manure

• Autorzy: Zhu Fanglun , Zhang Cheng , Shan Shengdao , Yuan Wenqiao , Pawłowski Artur , Song Chengfang , Cao Yucheng , Li Yongfu , Wangj Junjie , Qian Jinyao

Identyfikatory

DOI

10.37190/epe210307

• Języki publikacji: EN

Abstrakty

EN

Phosphorus in wastewater is one of the main causes of water eutrophication. Phosphorus removal from swine wastewater is always a challenge. To achieve on-site recycling of swine farm waste, the low-cost pyro/hydrochars and their Fe-Mn-modified form were prepared from swine manure as an efficient adsorbent for phosphate removal. The results showed that the phosphate removal efficiency of unmodified pyro/hydrochars was less than 7.77%, which was significantly increased to 58.21–83.76% for the Fe-Mn-modified-pyro/hydrochars. The maximum adsorption capacity of pyrochar was found on the Fe-Mn-modified-pyrochar (PC-600M) with a surface area of 102.03 m²/g and a micropore volume of 0.25 cm³/g. The PC-600M exhibited high adsorption capacity (26.07 mg/g) in a low concentration of phosphate (50 mg/dm³), and its removal efficiency reached up to 83.76% within 24 hours. Furthermore, the adsorption of phosphate on biochars without modification (HC-210 and PC-600) was validated using a first-order kinetic model, and the adsorption of phosphate on modified biochars (HC-210M and PC-600M) was well described by the second-order kinetic model and Langmuir isotherm. In addition, there is no significant difference in the adsorption of phosphorus between pyrochars and hydrochars, but the preparation cost of hydrochars is lower than that of pyrochars. It was confirmed that the low-cost Fe-Mn-modified pyro/hydrochar from swine manure had potential for efficient phosphate removal in wastewater treatment and would facilitate value-added utilization of swine manure.

Słowa kluczowe

EN

phosphate adsorption; pig; water eutrophication; biochar; swine manure

PL

adsorpcja fosforanów; trzoda chlewna; eutrofizacja wód; biowęgiel; obornik świński

• Wydawca: Oficyna Wydawnicza Politechniki Wrocławskiej
• Czasopismo: Environment Protection Engineering
• Rocznik: 2021
• Tom: Vol. 47, nr 3
• Strony: 83--101
• Opis fizyczny: Bibliogr. 25 poz., rys., tab.

Twórcy

autor

Zhu Fanglun

• Key Laboratory of Soil Contamination Bioremediation of Zhejiang Province, Zhejiang A & F University, Hangzhou 311300, China

• https://orcid.org/0000-0003-2745-6799

autor

Zhang Cheng

• Key Laboratory of Soil Contamination Bioremediation of Zhejiang Province, Zhejiang A & F University, Hangzhou 311300, China

• https://orcid.org/0000-0003-0272-9041

autor

Shan Shengdao

• Zhejiang Province Key Laboratory of Recycling and Ecological Treatment of Waste Biomass, Zhejiang University of Science and Technology, Hangzhou 310023, China

autor

Yuan Wenqiao

• Department of Biological and Agricultural Engineering, North Carolina State University, Raleigh, NC 27695, USA

autor

Pawłowski Artur

• Faculty of Environmental Engineering, Lublin University of Technology, ul. Nadbystrzycka 40B, 20-618 Lublin, Poland

autor

Song Chengfang

• Key Laboratory of Soil Contamination Bioremediation of Zhejiang Province, Zhejiang A & F University, Hangzhou 311300, China

autor

Cao Yucheng

• Key Laboratory of Soil Contamination Bioremediation of Zhejiang Province, Zhejiang A & F University, Hangzhou 311300, China

autor

Li Yongfu

• Key Laboratory of Soil Contamination Bioremediation of Zhejiang Province, Zhejiang A & F University, Hangzhou 311300, China

autor

Wangj Junjie

• Key Laboratory of Soil Contamination Bioremediation of Zhejiang Province, Zhejiang A & F University, Hangzhou 311300, China

autor

Qian Jinyao

• Key Laboratory of Soil Contamination Bioremediation of Zhejiang Province, Zhejiang A & F University, Hangzhou 311300, China

Bibliografia

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