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Preparation of magnesium hydroxide by modifier-directed hydration and its effect on flame retardancy and mechanical properties of polypropylene

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Języki publikacji
EN
Abstrakty
EN
With the rapid development of the polymer materials industry and the improvement of people's environmental awareness, magnesium hydroxide has been widely used in polymer materials due to its high decomposition temperature, non-toxic smoke suppression, and the advantages of neutralizing harmful gases produced by polymer combustion. However, the conventional preparation methods of magnesium hydroxide exhibit several issues, including high hydrophilicity, elevated polarity, and limited compatibility with polymers. This research proposes an improved method by adding sodium stearate and KH560 modifier, controlling the rate of magnesium oxide and preparing magnesium hydroxide flame retardants using a modifier-directed hydration method. Various characterizations confirmed its morphology, particle size and structure. The magnesium hydroxide exhibits low polarity, small particle size, stable structure and excellent hydrophobicity (with a contact angle of 120.32°, and a free energy of 1.34mN/m). In parallel, the magnesium hydroxide/polypropylene composites demonstrate excellent flame retardancy (LOI of 25%, V-1 grade) and simultaneously enhance the dispersion of magnesium hydroxide within the polypropylene matrix, improving the material's toughness and strength.
Rocznik
Strony
art. no. 175706
Opis fizyczny
Bibliogr. 40 poz., rys., tab., wykr.
Twórcy
autor
  • College of Mining Engineering, North China University of Science and Technology, Tangshan 063210, China
  • Collaborative Innovation Center of Green Development and Ecological Restoration of Mineral Resources, Tangshan 063210, China
  • Heibei province Key Laboratory of Mining Development and Security Technology, Tangshan 063210, China
autor
  • College of Mining Engineering, North China University of Science and Technology, Tangshan 063210, China
  • Collaborative Innovation Center of Green Development and Ecological Restoration of Mineral Resources, Tangshan 063210, China
  • Heibei province Key Laboratory of Mining Development and Security Technology, Tangshan 063210, China
  • College of Mining Engineering, North China University of Science and Technology, Tangshan 063210, China
  • Collaborative Innovation Center of Green Development and Ecological Restoration of Mineral Resources, Tangshan 063210, China
  • Heibei province Key Laboratory of Mining Development and Security Technology, Tangshan 063210, China
autor
  • College of Mining Engineering, North China University of Science and Technology, Tangshan 063210, China
  • Collaborative Innovation Center of Green Development and Ecological Restoration of Mineral Resources, Tangshan 063210, China
  • Heibei province Key Laboratory of Mining Development and Security Technology, Tangshan 063210, China
  • College of Mining Engineering, North China University of Science and Technology, Tangshan 063210, China
  • Collaborative Innovation Center of Green Development and Ecological Restoration of Mineral Resources, Tangshan 063210, China
  • Heibei province Key Laboratory of Mining Development and Security Technology, Tangshan 063210, China
autor
  • College of Mining Engineering, North China University of Science and Technology, Tangshan 063210, China
  • Collaborative Innovation Center of Green Development and Ecological Restoration of Mineral Resources, Tangshan 063210, China
  • Heibei province Key Laboratory of Mining Development and Security Technology, Tangshan 063210, China
Bibliografia
  • MENSAH, R. A., SHANMUGAM, V., NARAYANAN S., RENNER, J. S., BABU, K., NEISIANY, R. E., FORSTH, M., SAS, G., DAS, O. 2022. A review of sustainable and environment-friendly flame retardants used in plastics. Polymer Testing 108, 107511.
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  • BROSTOW, W., S. LOHSE, A. T. LU. 2019. Nano-Al(OH)3 and Mg(OH)2 as flame retardants for polypropylene used on wires and cables. Emergent Mater 2(1), 23-34.
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  • NEREA, P., X. L. QI, S. B. NIE, P. ACUÑA, M. J. CHEN, D. Y. WANG. 2019. Flame retardant polypropylene composites with low densities. Materials 12(1), 152.
  • PARIDA, M, R., S. MOHANTY, M. BISWAL, S. K. NAYAK. 2022. Influence of aluminum trihydrate (ATH) particle size on mechanical, thermal, flame retardancy and combustion behavior of polypropylene composites. Journal of Thermal Analysis and Calorimetry 148(3), 807-819.
  • ARZHAKOVA, O. V., A. A. DOLGOVA, A. YU. KOPNOV, A. YU. YARYSHEVA, A. L. VOLYNSKII. 2023. Efficient Approach to the Preparation of Flame-Retardant Nanocomposite Polymeric Materials Based on High Density Polyethylene and Magnesium Hydroxide. Doklady Physical Chemistry 510(2), 95-99.
  • PILARSKA, A., M. WYSOKOWSKI, E. MARKIEWICZ, T. JESIONOWSKI. 2012. Synthesis of magnesium hydroxide and its calcinates by a precipitation method with the use of magnesium sulfate and poly(ethylene glycols). Powder Technol. 235, 148–157.
  • SIERRA-FERNANDEZ, A., L.S. GOMEZ-VILLALBA, O. MILOSEVIC, R. FORT, M.E. RABANAL. 2014. Synthesis and morpho-structural characterization of nanostructured magnesium hydroxide obtained by a hydrothermal method. Ceramics International 40(8), 12285-12292.
  • ZHANG, H. Y., H. Q. WANG, H. Q. WANG. 2018. Flame retardant mechanism and surface modification of magnesium hydroxide flame Retardant. IOP Conference Series: Earth and Environment Science 170(3): 032028.
  • LIANG, J. Z. 2017. Tensile and flexural properties of polypropylene composites filled with highly effective flame retardant magnesium hydroxide. Polymer Testing 60, 110-116.
  • WANG, SEN., S. T. LIANG, K. S. WANG, J. C. LIU, J. LUO, S. G. PENG. 2023. Enhanced flame retardancy, smoke suppression, and acid resistance of polypropylene/magnesium hydroxide composite by expandable graphite and microencapsulated red phosphorus. Journal of Vinyl and Additive Technology 29(2), 395-409.
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  • LIU, J. H., N. FENG, S. Q. CHANG, H. L. KANG. 2012. Preparation and characterization of poly (glycidyl methacrylate) grafted from magnesium hydroxide particles via SI-ATRP. Applied Surface Science 258(16), 6127-6135.
  • WANG, T., D. W. YAO, G. Z. YIN, Y. JIANG, N. WANG, D. Y. WANG. 2023. Gallic acid-iron complex modified magnesium hydroxide and its effect on flame retardancy of EVA. Advanced Industrial and Engineering Polymer Research 6(2), 172-180.
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Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-4ee87224-55bb-452e-bc1e-4d2b04039acc
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