Carboxymethyl Cellulose Oxidation to Form Aldehyde Group

• Autorzy: Kulikowska A. , Wasiak I. , Ciach T.
• Języki publikacji: EN

Abstrakty

EN

Oxidation of carboxymethyl cellulose (CMC) is a method of its modification, which allows to improve the functionality of this compound by increasing its reactivity. Presented work describes two methods of oxidation of carboxymethyl cellulose. The first is the conversion of CMC to its dialdehyde derivatives (DCMC) by sodium periodate. In the second method, hydrogen peroxide in the presence of iron tetrasulfophthalocyanine (FePcS) as catalyst was applied. Oxidation degree of CMC in different process parameters and time intervals was estimated using hydroxylamine hydrochloride. Modified CMC will be used in nanoparticles preparation in medical diagnostics.

Słowa kluczowe

EN

oxidation; carboxymethylcellulose; sodium periodate; hydrogen peroxide; iron tetrasulfophthalocyanine

PL

utlenianie; karboksymetyloceluloza; nadjodan sodu; nadtlenek wodoru; żelazo tetrasulfophthalocyanine

• Wydawca: Foundation for Young Scientists
• Czasopismo: Challenges of Modern Technology
• Rocznik: 2013
• Tom: Vol. 4, no. 2
• Strony: 11--18
• Opis fizyczny: Bibliogr. 13 poz., rys., tab., wykr.

Twórcy

autor

Kulikowska A.

• Biomedical Engineering Laboratory, Faculty of Chemical Engineering, Warsaw University of Technology

autor

Wasiak I.

• Biomedical Engineering Laboratory, Faculty of Chemical Engineering, Warsaw University of Technology

autor

Ciach T.

• Biomedical Engineering Laboratory, Faculty of Chemical Engineering, Warsaw University of Technology

Bibliografia

• [1] Hongli, L., et al. “Concomitant degradation in periodate oxidation of carboxymethyl cellulose”. Carbohydrate Polymers 84 (2011): 881–886.
• [2] Miller-Keane, and O’Toole. Encyclopedia & Dictionary of Medicine, Nursing & Allied Health, Revised Reprint, 7th Edition.
• [3] Boruvkova, K., and J. Wiener. “Water absorption in carboxymethyl cellulose”. AUTEX Research Journal 11 (4), 2011.
• [4] Klein-Koerkamp, C. et al. “Efficient oxidative modification of polysaccharides in water using H2O2 activated by iron sulfophthalocyanine”. Carbohydrate Polymers 78 (2009): 938–934.
• [5] Wim, H. De Jong, and Paul J.A. Borm. “Drug delivery and nanoparticles: Applications and hazards”. International Journal of Nanomedicine 3(2), 2008: 133–149.
• [6] Zonghua, L., et al. “Polysaccharides-based nanoparticles as drug delivery systems”. Advanced Drug Delivery Reviews 60 (2008): 1650–1662.
• [7] Kim, U.J., et al. “Periodate oxidation of crystalline cellulose”. Biomacromolecules 1 (2000): 488–492.
• [8] Changdao, M., et al. “Preparation and properties of dialdehyde carboxymethyl cellulose crosslinked gelatin edible films”. Food Hydrocolloids 27 (2012): 22–29.
• [9] Fuentes, M., et al. “Determination of protein-protein interac-tions through aldehyde-dextran intermolecular cross-linking”. Proteomics 4 (2004): 2602–2607.
• [10] Weber, J.H., and D.H. Bush. “Complexes derived from strong field ligands. XIX. Magnetic properties of transition metal derivatives of 4,4’,4’’,4’’’-tetrasulfophthalocyanine”. Inorganic Chemistry 4 (1965): 469–471.
• [11] Zhao, H. and N.D. Heindel. “Determination of degree of substitution of formyl groups in polyadehyde dextran by the hydroksyloamine hydrochloride method”. Pharamaceutical Research 8 (3), 1991: 400–402.
• [12] Fan, Q.G., D.M. Lewis, and K.N. Tapley. “Characterization of Cellulose Aldehyde Using Fourier Transform Infrared Spectroscopy”. Department of Colour Chemistry 2001: 1195–1202.
• [13] Calvini, P., et al. “FTIR and WAX analysis of periodate oxycellulose: Evidence for a cluster mechanism of oxidation”. Vibration Spectroscopy 40 (2006): 177–183