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Evaluation of polymers designed for radiation processing

Treść / Zawartość
Identyfikatory
Warianty tytułu
Konferencja
International Conference on Recent Developments and Applications of Nuclear Technologies (15-17.09 2008 ; Białowieża, Poland)
Języki publikacji
EN
Abstrakty
EN
Five types of commercially available polyethylene (PE) and some selected blends with components supporting cross-linking were radiation cross-linked. Mechanical properties and gel fraction were determined upon electron beam irradiation to such a dose that induces about 60% gel fraction. It was confirmed that for easily cross-linked PEs strength at break usually was growing and for polyethylenes less susceptible to radiation cross-linking – was reduced. Similar dependence was found for elongation at break. It was confirmed that for polyethylenes demonstrating high strength at break the efficiency of radiation cross-linking is limited. Additionally, for selected polymeric materials, stress relaxation and accelerated thermal aging were estimated. In order to enhance cross-linking yield some blends with EVA copolymer (ethylene-vinyl acetate) were prepared. On the basis of the literature data, the influence of crystalline regions on cross-linking and mechanical properties was discussed as well.
Słowa kluczowe
Czasopismo
Rocznik
Strony
67--72
Opis fizyczny
Bibliiogr. 16 poz., rys.
Twórcy
  • Department of Radiation Chemistry and Technology, Institute of Nuclear Chemistry and Technology, 16 Dorodna Str., 03-195 Warsaw, Poland, Tel.: +48 22 5041094, Fax: +48 22 8111532
autor
  • Department of Radiation Chemistry and Technology, Institute of Nuclear Chemistry and Technology, 16 Dorodna Str., 03-195 Warsaw, Poland, Tel.: +48 22 5041094, Fax: +48 22 8111532
autor
  • Department of Radiation Chemistry and Technology, Institute of Nuclear Chemistry and Technology, 16 Dorodna Str., 03-195 Warsaw, Poland, Tel.: +48 22 5041094, Fax: +48 22 8111532
Bibliografia
  • 1.Berejka AJ (2007) Radiation response of industrial materials: dose-rate and morphology implications. Nucl Instrum Methods Phys Res B 261:86–89
  • 2. Chmielewski AG, Haji-Saeid M, Ahmed S (2005) Progress in radiation processing of polymers. Nucl Instrum Methods Phys Res B 236:44–54
  • 3. Chodak I (1995) Properties of crosslinked polyolefinebased materials. Prog Polym Sci 20:1165–1199
  • 4. Gehring J, Zyball A (1995) Radiation cross linking of polymers – status, current issues, trends and challenges. Radiat Phys Chem 46:931–936
  • 5. Gheysari D, Behjat A, Haji-Saeid M (2001) The effect of high-energy electron beam on mechanical and thermal properties of LDPE and HDPE. Eur Polym J 37:295–302
  • 6. Hutzler BW, Machado LDB, Villavicencio A-LCH, Lugao AB (2000) Crystallization of irradiated polyethylene. Radiat Phys Chem 57:431–434
  • 7. Mateev M, Karageorgiev S (1998) The effect of electron beam irradiation of EVA upon the gel-forming processes in LDPE-EVA films. Radiat Phys Chem 51:205–206
  • 8. Moly KA, Radusch HJ, Androsh R, Bhagawan SS, Thomas S (2005) Nonisothermal crystallisation, melting behaviour and wide angle X-ray scattering investigations on linear low density polyethylene (LLDPE)/ethylene vinyl acetate (EVA) blends: effects of compatibilisation and dynamic crosslinking. Eur Polym J 41:1410–1419
  • 9. Patel GN, Keller A (1975) Crystallinity and the effect of ionizing radiation in polyethylene. I. Crosslinking and the crystal core. J Polym Sci: Polym Phys Ed 13:303–321
  • 10. Sigh A, Lopata VJ, Kremers W, Sze YK (1996) Crosslinking of commercial polyethylenes by 10 MeV electrons. Atomic Energy of Canada Limited Report AECL-11259
  • 11. Silverman J (1992) Radiation-induced and chemical crosslinking. In: Singh A, Silverman J (ed) Radiation processing of polymers. Hanser Publisher, Munch, pp 15–22
  • 12. Singh A (1999) Irradiation of polyethylene: some aspects of crosslinking and oxidative degradation. Radiat Phys Chem 56:375–380
  • 13. Sohma J, Chen Q, Wu XW, Scholtyssek G, Zachmann GH (1991) MAS NMR studies on cross links induced by irradiation to polyethylene. In: Proc of 7th Tihany Symp on Radiation Chemistry, pp 281–288
  • 14. Whittaker A (1996) 1H NMR studies of the radiation-induced crosslinking of poly(ethylene). Radiat Phys Chem 48:601–604
  • 15. Zagorski ZP (2004) EB-crosslinking of elastomers, how does it compare with radiation crosslinking of other polymers? Radiat Phys Chem 71:261–265
  • 16. Zhen SJ (2001) The effect of chain flexibility and chain mobility on radiation crosslinking of polymers. Radiat Phys Chem 60:445–451
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-4de0494f-57d4-41c0-baab-01674660c3ea
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